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Related papers: Polyatomic trilobite Rydberg molecules in a dense …

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The passage of cold cesium 49S$_{1/2}$ Rydberg atoms through an electric-field-induced multi-level avoided crossing with nearby hydrogen-like Rydberg levels is employed to prepare a cold, dipolar Rydberg atom gas. When the electric field is…

We predict that ultralong-range Rydberg bi-molecules form in collisions between polar molecules in cold and ultracold settings. The collision of $\Lambda$-doublet nitric oxide (NO) with long-lived Rydberg NO($nf$, $ng$) molecules forms…

Atomic Physics · Physics 2021-02-03 Rosario Gonzalez-Ferez , Janine Shertzer , H. R. Sadeghpour

We investigate the impact of an electric field on the structure of ultralong-range polar diatomic Rydberg molecules. Both the s-wave and p-wave interactions of the Rydberg electron and the neutral ground state atom are taken into account.…

Atomic Physics · Physics 2015-06-15 Markus Kurz , Peter Schmelcher

We explore the electronic structure and rovibrational properties of an ultralong-range triatomic Rydberg molecule formed by a Rydberg atom and a ground state heteronuclear diatomic molecule. We focus here on interaction of Rb($27s$) Rydberg…

Atomic Physics · Physics 2015-06-22 Rosario González-Férez , H. R. Sadeghpour , Peter Schmelcher

By investigating the quantum properties of magnetically trapped nS Rydberg atoms, it is demonstrated that the composite nature of Rydberg atoms significantly alters their trapping properties opposed to point-like particles with the same…

Atomic Physics · Physics 2009-04-22 M. Mayle , I. Lesanovsky , P. Schmelcher

We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…

Atomic Physics · Physics 2020-03-18 Christian Fey , Frederic Hummel , Peter Schmelcher

We have performed high resolution photoassociation spectroscopy of rubidium ultra long-range Rydberg molecules in the vicinity of the 25$P$ state. Due to the hyperfine interaction in the ground state perturber atom, the emerging mixed…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Tanita Eichert , Herwig Ott

We explore one-dimensional (1-D) samples of ultracold polar molecules with attractive dipole-dipole interactions and show the existence of a repulsive barrier due to a strong quadrupole interaction between molecules. This barrier can…

Chemical Physics · Physics 2015-06-05 Jason N. Byrd , John A. Montgomery , Robin Côté

Many organic molecules possess large permanent dipole moments that differ depending on the electronic state. These permanent dipoles influence both intermolecular coupling and interactions with the optical fields, yet they are often…

Quantum Physics · Physics 2025-08-18 Matthew Freed , Dominic M. Rouse , Andrea Rocco , Jim Al-Khalili , Marian Florescu , Adam Burgess

Rydberg excitons (analogues of Rydberg atoms in condensed matter systems) are highly excited bound electron-hole states with large Bohr radii. The interaction between them as well as exciton coupling to light may lead to strong optical…

We theoretically study trapped ions that are immersed in an ultracold gas of Rydberg-dressed atoms. By off-resonant coupling on a dipole-forbidden transition, the adiabatic atom-ion potential can be made repulsive. We study the energy…

Atomic Physics · Physics 2017-06-30 T. Secker , N. Ewald , J. Joger , H. Fürst , T. Feldker , R. Gerritsma

Dense atom ensembles with Rydberg excitations display intriguing collective effects mediated by their strong, long-range dipole-dipole interactions. These collective effects, often modeled using Rydberg superatoms, have gained significant…

Quantum Physics · Physics 2024-08-26 Xiao-Qiang Shao , Shi-Lei Su , Lin Li , Rejish Nath , Jin-Hui Wu , Weibin Li

The properties and behaviour of a Ring Rydberg Composite are explicated. This system consists of a ring of ground state atoms centered on a Rydberg atom, whose electron elastically scatters off the ground state atoms. We transform the…

Atomic Physics · Physics 2020-02-19 Matthew T. Eiles , Andrew L. Hunter , Jan M. Rost

We investigate a possible mechanism for the autoionization of ultracold Rydberg gases, based on the resonant coupling of Rydberg pair states to the ionization continuum. Unlike an atomic collision where the wave functions begin to overlap,…

Atomic Physics · Physics 2015-05-13 T. Amthor , J. Denskat , C. Giese , N. N. Bezuglov , A. Ekers , L. Cederbaum , M. Weidemüller

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

We develop a self-consistent approach that provides an explicit potential for a Rydberg electron whose ionic core consists of a polarizable medium, typically realized with superfluid droplets. The electron's motion remains separable in…

Atomic Physics · Physics 2026-02-23 Juan Carlos Acosta Matos , P. Giannakeas , Jan M. Rost

The multipartite polarization entangled states of bright optical beams directly associating with the spin states of atomic ensembles are one of the essential resources in the future quantum information networks, which can be conveniently…

Quantum Physics · Physics 2017-12-13 Liang Wu , Zhihui Yan , Yanhong Liu , Ruijie Deng , Xiaojun Jia , Changde Xie , Kunchi Peng

The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly…

Quantum Physics · Physics 2015-06-22 Torsten Scholak , Thomas Wellens , Andreas Buchleitner

While generating ultracold plasma (UCP) by photoinization of laser-cooled atoms, only a small fraction of atoms are ionized, and the remaining neutrals interact with the electrons present therein. These interactions, in addition to the…

Atomic Physics · Physics 2026-03-10 Satyam Prakash , Ashok S Vudayagiri

Recent theoretical studies with alkali atoms A$^{\ast}$ excited to high Rydberg states predicted the existence of ultra long-range molecular bound states. Such excited dimers have large electric dipole moments which, in combination with…

Atomic Physics · Physics 2009-11-13 Chris H. Greene , Edward L. Hamilton , Heather Crowell , Cedomil Vadla , Kay Niemax