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Long-range metastable molecules consisting of two cesium atoms in high Rydberg states have been observed in an ultracold gas. A sequential three-photon two-color photoassociation scheme was employed to form these molecules in states which…

Atomic Physics · Physics 2016-11-17 Heiner Saßmannshausen , Johannes Deiglmayr

Electrostatic multipole interactions generate long-range Rydberg-Rydberg macrodimer. We calculate the adiabatic potentials of cesium $(nD_{J})_2$ Rydberg macrodimers for principal quantum numbers $n$ ranging from 56 to 62, for $J=3/2$ and…

Atomic Physics · Physics 2019-07-16 Xiaoxuan Han , Suying Bai , Yuechun Jiao , Georg Raithel , Jianming Zhao , Suotang Jia

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

Atomic Physics · Physics 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…

We propose a novel type of Rydberg dimer, consisting of a Rydberg-state atom bound to a distant positive ion. The molecule is formed through long-range electric-multipole interaction between the Rydberg atom and the point-like ion. We…

Atomic Physics · Physics 2021-05-14 A. Duspayev , X. Han , M. A. Viray , L. Ma , J. Zhao , G. Raithel

We investigate a long-range interaction between $64D_{5/2}$ Rydberg-atom pairs and antiblockade effect employing a two-color excitation scheme. The first color (pulse A) is set to resonantly excite the Rydberg transition and prepare a few…

Atomic Physics · Physics 2020-02-25 Suying Bai , Xuedong Tian , Xiaoxuan Han , Yuechun Jiao , Jinhui Wu , Jianming Zhao , Suotang Jia

Controlling molecular binding at the level of single atoms is one of the holy grails of quantum chemistry. Rydberg macrodimers -- bound states between highly excited Rydberg atoms -- provide a novel perspective in this direction. Resulting…

Atomic Physics · Physics 2023-06-14 Simon Hollerith , Johannes Zeiher

Long-range $(n+2)D_{5/2} \, nF_J$ Rydberg macro-dimers are observed in an ultracold cesium Rydberg gas for $39\leq n\leq48$. Strong dipolar "flip" ($\langle D_{5/2} F_{5/2} \vert \hat{V}_{dd} \vert F_{5/2} D_{5/2} \rangle$, $\langle D_{5/2}…

Atomic Physics · Physics 2024-11-05 Jingxu Bai , Yuechun Jiao , Rong Song , Georg Raithel , Suotang Jia , Jianming Zhao

We propose a new approach to excite ion-pair states of ultracold dimers. The central idea is a two-step process where first long-range Rydberg molecules are formed by photoassociation, which are then driven by stimulated emission towards…

Atomic Physics · Physics 2020-02-25 Michael Peper , Johannes Deiglmayr

We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…

Cs$_2$ Rydberg-ground molecules consisting of a Rydberg, $nD_{J}$ (33 $\leq$ $n$ $\leq$ 39), and a ground state atom, 6$S_{1/2} (F=$3 or 4$)$, are investigated by photo-association spectroscopy in a cold atomic gas. We observe vibrational…

Atomic and Molecular Clusters · Physics 2020-10-07 Suying Bai , Xiaoxuan Han , Jingxu Bai , Yuechun Jiao , Jianming Zhao , Suotang Jia , Georg Raithel

The lifetimes and decay channels of ultralong-range Rydberg molecules created in a dense BEC are examined by monitoring the time evolution of the Rydberg population using field ionization. Studies of molecules with values of principal…

We report the creation of ultralong-range Sr$_2$ molecules comprising one ground-state $5s^2$ $^1S_0$ atom and one atom in a $5sns$ $^3S_1$ Rydberg state for $n$ ranging from 29 to 36. Molecules are created in a trapped ultracold atomic gas…

Pulsed laser excitation of a dense ultracold Cs vapor has been used to study the pairwise interactions between Cs atoms excited to $n$p$_{3/2}$ Rydberg states of principal quantum numbers in the range $n=22-36$. Molecular resonances were…

Atomic Physics · Physics 2015-09-14 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

The lifetimes of the lower-lying vibrational states of ultralong-range strontium Rydberg molecules comprising one ground-state 5s2 1S0 atom and one Rydberg atom in the 5s38s 3S1 state are reported. The molecules are created in an ultracold…

Experimental measurements of photoionization rates of $nD_{5/2}$ Rydberg states of Cs ($50 \leq n \leq 75$) in a 1064 nm far off-resonance dipole trap are presented. The photoionization rates are obtained by measuring the lifetimes of…

Atomic Physics · Physics 2015-05-20 J. Tallant , D. Booth , J. P. Shaffer

When ultracold plasma is generated using photonization of laser cooled atoms, some atoms reach only upto Rydberg states. These in turn interact with the free electrons of the plasma and get ionized further. We study the interaction of…

Atomic Physics · Physics 2026-03-18 Satyam Prakash , Ashok S Vudayagiri

We study long range interactions between two Rydberg atoms and predict the existence of ultralong range Rydberg dimers with equilibrium distances of many thousand Bohr radii. We calculate the dispersion coefficients $C_{5}$, $C_{6}$ and…

Atomic Physics · Physics 2009-11-07 Christophe Boisseau , Ionel Simbotin , Robin Cote

Long-range Rydberg molecules (LRMs) form when a highly excited Rydberg electron scatters from ground-state atoms inside its orbit, creating oscillatory, long-range potentials. We present a combined theoretical and experimental study of…

We explore long-range interactions between two atoms excited into high principal quantum number n Rydberg states, and present calculated potential energy surfaces (PES) for various symmetries of doubly excited ns and np rubidium atoms. We…

Atomic Physics · Physics 2015-05-28 Nolan Samboy , Robin Côté
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