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We numerically investigate the high-efficiency photovoltaic effect in lateral p-n homojunction based on monolayer black phosphorus (MBP) by using the non-equilibrium Green's function combined with the density functional theory. Due to the…

Mesoscale and Nanoscale Physics · Physics 2023-08-15 Xueying Zuo , Jingjing Cheng , Yulin Liang , Fuming Xu , Yanxia Xing

We experimentally determine the lattice dynamics of black phosphorus layered crystals through a combination of x-ray diffuse scattering and inelastic x-ray scattering, and we rationalize our experimental findings using $\textit{ab initio}$…

Phosphorene, a monolayer of black phosphorus, is a two-dimensional material that lacks a multivalley structure in the Brillouin zone and has negligible spin-orbit coupling. This makes it a promising candidate for investigating the orbital…

Mesoscale and Nanoscale Physics · Physics 2023-10-20 Tarik P. Cysne , Marcio Costa , Marco Buongiorno Nardelli , R. B. Muniz , Tatiana G. Rappoport

Black phosphorus thin films might offer attractive alternatives to narrow gap compound semiconductors for optoelectronics across mid- to near-infrared frequencies. In this work, we calculate the optical conductivity tensor of multilayer…

Materials Science · Physics 2014-09-18 Tony Low , A. S. Rodin , A. Carvalho , Yongjin Jiang , Han Wang , Fengnian Xia , A. H. Castro Neto

We apply the generalized Boltzmann theory to describe thermoelectric transport properties of monolayer phosphorene in the presence of short- and long-range charged impurity interactions. First, we propose a low-energy Hamiltonian to explore…

Mesoscale and Nanoscale Physics · Physics 2017-01-27 Moslem Zare , Babak Zare Rameshti , Farnood G. Ghamsari , Reza Asgari

By performing \emph{ab initio} calculations for one- to four-layer black phosphorus within the $GW$ approximation, we obtain a significant difference in the band gap ($\sim$1.5 eV), which is in line with recent experimental data. The…

Materials Science · Physics 2014-06-25 Alexander N. Rudenko , Mikhail I. Katsnelson

Monolayers of group VA elements have attracted great attention with the rising of black phosphorus. Here, we derive a simple tight-binding model for monolayer grey arsenic, referred as arsenene (ML-As), based on the first-principles…

Materials Science · Physics 2018-09-19 Jin Yu , Mikhail I. Katsnelson , Shengjun Yuan

We calculate an electron-phonon scattering and intrinsic transport properties of black phosphorus monolayer using tight-binding and Boltzmann treatments as a function of temperature, carrier density, and electric field. The low-field…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Yuri Trushkov , Vasili Perebeinos

We investigate the impact of the encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black…

Mesoscale and Nanoscale Physics · Physics 2017-11-23 J. M. Urban , M. Baranowski , A. Surrente , D. Wlodarczyk , A. Suchocki , G. Long , Y. Wang , L. Klopotowski , N. Wang , D. K. Maude , P. Plochocka

Ultrathin black phosphorus, or phosphorene, is the second known elementary two-dimensional material that can be exfoliated from a bulk van der Waals crystal. Unlike graphene it is a semiconductor with a sizeable band gap and its excellent…

Black phosphorous is a layered material having a high capacity of 2596 mAh/g as a battery electrode, however it suffers from cracking due to high volume expansion during lithiation. These cracks causes loss of electrical contact in the…

Materials Science · Physics 2020-07-21 Burak Ozdemir

In 2D materials, the quantum confinement and van der Waals-type interlayer interactions largely govern the fundamental electronic and optical properties, and the dielectric screening plays a dominant role in the excitonic properties. This…

Mesoscale and Nanoscale Physics · Physics 2021-02-19 Guowei Zhang , Shenyang Huang , Fanjie Wang , Hugen Yan

We investigate the effect of charge carrier interaction with surface optical phonons on the band properties of monolayer black phosphorus induced by polar substrates. We develop an analytical method based on the Lee-Low-Pines theory to…

Mesoscale and Nanoscale Physics · Physics 2016-02-12 A. Mogulkoc , Y. Mogulkoc , A. N. Rudenko , M. I. Katsnelson

Black phosphorus exhibits a high degree of band anisotropy. However, we found that its in-plane static screening remains relatively isotropic for momenta relevant to elastic long-range scattering processes. On the other hand, the collective…

Experimental studies on two-dimensional (2D) materials are still in the early stages, and most of the theoretical studies performed to screen these materials are limited to the room-temperature carrier-mobility in the free standing 2D…

Mesoscale and Nanoscale Physics · Physics 2020-07-30 Gautam Gaddemane , Maarten L. Van de Put , William G. Vandenberghe , Edward Chen , Massimo V. Fischetti

In order to understand the relation of strain and material properties, both a microscopic model connecting a given strain to the displacement of atoms, and a macroscopic model relating applied stress to induced strain, are required.…

Mesoscale and Nanoscale Physics · Physics 2016-08-11 Daniel Midtvedt , Alexander Croy

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

Black phosphorus (BP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted,…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 Mazhar Chebl , Xing He , Ding-Shyue Yang

As a new two-dimensional layered material, black phosphorus (BP) is a promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to report our findings related to low-frequency…

We report a straightforward chemical methodology for controlling the thickness of black phosphorus flakes down to the monolayer limit by layer-by-layer oxidation and thinning, using water as solubilizing agent. Moreover, the oxidation…