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A new type of two-dimensional layered semiconductor with weak electrostatic but not van der Waals interlayer interactions, Bi2O2Se, has been recently synthesized, which shown excellent air stability and ultrahigh carrier mobility. Herein,…

Mesoscale and Nanoscale Physics · Physics 2018-08-20 Ting Cheng , Congwei Tan , Shuqing Zhang , Teng Tu , Hailin Peng , Zhirong Liu

Raman and photoluminescence (PL) measurements were performed on suspended and supported MoS2 up to 6 trilayers (TLs). The difference in the dielectric environment of suspended and supported MoS2 does not lead to large differences in the PL…

Mesoscale and Nanoscale Physics · Physics 2015-11-05 Jae-Ung Lee , Kangwon Kim , Hyeonsik Cheong

The symmetry group analysis is applied to classify the phonon modes of $N$-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated…

Materials Science · Physics 2008-06-30 Jin-Wu Jiang , Hui Tang , Bing-Shen Wang , Zhao-Bin Su

We present Raman measurements of mono- and few-layer WS2. We study the monolayer A'1 mode around 420 cm(-1) and its evolution with the number of layers. We show that with increasing layer number there is an increasing number of possible…

Two-dimensional (2D) transition metal dichalcogenide (TMD) nanosheets exhibit remarkable electronic and optical properties. The 2D features, sizable bandgaps, and recent advances in the synthesis, characterization, and device fabrication of…

Materials Science · Physics 2015-02-04 Xin Zhang , Xiao-Fen Qiao , Wei Shi , Jiang-Bin Wu , De-Sheng Jiang , Ping-Heng Tan

The structural polymorphism in transition metal dichalcogenides (TMDs) provides exciting opportunities for developing advanced electronics. For example, MoTe$_2$ crystallizes in the 2H semiconducting phase at ambient temperature and…

Detailed high pressure Resonance Raman ($RR$) Spectroscopy and X-ray diffraction ($XRD$) studies are carried out on 3-4 layered $MoSe_2$ obtained by liquid exfoliation. Analysis of ambient $XRD$ pattern and $RR$ spectra indicate the…

Materials Science · Physics 2019-08-29 Pinku Saha , Bishnupada Ghosh , Aritra Mazumder , Goutam Dev Mukherjee

Raman scattering excitation (RSE) is an experimental technique in which the spectrum is made up by sweeping the excitation energy when the detection energy is fixed. We study the low-temperature ($T$=5~K) RSE spectra measured on four high…

We perform density functional theory calculation to investigate the structural and electronic properties of various two-dimensional transition metal dichalcogenides, MX$_2$ (M$=$Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W, and X$=$S or Se), and…

Materials Science · Physics 2019-05-21 Seoung-Hun Kang , Young-Kyun Kwon

Transition-metal dichalcogenide (TMD) semiconductors have been widely studied due to their distinctive electronic and optical properties. The property of TMD flakes is a function of its thickness, or layer number (N). How to determine N of…

Materials Science · Physics 2016-03-01 Xiao-Li Li , Xiao-Fen Qiao , Wen-Peng Han , Xin Zhang , Qing-Hai Tan , Tao Chen , Ping-Heng Tan

We report a comprehensive study of the two-phonon inter-valley (2D) Raman mode in graphene monolayers, motivated by recent reports of asymmetric 2D-mode lineshapes in freestanding graphene. For photon energies in the range $1.53 \rm eV -…

Mesoscale and Nanoscale Physics · Physics 2014-06-26 Stéphane Berciaud , Xianglong Li , Han Htoon , Louis E. Brus , Stephen K. Doorn , Tony F. Heinz

We have investigated the interlayer shear and breathing phonon modes in MoS$_{2}$ with pure 3R and 2H stacking order by using polarization-dependent ultralow-frequency Raman spectroscopy. We observe up to three shear branches and four…

Mesoscale and Nanoscale Physics · Physics 2019-02-01 Jeremiah van Baren , Gaihua Ye , Jia-An Yan , Zhipeng Ye , Pouyan Rezaie , Peng Yu , Zheng Liu , Rui He , Chun Hung Lui

Two-dimensional (2D) van der Waals (vdW) magnetic materials have emerged as key materials for next-generation magneto-electric and spintronic devices, where understanding the relationship between layer number, lattice dynamics, and magnetic…

Materials Science · Physics 2025-11-18 Nilesh Choudhury , Sandeep , Neesha Yadav , Mayank Shukla , Pintu Das

Transition metal dichalcogenides (TMDs) have recently attracted attention due to their interesting electronic and optical properties. Fabrication of these materials in a reliable and facile method is important for future applications, as…

Intercalation offers a promising way to alter the physical properties of two-dimensional (2D) layered materials. Here we investigate the electronic and vibrational properties of 2D layered MoSe$_2$ intercalated with atomic manganese at…

Materials Science · Physics 2020-09-28 Shunda Chen , Virginia L. Johnson , Davide Donadio , Kristie J. Koski

We study in-plane lateral heterostructures of commensurate transition-metal dichalcogenides, such as MoS$_{2}$-WS$_{2}$ and MoSe$_{2}$-WSe$_{2}$, and find interfacial and edge states that are highly localized to these regions of the…

Mesoscale and Nanoscale Physics · Physics 2019-01-04 Oscar Ávalos-Ovando , Diego Mastrogiuseppe , Sergio E. Ulloa

We investigate the ultralow-frequency Raman response of atomically thin ReS2, a special type of two-dimensional (2D) semiconductors with unique distorted 1T structure. Bilayer and few-layer ReS2 exhibit rich Raman spectra at frequencies…

Mesoscale and Nanoscale Physics · Physics 2016-02-16 Rui He , Jia-An Yan , Zongyon Yin , Zhipeng Ye , Gaihua Ye , Jason Cheng , Ju Li , C. H. Lui

Despite being usually considered two competing phenomena, charge-density-wave and superconductivity coexist in few systems, the most emblematic one being the transition metal dichalcogenide 2H-NbSe$_2$. This unusual condition is responsible…

The vibrational and electronic properties of 2-dimensinal (2D) materials can be efficiently tuned by external strain due to their good stretchability. Resonant Raman spectroscopy is a versatile tool to study the physics of phonons,…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Chaoyu Song , Fengren Fan , Ningning Xuan , Shenyang Huang , Chong Wang , Guowei Zhang , Fanjie Wang , Qiaoxia Xing , Yuchen Lei , Zhengzong Sun , Hua Wu , Hugen Yan

We investigated interlayer phonon modes of mechanically exfoliated few-layer 2H-SnS2 samples by using room temperature low-frequency micro-Raman spectroscopy. Raman measurements were performed using laser wavelength of 441.6, 514.4, 532 and…

Materials Science · Physics 2018-07-16 Tharith Sriv , Kangwon Kim , Hyeonsik Cheong