Related papers: Crossing conditions in coupled cluster theory
Conical intersections (CI) between molecular potential energy surfaces with non-vanishing non-adiabatic couplings generally occur in any molecule consisting of at least three atoms. They play a fundamental role in describing the molecular…
We present an efficient implementation of analytical non-adiabatic derivative coupling elements for the coupled cluster singles and doubles model. The derivative coupling elements are evaluated in a biorthonormal formulation in which the…
Coupled excitonic structures are found in natural and artificial light harvesting systems where optical transitions link different excitation manifolds. In systems with symmetry, some optical transitions are allowed, while others are…
The rigorous description of Conical Intersections (CIs) remains the central challenge of non-adiabatic quantum chemistry. While the ``Yarkony Seam'' -- the $(3N-8)$-dimensional manifold of degeneracy -- is well-understood geometrically, its…
Symmetries corresponding to local transformations of the fundamental fields that leave the action invariant give rise to (invertible) topological defects, which obey group-like fusion rules. One can construct more general (codimension-one)…
This paper constructs (with challenging obstacles) on the three torus with its cubical decomposition: Firstly, a combinatorial graded intersection algebra (graded by the codimension) which is commutative and associative defined by…
In the spectrum of systems showing chaos-assisted tunneling, three-state crossings are formed when a chaotic singlet intersects a tunnel doublet. We study the dissipative quantum dynamics in the vicinity of such crossings. A harmonically…
An analogy between the twisted quantum xxz model and a gated Josephson junction array is used to predict sharp structure in the critical currents versus gate voltage, and fractional AC Josephson frequencies. We prove selection rules for…
We find that energy surfaces of more than two atoms or molecules interacting via dipole-dipole po- tentials generically possess conical intersections (CIs). Typically only few atoms participate strongly in such an intersection. For the…
We present a model for molecular materials made up of polar and polarizable molecular units. A simple two state model is adopted for each molecular site and only classical intermolecular interactions are accounted for, neglecting any…
We consider two dimensional systems in which edge states coexist with a gapless bulk. Such systems may be constructed, for example, by coupling a gapped two dimensional state of matter that carries edge states to a gapless two dimensional…
We use holography to analyse relativistic collisions in a one-parameter family of strongly coupled gauge theories with thermal phase transitions. For a critical value of the parameter the transition is second order, for subcritical values…
We observe a series of conical intersections in the potential energy curves governing both the collision between a Rydberg atom and a ground-state atom and the structure of Rydberg molecules. By employing the electronic energy of the…
We prove the existence of non-trivial phase transitions for the intersection of two independent random interlacements and the complement of the intersection. Some asymptotic results about the phase curves are also obtained. Moreover, we…
Understanding the electron pairing in hole-doped cuprate superconductors has been a challenge, in particular because the "normal" state from which it evolves is unprecedented. Now, after three and a half decades of research, involving a…
In this note, we will characterize constraints on the possible IR phases of a given QFT by anomalies in the space of coupling constants. We will give conditions under which a coupling constant anomaly cannot be matched by a continuous…
Symmetry-breaking phase transitions are ubiquitous in condensed matter systems and in quantum field theories. There is also good reason to believe that they feature in the very early history of the Universe. At many such transitions…
We characterize parallel double quantum dot Josephson junctions based on closely-grown double nanowires bridged by in-situ deposited superconductors. The parallel double dot behavior occurs despite the closeness of the nanowires and the…
The interplay of interactions and disorder is studied using the Anderson-Hubbard model within the typical medium dynamical cluster approximation. Treating the interacting, non-local cluster self-energy ($\Sigma_c[{\cal \tilde{G}}](i,j\neq…
As a test of the new light-front coupled-cluster method in a gauge theory, we apply it to the nonperturbative construction of the dressed-electron state in QED, for an arbitrary covariant gauge, and compute the electron's anomalous magnetic…