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Related papers: Deformed Jarzynski Equality

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The computation of free energy differences through an exponential weighting of out of equilibrium paths (known as the Jarzynski equality) is often used for transitions between states described by an external parameter $\lambda$ in the…

Statistical Mechanics · Physics 2015-06-25 Tony Lelievre , Mathias Rousset , Gabriel Stoltz

We have studied the Jarzynski equality (JE) in van der Pol and Rayleigh oscillators which are typical deterministic non-Hamiltonian models, but not expected to rigorously satisfy the JE because they are not microscopically reversible. Our…

Statistical Mechanics · Physics 2015-05-28 Hideo Hasegawa

The quantum Jarzynski equality and the Crooks relation are fundamental laws connecting equilibrium processes with nonequilibrium fluctuations. They are promising tools to benchmark quantum devices and measure free energy differences. While…

Statistical Mechanics · Physics 2023-11-07 Dominik Hahn , Maxime Dupont , Markus Schmitt , David J. Luitz , Marin Bukov

The Jarzynski equality and the fluctuation theorem relate equilibrium free energy differences to non-equilibrium measurements of the work. These relations extend to single-molecule experiments that have probed the finite-time thermodynamics…

Statistical Mechanics · Physics 2008-08-30 Paul Maragakis , Felix Ritort , Carlos Bustamante , Martin Karplus , Gavin E. Crooks

The energy change dE_k for the kth microstate is erroneously equated with the external work done on the microstate. It ignores the ubiquitous internal energy change d_iW_k due to force imbalance between the internal and external forces. We…

Statistical Mechanics · Physics 2018-03-29 P. D. Gujrati

We show a practical application of an well-known nonequilibrium relation, the Jarzynski equality, in quantum computation. Its implementation may open a way to solve combinatorial optimization problems, minimization of a real single-valued…

Quantum Physics · Physics 2010-07-06 Masayuki Ohzeki , Hidetoshi Nishimori

The celebrated exchange fluctuation theorem -- proposed by Jarzynski and W\'ozcik, (Phys Rev. Lett. 92, 230602 (2004)) for heat exchange between two systems in thermal equilibrium at different temperatures -- is explored here for quantum…

Quantum Physics · Physics 2021-11-05 A R Usha Devi , Sudha , A. K. Rajagopal , A. M. Jayannavar

We introduce a simple enhanced sampling approach for the calculation of free energy differences and barriers along a one-dimensional reaction coordinate. First, a small number of short nonequilibrium simulations are carried out along the…

Chemical Physics · Physics 2021-11-03 Kristof M. Bal

When a thermally isolated system performs a driving process in the quasistatic regime, its variation of average energy is equal to its quasistatic work. Even though presenting this simple definition, few attempts have been made to describe…

Statistical Mechanics · Physics 2025-02-17 Pierre Nazé

We present a general scheme to obtain work distribution in closed systems under continuous quantum histories of corresponding "power" operator. The scheme is tested by analytically calculating the quantum work distribution for a prototype…

Statistical Mechanics · Physics 2013-04-24 Huanan Li , Jian-Sheng Wang

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

Characterizing fluctuations of work in coherent quantum systems is notoriously problematic. Here we reveal the ultimate source of the problem by proving that ($\mathfrak{A}$) energy conservation and ($\mathfrak{B}$) the Jarzynski…

Quantum Physics · Physics 2024-05-08 Karen V. Hovhannisyan , Alberto Imparato

Responses of small open oscillator systems to applied external forces have been studied with the use of an exactly solvable classical Caldeira-Leggett (CL) model in which a harmonic oscillator (system) is coupled to finite $N$-body…

Statistical Mechanics · Physics 2015-05-27 Hideo Hasegawa

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in…

Quantum Physics · Physics 2019-11-05 Tiago Debarba , Gonzalo Manzano , Yelena Guryanova , Marcus Huber , Nicolai Friis

We show how Jarzynski relation can be exploited to analyze the nature of order-disorder and a bifurcation type dynamical transition in terms of a response function derived on the basis of work distribution over non-equilibrium paths between…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Deb Shankar Ray

We study two non-equilibrium work fluctuation theorems, the Crooks' theorem and the Jarzynski equality, for a test system coupled to a spatially extended heat reservoir whose degrees of freedom are explicitly modeled. The sufficient…

Statistical Mechanics · Physics 2010-02-22 Punyabrata Pradhan , Yariv Kafri , Dov Levine

The two-time measurement scheme is well studied in the context of quantum fluctuation theorem. However, it becomes infeasible when the random variable determined by a single measurement trajectory is associated with the von-Neumann entropy…

Quantum Physics · Physics 2023-04-20 Akira Sone , Naoki Yamamoto , Tharon Holdsworth , Prineha Narang

A superconducting cavity model was proposed as a way to experimentally investigate the work performed in a quantum system. We found a simple mathematical relationship between the free energy variation and visibility measurement in quantum…

In open systems with strong coupling, the interaction energy between the system and the environment is significant, so thermodynamic quantities cannot be reliably obtained by traditional statistical mechanics methods. The Hamiltonian of…

Statistical Mechanics · Physics 2025-05-02 Mohammad Rahbar , Christopher J. Stein
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