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The variational procedure to construct compact and accurate wave functions for three-electron atoms and ions is developed. The procedure is based on the use of six-dimensional gaussoids written in the relative four-body coordinates $r_{12},…

Atomic Physics · Physics 2011-01-11 Alexei M. Frolov , David M. Wardlaw

In this paper, we consider the Dirac-Coulomb equation for many-particles, to describe the interaction between electrons in the system having many electrons. The four-component wave function will expanding into a finite basis-set, using…

Quantum Physics · Physics 2019-12-10 Bilal K. Jasim , Ayad A. Al-Ani , Saad N. Abood

A Gaussian operator representation for the many body density matrix of fermionic systems, developed by Corney and Drummond [Phys. Rev. Lett, v93, 260401 (2004)], is used to derive approximate decoupling schemes for their dynamics. In this…

Other Condensed Matter · Physics 2009-06-01 Saar Rahav , Shaul Mukamel

We have developed a symmetry-adapted modeling procedure for molecules and crystals. By using the completeness of multipoles to express spatial and time-reversal parity-specific anisotropic distributions, we can generate systematically the…

Materials Science · Physics 2023-05-12 Hiroaki Kusunose , Rikuto Oiwa , Satoru Hayami

We present a new efficient way to perform hybrid density functional theory (DFT) based electronic structure calculation. The new method uses an interpolative separable density fitting (ISDF) procedure to construct a set of numerical…

Computational Physics · Physics 2017-07-31 Wei Hu , Lin Lin , Chao Yang

A mixed basis approach based on density functional theory is extended to one-dimensional(1D) systems. The basis functions here are taken to be the localized B-splines for the two finite non-periodic dimensions and the plane waves for the…

Materials Science · Physics 2016-04-20 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue

A very popular ab-initio scheme to calculate electronic properties in solids is the use of hybrid functionals in density functional theory (DFT) that mixes a portion of Fock exchange with DFT functionals. In spite of their success, a major…

Materials Science · Physics 2015-05-20 Miguel A. L. Marques , Julien Vidal , Micael J. T. Oliveira , Lucia Reining , Silvana Botti

We study the performance of a multidimensional matched filter as a follow-up module of the coherent method recently developed by two of us for the detection of gravitational wave bursts by spherical resonant detectors. We have tested this…

General Relativity and Quantum Cosmology · Physics 2015-05-13 Carlos Filipe Da Silva Costa , Stefano Foffa , Riccardo Sturani

The evaluation of exact (Hartree--Fock, HF) exchange operator is a crucial ingredient for the accurate description of electronic structure in periodic systems through ab initio and hybrid density functional approaches. An efficient…

Chemical Physics · Physics 2020-10-28 Xiao Wang , Cannada A. Lewis , Edward F. Valeev

In the present letter, we report the extension of our Wannier-function-based ab initio Hartree-Fock approach---meant originally for three-dimensional crystalline insulators---to deal with quasi-one-dimensional periodic systems such as…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Hermann Stoll

The series expansion formulae are established for the one- and two-center charge densities over complete orthonormal sets of exponential type orbitals introduced by the author. Three-center overlap integrals of appearing in these relations…

Chemical Physics · Physics 2009-02-04 I. I. Guseinov

We provide new single-integral formulas of the power spectral density of single-channel and cross-channel nonlinear interference in highly-dispersed coherent optical links for which the Gaussian Noise model [1], [2] applies.

Optics · Physics 2013-09-03 Alberto Bononi , Ottma Beucher

Simulating vibrationally resolved electronic spectra of anharmonic systems, especially those involving double-well potential energy surfaces, often requires expensive quantum dynamics methods. Here, we explore the applicability and…

Chemical Physics · Physics 2022-05-12 Tomislav Begušić , Enrico Tapavicza , Jiří Vaníček

We evaluate an adaptive gaussian quadrature integration scheme that will be suitable for the numerical evaluation of generalized redistribution in frequency functions. The latter are indispensable ingredients for "full non-LTE" radiation…

Instrumentation and Methods for Astrophysics · Physics 2020-01-29 F. Paletou , C. Peymirat , E. Anterrieu , T. Böhm

Computation of high frequency solutions to wave equations is important in many applications, and notoriously difficult in resolving wave oscillations. Gaussian beams are asymptotically valid high frequency solutions concentrated on a single…

Analysis of PDEs · Mathematics 2009-06-17 Hailiang Liu , James Ralston

Gravitational wave detectors like the Einstein Telescope and LISA generate long multivariate time series, which pose significant challenges in spectral density estimation due to a number of overlapping signals as well as the presence of…

General Relativity and Quantum Cosmology · Physics 2024-09-23 Jianan Liu , Avi Vajpeyi , Renate Meyer , Kamiel Janssens , Jeung Eun Lee , Patricio Maturana-Russel , Nelson Christensen , Yixuan Liu

A recently proposed approach for performing electronic-structure calculations on crystalline insulators in terms of localized orthogonal orbitals is applied to the oxides of lithium and sodium, Li2O and Na2O. Cohesive energies, lattice…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

We present a mixed basis-set approach to obtain optical absorption spectra within a generalized Kohn-Sham time-dependent density functional theory framework. All occupied valence molecular orbitals (MOs) are expanded in a plane-wave (PW)…

Chemical Physics · Physics 2025-08-13 Kyle Chen , Barry Y. Li , Tucker Allen , Daniel Neuhauser

We present a novel approach to approximate Gaussian and mixture-of-Gaussians filtering. Our method relies on a variational approximation via a gradient-flow representation. The gradient flow is derived from a Kullback--Leibler discrepancy…

Computation · Statistics 2023-06-21 Adrien Corenflos , Hany Abdulsamad

The analytical gradient for periodic systems is presented, for the case of metallic systems. The total energy and the free energy are computed on the Hartree-Fock or density functional level, with the wave function being expanded in terms…

Materials Science · Physics 2012-04-25 K. Doll