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We propose a variational formulation for the nonequilibrium thermodynamics of discrete open systems, i.e., discrete systems which can exchange mass and heat with the exterior. Our approach is based on a general variational formulation for…
The energetics of the stochastic process has shown the balance of energy on the mesoscopic level. The heat and the energy defined there are, however, generally different from their macroscopic counterpart. We show that this discrepancy can…
We investigate the thermalization of a stochastic system with discrete phase space, initially at equilibrium at temperature $T_i$ and then termalizing in an environment at temperature $T_f$ , considering both cases $T_i > T_f$ and $T_i <…
The process of deriving an interatomic potentials represents an attempt to integrate out the electronic degrees of freedom from the full quantum description of a condensed matter system. In practice it is the derivatives of the interatomic…
Breakage is generally understood in mechanical terms, yet nano-structures can rupture not only under external loads but also via thermal activation. Here we treat in a general framework the statistical mechanics of thermally induced…
We focus on a highly nonlinear evolutionary abstract PDE system describing volume processes coupled with surfaces processes in thermoviscoelasticity, featuring the quasi-static momentum balance, the equation for the unidirectional evolution…
We consider the thermal behavior of a large number of matrix degrees of freedom in the planar limit. We work in $0+1$ dimensions, with $D$ matrices, and use $1/D$ as an expansion parameter. This can be thought of as a non-commutative…
Thermodynamical arguments are known to be useful in the construction of physically motivated Lyapunov functionals for nonlinear stability analysis of spatially homogeneous equilibrium steady states in thermodynamically isolated systems.…
We consider conditions under which an isolated quantum system approaches a microcanonical equilibrium state. A key component is the eigenstate thermalisation hypothesis, which proposes that all energy eigenstates appear thermal. We…
We describe a symplectic approach towards thermodynamics in which thermodynamic transformations are described by (symplectic) Hamiltonian dynamics. Upon identifying the spaces of equilibrium states with Lagrangian submanifolds of a…
We discuss the crystallization process from the supersaturated melt in terms of its non-equilibrium properties. In particular, we quantify the amount of heat that is produced irreversibly when a suspension of hard spheres crystallizes. This…
The minimal work principle states that work done on a thermally isolated equilibrium system is minimal for adiabatically slow (reversible) realization of a given process. This principle, one of the formulations of the second law, is studied…
In this paper, we analyze a PDE system arising in the modeling of phase transition and damage phenomena in thermoviscoelastic materials. The resulting evolution equations in the unknowns \theta (absolute temperature), u (displacement), and…
The thermal decay of linear chains from a metastable state is investigated. A crossover from rigid to elastic decay occurs when the number of particles, the single particle energy barrier or the coupling strength between the particles is…
We investigate the fundamental limitations imposed by thermodynamics for creating correlations. Considering a collection of initially uncorrelated thermal quantum systems, we ask how much classical and quantum correlations can be obtained…
Using holographic duality, we investigate thermalization process when two finite-size quantum critical systems are brought into thermal contact along a perfectly transmitting interface. Through real-time simulations of gravitational…
We formalize and prove the extension to finite temperature of a class of quantum phase transitions, acting as condensations in the space of states, recently introduced and discussed at zero temperature~(Ostilli and Presilla 2021 \textit{J.…
In this work, a thermal energy transfer problem in a one-dimensional multilayer body is theoretically analyzed, considering diffusion, advection, internal heat generation or loss linearly dependent on temperature in each layer, as well as…
Classical phase transitions, like solid-liquid-gas or order-disorder spin magnetic phases, are all driven by thermal energy fluctuations by varying the temperature. On the other hand, quantum phase transitions happen at absolute zero…
Recent progress in the synthesis and processing of nano-structured materials and systems calls for an improved understanding of thermal properties on small length scales. In this context, the question whether thermodynamics and, in…