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Richardson-Gaudin states provide a basis of the Hilbert space for strongly correlated electrons. In this study, optimal expressions for the transition density matrix elements between Richardson-Gaudin states are obtained with a cost…

Chemical Physics · Physics 2024-05-02 Paul A. Johnson

By application of a straightforward variational procedure we derive a simple, analytic upper bound on the ground-state energy eigenvalue of a semirelativistic Hamiltonian for (one or two) spinless particles which experience some…

High Energy Physics - Phenomenology · Physics 2009-10-28 Wolfgang Lucha , Franz F. SCHÖberl

In electronic structure theory, variational methods offer a valuable paradigm for approximating electronic ground states. However, for historical reasons, this principle is mostly restricted to model chemistries in pre-defined fixed basis…

Quantum Physics · Physics 2025-11-17 Fabian Langkabel , Stefan Knecht , Jakob S. Kottmann

We present a generalization of the variational principle that is compatible with any Hamiltonian eigenstate that can be specified uniquely by a list of properties. This variational principle appears to be compatible with a wide range of…

Chemical Physics · Physics 2020-02-07 Jacqueline A. R. Shea , Elise Gwin , Eric Neuscamman

We employ a generalized variational principle to improve the stability, reliability, and precision of fully excited-state-specific complete active space self-consistent field theory. Compared to previous approaches that similarly seek to…

Chemical Physics · Physics 2022-09-05 Rebecca Hanscam , Eric Neuscamman

We propose an improved parametric form for the equation of state of three-dimensional O(N) spin systems. The proposed form is a series expansion with two sets of terms, which contribute (mainly) separately to the description of the high-…

High Energy Physics - Lattice · Physics 2009-11-10 Attilio Cucchieri , Tereza Mendes

One of the key applications for the emerging quantum simulators is to emulate the ground state of many-body systems, as it is of great interest in various fields from condensed matter physics to material science. Traditionally, in an analog…

Quantum Physics · Physics 2020-09-18 Chufan Lyu , Victor Montenegro , Abolfazl Bayat

Due to an extremely rugged structure of the free energy landscape, the determination of spin-glass ground states is among the hardest known optimization problems, found to be NP-hard in the most general case. Owing to the specific structure…

Disordered Systems and Neural Networks · Physics 2011-11-10 Martin Weigel

We present a multi-reference configuration mixing scheme for describing ground and excited states, with well defined spin and space group symmetry quantum numbers, of the one-dimensional Hubbard model with nearest-neighbor hopping and…

Strongly Correlated Electrons · Physics 2013-06-28 R. Rodríguez-Guzmán , Carlos A. Jiménez-Hoyos , R. Schutski , Gustavo E. Scuseria

In this paper, we discuss information-theoretic tools for obtaining optimized coarse-grained molecular models for both equilibrium and non-equilibrium molecular dynamics. The latter are ubiquitous in physicochemical and biological…

Numerical Analysis · Mathematics 2016-04-20 Vagelis Harmandaris , Evangelia Kalligiannaki , Markos A. Katsoulakis , Petr Plecháč

The objective of this work is to examine the integrability of Hamiltonian systems in $2D$ spaces with variable curvature of certain types. Based on the differential Galois theory, we announce the necessary conditions of the integrability.…

Exactly Solvable and Integrable Systems · Physics 2026-02-26 Wojciech Szumiński , Adel A. Elmandouh

Within the framework of exact diagonalization (ED), we compute the ground state of Anderson impurity problem using the variational approach based on the configuration interaction (CI) expansion. We demonstrate that an accurate ground state…

Strongly Correlated Electrons · Physics 2013-07-19 Chungwei Lin , Alexander A. Demkov

A generalized version of the rotating-wave approximation for the single-mode spin-boson Hamiltonian is presented. It is shown that performing a simple change of basis prior to eliminating the off-resonant terms results in a significantly…

Quantum Physics · Physics 2009-11-13 E. K. Irish

An analytical variational method for the ground state of the biased quantum Rabi model in the ultra-strong coupling regime is presented. This analytical variational method can be obtained by a unitary transformation or alternatively by…

Quantum Physics · Physics 2019-04-23 Bin-Bin Mao , Maoxin Liu , Wei Wu , Liangsheng Li , Zu-Jian Ying , Hong-Gang Luo

Gradient matching is a promising tool for learning parameters and state dynamics of ordinary differential equations. It is a grid free inference approach, which, for fully observable systems is at times competitive with numerical…

Machine Learning · Statistics 2018-04-11 Nico S. Gorbach , Stefan Bauer , Joachim M. Buhmann

Based on Richardson's exact solution of the pairing model and the Gaudin model for spin systems we derive a new class of exactly solvable models for finite boson system. As an example we solve a particular hamiltonian which displays a…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 J. Dukelsky , P. Schuck

The n-vicinities method for approximate calculations of the partition function of a spin system was proposed previously. The equation of state was obtained in the most general form. In the present publication these results are adapted to…

Disordered Systems and Neural Networks · Physics 2016-06-30 Boris Kryzhanovsky , Leonid Litinskii

Besides perturbation theory (which clearly requires the knowledge of the exact unperturbed solution), variational techniques represent the main tool for any investigation of the eigenvalue problem of some semibounded operator H in quantum…

High Energy Physics - Phenomenology · Physics 2009-10-31 Wolfgang Lucha , Franz F. Schoberl

Hybrid quantum-classical embedding methods for correlated materials simulations provide a path towards potential quantum advantage. However, the required quantum resources arising from the multi-band nature of $d$ and $f$ electron materials…

Quantum Physics · Physics 2023-01-09 Anirban Mukherjee , Noah F. Berthusen , João C. Getelina , Peter P. Orth , Yong-Xin Yao

The physics of interacting integer-spin chains has been a topic of intense theoretical interest, particularly in the context of symmetry-protected topological phases. However, there has not been a controllable model system to study this…

Quantum Physics · Physics 2015-06-24 C. Senko , P. Richerme , J. Smith , A. Lee , I. Cohen , A. Retzker , C. Monroe