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The electronic band gap in conventional semiconductor materials, such as silicon, is fixed by the material's crystal structure and chemical composition. The gap defines the material's transport and optical properties and is of great…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Cheng Wang , Heidi Seinige , Gang Cao , Jian-Shi Zhou , John B. Goodenough , Maxim Tsoi

Two-dimensional silicon carbide stands out among 2D materials, primarily due to its notable band gap, unlike its carbon-based counterparts. However, the binary nature and non-layered structure of bulk SiC present challenges in fabricating…

Materials Science · Physics 2024-11-26 Arushi Singh , Vikram Mahamiya , Alok Shukla

Based on first-principles calculations, we predict that nitrogen atoms can assemble into a single-layer double kagome lattice (DKL), which possesses the characteristics of an intrinsic direct band gap semiconductor, boasting a substantial…

Materials Science · Physics 2023-11-02 Wenzhang Li , Qin He , Xiao-Ping Li , Da-Shuai Ma , Botao Fu

We study how the electronic structure of the bilayer graphene (BLG) is changed by electric field and strain from {\it ab initio} density-functional calculations using the LMTO and the LAPW methods. Both hexagonal and Bernal stacked…

Materials Science · Physics 2010-03-10 B. R. K. Nanda , S. Satpathy

The zero band gap (Eg) graphene becomes narrow Eg semiconductor when graphene is patterned with periodic array of hexagonal shaped antidots, the resultant is the hexagonal Graphene Antidot Lattice (hGAL). Based on the number of atomic…

Mesoscale and Nanoscale Physics · Physics 2013-01-11 Penchalaiah Palla , J. P. Raina

The elemental two-dimensional (2D) materials such as graphene, silicene, germanene, and black phosphorus have attracted considerable attention due to their fascinating physical properties. Structurally they possess the honeycomb or…

Materials Science · Physics 2016-05-18 Ping Li , Weidong Luo

Although many graphene derivatives have sizable band gaps, their electrical or mechanical properties are significantly degraded due to the low degree of {\pi}-conjugation. Besides the {\pi}-{\pi} conjugation, there exists hyperconjugation…

Materials Science · Physics 2019-12-06 Gui-Lin Zhu , Xiao-Juan Ye , Chun-Sheng Liu

The electronic structure of two-dimensional (2D) semiconductors can be significantly altered by screening effects, either from free charge carriers in the material itself, or by environmental screening from the surrounding medium. The…

We determine the electronic structure of a graphene sheet on top of a lattice-matched hexagonal boron nitride (h-BN) substrate using ab initio density functional calculations. The most stable configuration has one carbon atom on top of a…

Two-dimensional (2D) polyaniline sheet has been recently synthesized and showed that it is a semiconductor with indirect band gap. In this research, we examine electrical and mechanical properties of a fully hydrogenated 2D polyaniline…

Materials Science · Physics 2018-06-12 Meysam Bagheri Tagani

The shortcomings of mono-component systems, e.g., the gapless nature of graphene, the lack of air-stability in phosphorene, etc. have drawn great attention toward stacked materials expected to show interesting electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2020-12-24 Maryam Mahdavifar , Sima Shekarforoush , Farhad Khoeini

The light-like dispersion of graphene monolayer results in many novel electronic properties in it1, however, this gapless feature also limits the applications of graphene monolayer in digital electronics2. A rare working solution to…

Mesoscale and Nanoscale Physics · Physics 2016-09-02 Si-Yu Li , Mei Zhou , Jia-Bin Qiao , Wenhui Duan , Lin He

Orthorhombic arsenene was recently predicted as an indirect bandgap semiconductor. Here, we demonstrate that nanostructuring arsenene into nanoribbons can successfully transform the bandgap to be direct. It is found that direct bandgaps…

Mesoscale and Nanoscale Physics · Physics 2015-02-06 Z. Y. Zhang , H. N. Cao , J. C. Zhang , Y. H. Wang , D. S. Xue , M. S. Si

The search of new means of generating and controlling topological states of matter is at the front of many joint efforts, including bandgap engineering by doping and light-induced topological states. Most of our understading, however, is…

Mesoscale and Nanoscale Physics · Physics 2018-07-19 Hernan L. Calvo , Javier S. Luna , Virginia Dal Lago , Luis E. F. Foa Torres

We characterize the electronic structure and elasticity of monolayer transition-metal dichalcogenides MX2 (M=Mo, W, Sn, Hf and X=S, Se, Te) with 2H and 1T structures using fully relativistic first principles calculations based on density…

Materials Science · Physics 2015-06-18 David M. Guzman , Alejandro Strachan

Based on first-principles calculations we performed a systematic study of the energetic stability, structural characterization, and electronic properties of the fully oxidized $A_{2}B$, electrenes, with the following combinations, (i)…

Materials Science · Physics 2022-06-15 Pedro H. Souza , Danilo Kuritza , José E. Padilha , Roberto H. Miwa

In a very recent accomplishment, the two-dimensional form of Biphenylene network (BPN) has been successfully fabricated [Fan et al., Science, 372, 852-856 (2021)]. Motivated by this exciting experimental result on 2D layered BPN structure,…

Materials Science · Physics 2021-11-04 A. Bafekry , M. Faraji , M. M. Fadlallah , H. R. Jappor , S. Karbasizadeh , M. Ghergherehchi , D. Gogova

Silicene monolayers grown on Ag(111) surfaces demonstrate a band gap that is tunable by oxygen adatoms from semimetallic to semiconducting type. By using low-temperature scanning tunneling microscopy, it is found that the adsorption…

Band gap control by an external field is useful in various optical, infrared and THz applications. However, widely tunable band gaps are still not practical due to variety of reasons. Using the orthogonal tight-binding method for…

Mesoscale and Nanoscale Physics · Physics 2017-05-03 V. A. Saroka , K. G. Batrakov , V. A. Demin , L. A. Chernozatonskii

The electronic structure of finite-length armchair carbon nanotubes has been studied using several ab-initio and semi-empirical quantum computational techniques. The additional confinement of the electrons along the tube axis leads to the…

Materials Science · Physics 2007-05-23 Alain Rochefort , Dennis R. Salahub , Phaedon Avouris