Related papers: Supercritical Gr\"uneisen parameter and its univer…
We use the recently-proposed \emph{compressible cell} Ising-like model [Phys. Rev. Lett. \textbf{120}, 120603 (2018)] to estimate the ratio between thermal expansivity and specific heat (the Gr\"uneisen parameter $\Gamma$) in supercooled…
Recent research suggests that the supercritical state consists of liquidlike and gaslike states where particle dynamics and key system properties are qualitatively different. We report experimental evidence of the structural crossover in…
A hallmark of a thermodynamic phase transition is the qualitative change of system thermodynamic properties such as energy and heat capacity. On the other hand, no phase transition is thought to operate in the supercritical state of matter…
Since their discovery in 1822, supercritical fluids have been of enduring interest, and have started to be deployed in many important applications. Theoretical understanding of the supercritical state is lacking, and is seen to limit…
Supercritical fluids play a significant role in elucidating fundamental aspects of liquid matter under extreme conditions. They have been extensively studied at pressures and temperatures relevant to various industrial applications.…
The Gr\"uneisen ratio ($\Gamma$), i.e.\,the ratio of the linear thermal expansivity to the specific heat at constant pressure, quantifies the degree of anharmonicity of the potential governing the physical properties of a system. While…
A large and mostly unexplored part of the phase diagram lies above the critical point. The supercritical matter was traditionally believed to be physically homogeneous with no discernible differences between liquidlike and gaslike states.…
The Gr\"uneisen parameter ({\gamma}) is crucial for determining many thermal properties, including the anharmonic effect, thermostatistics, and equation of state (EOS) of materials. However, the isentropic adiabatic compression conditions…
We consider the behavior of the Gr\"{u}neisen parameter, the ratio between thermal expansion and specific heat, at pressure-tuned infinite-randomness quantum-critical points and in the associated quantum Griffiths phases. We find that the…
We have studied in detail the transition from gas-like to rigid liquid-like behaviour in supercritical $N_2$ at 300 K (2.4 $T_C$). Our study combines neutron diffraction and Raman spectroscopy with empirical potential structure refinement…
We consider the Grueneisen parameter and the magnetocaloric effect near a pressure and magnetic field controlled quantum critical point, respectively. Generically, the Grueneisen parameter (and the thermal expansion) displays a…
Thermal expansion data are used to study the uniaxial pressure dependence of the electronic/magnetic entropy of Ba(Fe1-xCox)2As2. Uniaxial pressure is found to be proportional to doping and, thus, also an appropriate tuning parameter in…
The Gr\"uneisen parameter, experimentally determined from the ratio of thermal expansion to specific heat, quantifies the pressure dependence of characteristic energy scales of matter. It is highly enhanced for Kondo lattice systems, whose…
Dusty plasmas represent a powerful playground to study the collective dynamics of strongly coupled systems with important interdisciplinary connections to condensed matter physics. Due to the pure Yukawa repulsive interaction between dust…
Universality aids consistent understanding of physical properties. This includes understanding the states of matter where a theory predicts how a property of a phase (solid, liquid, gas) changes with temperature or pressure. Here, we show…
Can liquid-like and gas-like states be distinguished beyond the critical point, where the liquid-gas phase transition no longer exists and conventionally only a single supercritical fluid phase is defined? Recent experiments and simulations…
In the framework of the van-der-Waals model, analytical expressions for the locus of extrema (ridges) for heat capacity, thermal expansion coefficient, compressibility, density fluctuation, and sound velocity in the supercritical region…
In the supercritical fluid (SCF) region, at temperatures and pressures above the critical point, the thermodynamic singularity separating liquids and gases no longer exists. Recent arguments based on thermodynamics and critical scalings…
A new dynamic line, the Frenkel line, has recently been proposed to separate the supercritical state into rigid-liquid and non-rigid gas-like uid. The location of Frenkel line on the phase diagram is unknown for real uids. Here, we map the…
We report experimental evidence for a crossover between a liquid-like state and a gas-like state in fluid methane (CH4). This crossover is observed in all of our experiments, up to 397 K temperature; 2.1 times the critical temperature of…