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This work constitutes a comprehensive and improved account of electronic-structure and mechanical properties of silicon-nitride (Si3N4) polymorphs via van Leeuwen and Baerends (LB) exchange-corrected local density approximation (LDA) that…

Materials Science · Physics 2017-09-11 Prashant Singh , Manoj K. Harbola , Duane D. Johnson

Insulating-metallic transition mediated by substitutional atoms is predicted in a series of two-dimensional carbon-based structures. Introducing Si atoms in selected sites of tetrahexcarbon [Carbon 137 (2018) 266] according to rational…

Materials Science · Physics 2022-02-16 Alejandro Lopez-Bezanilla , Peter B. Littlewood

Aiming to remedy the incorrect asymptotic behavior of conventional semilocal exchange-correlation (XC) density functionals for finite systems, we propose an asymptotic correction scheme, wherein an exchange density functional whose…

Chemical Physics · Physics 2013-05-17 Chi-Ruei Pan , Po-Tung Fang , Jeng-Da Chai

We report a series of calculations testing the predictions of the Tran-Blaha functional for the electronic structure and magnetic properties of condensed systems. We find a general improvement in the properties of semiconducting and…

Materials Science · Physics 2010-11-08 David J. Singh

In this work we use density functional theory (DFT) to investigate the influence of semi-local exchange and correlation effects on the electronic and optical properties of zinc oxide. We find that the inclusion of such effects using the…

Materials Science · Physics 2019-05-01 R. M. V. S. Almeida , A. L. da Rosa , J. S. de Almeida

The design of band-gap metamaterials, i.e., metamaterials with the capability to inhibit wave propagation of a specific frequency range, has numerous potential engineering applications, such as acoustic filters and vibration isolation…

Applied Physics · Physics 2024-07-17 Milan Jirásek , Martin Horák , Michal Šmejkal

A long range corrected range separated hybrid functional is developed based on the density matrix expansion (DME) based semilocal exchange hole with Lee-Yang-Parr (LYP) correlation. An extensive study involving the proposed range separated…

Materials Science · Physics 2017-09-05 Subrata Jana , Bikash Patra , Hemanadhan Myneni , Prasanjit Samal

For a set of ten crystalline materials (oxides and semiconductors), we compute the electronic band structures using the Tran-Blaha [Phys. Rev. Lett. 102, 226401 (2009)] (TB09) functional. The band widths and gaps are compared with those…

Following Hollins et al. [J. Phys.: Condens. Matter 29, 04LT01 (2017)], we invert the electronic ground state densities for various semiconducting and insulating solids calculated using several density functional approximations within the…

Chemical Physics · Physics 2025-11-05 Visagan Ravindran , Nikitas I. Gidopoulos , Stewart J. Clark

We formulate a spin-polarized van Leeuwen and Baerends (vLB) correction to the local density approximation (LDA) exchange potential [Phys. Rev. A 49, 2421 (1994)] that enforces the ionization potential (IP) theorem following Stein et al.…

Materials Science · Physics 2016-03-09 Prashant Singh , Manoj K. Harbola , M. Hemanadhan , Abhijit Mookerjee , D. D. Johnson

Self interaction error remains an impotrant problem in density functional theory. A number of approximations to exact exchange aimed to correct for this error while retainining computational efficiency had been suggested recently. We…

Chemical Physics · Physics 2012-01-31 Valentin V. Karasiev , Eduardo V. Ludeña , Artëm E. Masunov

The modern semilocal exchange potential is an accurate and efficient approximation to the exact exchange potential of density functional theory. We tried to combine it with the dynamical mean-field theory to derive a new first-principles…

Strongly Correlated Electrons · Physics 2016-09-09 Li Huang , Haiyan Lu

In this paper we consider two different geometry of quasi one-dimensional semiconductors and calculate their exchange-correlation induced bandgap renormalization (BGR) as a function of the electron-hole plasma density and quantum wire…

Strongly Correlated Electrons · Physics 2009-11-11 Kourosh Nozari , Mahyar Madadi

The exchange-correlation hole and potential of the homogeneous electron gas have been investigated within the random-phase approximation, employing the plasmon-pole approximation for the linear density response function. The angular…

Strongly Correlated Electrons · Physics 2023-04-12 K. Karlsson , F. Aryasetiawan

The construction of meta generalized gradient approximations based on the density matrix expansion (DME) is considered as one of the most accurate technique to design semilocal exchange energy functionals in two-dimensional density…

Materials Science · Physics 2018-05-09 Abhilash Patra , Subrata Jana , Prasanjit Samal

The objective of this paper is to use transfer functions to comprehend the formation of band gaps in locally resonant acoustic metamaterials. Identifying a recursive approach for any number of serially arranged locally resonant mass in mass…

Classical Physics · Physics 2017-09-27 H. Al Ba'ba'a , M. Nouh , T. Singh

We present a theoretical study of dispersion of states which form the bulk band-gap edges in the three-dimensional topological insulator Bi2Te3. Within density functional theory, we analyze the effect of atomic positions varying within the…

Materials Science · Physics 2015-06-17 I. A. Nechaev , E. V. Chulkov

Accurate band gap prediction in semiconductors is crucial for materials science and semiconductor technology advancements. This paper extends the Perdew-Burke-Ernzerhof (PBE) functional for a wide range of semiconductors, tackling the…

Materials Science · Physics 2024-08-01 Satadeep Bhattacharjee , Namitha Anna Koshi , Seung-Cheol Lee

Atomic effective pseudopotentials enable atomistic calculations at the level of accuracy of density functional theory for semiconductor nanostructures with up to fifty thousand atoms. Since they are directly derived from ab-initio…

Materials Science · Physics 2024-03-14 Surender Kumar , Hanh Bui , Gabriel Bester

Multi-subband plasmon (MSP) modes in heavily doped InAs/GaSb broken-gap quantum wells grown via molecular beam epitaxy (MBE) are investigated. An $8$-band $\vec{k} \cdot \vec{p}$ semiclassical model accurately predicts ellipsometric…