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One-electron reduced density matrices (1RDMs) from equation-of-motion (EOM) coupled-cluster with single and double excitations (CCSD) calculations are analyzed to assess their N-representability ({\em i.e.}, whether they are derivable from…

Chemical Physics · Physics 2023-07-14 Stephen H. Yuwono , A. Eugene DePrince

As a new approach to efficiently describe correlation effects in the relativistic quantum world we propose to consider reduced density matrix functional theory, where the key quantity is the first-order reduced density matrix (1-RDM). In…

Chemical Physics · Physics 2022-05-05 M. Rodríguez-Mayorga , K. J. H. Giesbertz , L. Visscher

Many applications of quantum simulation require to prepare and then characterize quantum states by performing an efficient partial tomography to estimate observables corresponding to $k$-body reduced density matrices ($k$-RDMs). For…

Quantum Physics · Physics 2020-09-24 Xavier Bonet-Monroig , Ryan Babbush , Thomas E. O'Brien

Nonnegative matrix factorization (NMF) has been widely studied in recent years due to its effectiveness in representing nonnegative data with parts-based representations. For NMF, a sparser solution implies better parts-based…

Machine Learning · Computer Science 2022-04-25 Chong Peng , Yiqun Zhang , Yongyong Chen , Zhao Kang , Chenglizhao Chen , Qiang Cheng

Reduced density matrices (RDMs) are fundamental in quantum information processing, allowing the computation of local observables, such as energy and correlation functions, without the exponential complexity of fully characterizing quantum…

Quantum Physics · Physics 2025-06-13 Zherui Jerry Wang , David Dechant , Yash J. Patel , Jordi Tura

The goal of supervised representation learning is to construct effective data representations for prediction. Among all the characteristics of an ideal nonparametric representation of high-dimensional complex data, sufficiency, low…

Machine Learning · Computer Science 2022-09-02 Jian Huang , Yuling Jiao , Xu Liao , Jin Liu , Zhou Yu

We proposed a distributed approximating functional method for efficiently describing the electronic dynamics in atoms and molecules in the presence of the Coulomb singularities, using the kernel of a grid representation derived by using the…

Computational Physics · Physics 2016-04-05 Zhigang Sun

The Random Batch Method (RBM) is an effective technique to reduce the computational complexity when solving certain stochastic differential problems (SDEs) involving interacting particles. It can transform the computational complexity from…

Numerical Analysis · Mathematics 2024-12-23 Yanshun Zhao , Jingrun Chen , Zhiwen Zhang

A procedure based on a Mixture Density Model for correcting experimental data for distortions due to finite resolution and limited detector acceptance is presented. Addressing the case that the solution is known to be non-negative, in the…

Data Analysis, Statistics and Probability · Physics 2015-03-09 Nikolai Gagunashvili

This work studies the linear approximation of high-dimensional dynamical systems using low-rank dynamic mode decomposition (DMD). Searching this approximation in a data-driven approach is formalised as attempting to solve a low-rank…

Machine Learning · Statistics 2021-08-23 Patrick Héas , Cédric Herzet

Molecular simulations generally require fermionic encoding in which fermion statistics are encoded into the qubit representation of the wave function. Recent calculations suggest that fermionic encoding of the wave function can be bypassed,…

Quantum Physics · Physics 2022-04-18 David A. Mazziotti , Scott E. Smart , Alexander R. Mazziotti

This paper is presented to give numerical solutions of some cases of nonlinear wave-like equations with variable coefficients by using Reduced Differential Transform Method (RDTM). RDTM can be applied most of the physical, engineering,…

Numerical Analysis · Mathematics 2014-07-21 Murat Gubes , Yildiray Keskin , Galip Oturanc

The $\Delta$NO two-electron density matrix (2-RDM) and energy expression are derived from a multideterminantal wave function. The approximate $\Delta$NO 2-RDM is combined with an on-top density functional and a double-counting correction to…

Chemical Physics · Physics 2022-03-14 Ismael A. Elayan , Rishabh Gupta , Joshua W. Hollett

An active space variational calculation of the 2-electron reduced density matrix (2-RDM) is derived and implemented where the active orbitals are correlated within the pair approximation. The pair approximation considers only doubly…

Chemical Physics · Physics 2020-10-13 Kade Head-Marsden , David A. Mazziotti

We propose a novel algorithm based on inexact GMRES methods for linear response calculations in density functional theory. Such calculations require iteratively solving a nested linear problem $\mathcal{E} \delta\rho = b$ to obtain the…

Numerical Analysis · Mathematics 2025-10-30 Michael F. Herbst , Bonan Sun

Rank minimization methods have attracted considerable interest in various areas, such as computer vision and machine learning. The most representative work is nuclear norm minimization (NNM), which can recover the matrix rank exactly under…

Computer Vision and Pattern Recognition · Computer Science 2018-07-20 Zhiyuan Zha , Xin Yuan , Bei Li , Xinggan Zhang , Xin Liu , Lan Tang , Ying-Chang Liang

In this paper, we examine the problem of approximating a general linear dimensionality reduction (LDR) operator, represented as a matrix $A \in \mathbb{R}^{m \times n}$ with $m < n$, by a partial circulant matrix with rows related by…

Machine Learning · Statistics 2015-02-26 Swayambhoo Jain , Jarvis Haupt

With the rapid growth of neuroimaging technologies, a great effort has been dedicated recently to investigate the dynamic changes in brain activity. Examples include time course calcium imaging and dynamic brain functional connectivity. In…

Methodology · Statistics 2020-08-31 Wei Hu , Tianyu Pan , Dehan Kong , Weining Shen

We discuss how semidefinite programming can be used to determine the second-order density matrix directly through a variational optimization. We show how the problem of characterizing a physical or N -representable density matrix leads to…

Computational Physics · Physics 2011-10-27 Brecht Verstichel , Helen van Aggelen , Dimitri Van Neck , Paul W. Ayers , Patrick Bultinck

In this paper, we investigate the matrix estimation problem in the multi-response regression model with measurement errors. A nonconvex error-corrected estimator based on a combination of the amended loss function and the nuclear norm…

Statistics Theory · Mathematics 2022-09-19 Xin Li , Dongya Wu