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The study of Mayer's cluster expansion (CE) for the partition function demonstrates a possible way to resolve the problem of the CE non-physical behavior at condensed states of fluids. In particular, a general equation of state is derived…

Statistical Mechanics · Physics 2018-10-03 M. V. Ushcats , S. Yu. Ushcats , L. A. Bulavin , V. M. Sysoev

In contrast to the gaseous and the solid states, the liquid state does not have a simple model that could be developed into a quantitative theory. A central issue in the understanding of liquids is to estimate the energy state of liquids.…

Soft Condensed Matter · Physics 2017-03-09 Lianwen Wang

The equation of state of a hard sphere fluid at high density should exhibit a simple pole at the random close packing limit. Here we show that trying to obtain a compact semi-empirical equation of state simultaneously compatible with that…

Soft Condensed Matter · Physics 2019-08-14 Richard Bonneville

The question of whether the known virial coefficients are enough to determine the packing fraction $\eta_\infty$ at which the fluid equation of state of a hard-sphere fluid diverges is addressed. It is found that the information derived…

Statistical Mechanics · Physics 2011-02-25 Miguel Ángel G. Maestre , Andrés Santos , Miguel Robles , Mariano López de Haro

We consider a system of nonlinear partial differential equations describing the motion of an incompressible chemically reacting generalized Newtonian fluid in three space dimensions. The governing system consists of a steady…

Numerical Analysis · Mathematics 2017-08-29 Seungchan Ko , Endre Suli

A new method of estimating high-order virial coefficients for fluids composed of equal three-dimensional rigid spheres is proposed. The predicted $B_{11}$ and $B_{12}$ values are in good agreement with reliable estimates previously…

Statistical Mechanics · Physics 2014-03-07 C. C. F. Florindo , A. B. M. S. Bassi

The virial expansion method is applied within a harmonic approximation to an interacting N-body system of identical fermions. We compute the canonical partition functions for two and three particles to get the two lowest orders in the…

Statistical Mechanics · Physics 2012-12-27 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

The description of a stellar system as a continuous fluid represents a convenient first approximation to stellar dynamics, and its derivation from the kinetic theory is standard. The challenge lies in providing adequate closure…

Astrophysics · Physics 2007-05-23 Edward A. Spiegel , Jean-Luc Thiffeault

Following the work of Leutheusser [Physica A 127, 667 (1984)], the solution to the Percus-Yevick equation for a seven-dimensional hard-sphere fluid is explicitly found. This allows the derivation of the equation of state for the fluid…

Statistical Mechanics · Physics 2015-06-29 M. Robles , M. Lopez de Haro , A. Santos

We characterize a system of hard spheres with a simple collision rule that breaks time reversal symmetry, but conserves energy. The collisions lead to an a-chiral, isotropic, and homogeneous stationary state, whose properties are determined…

Statistical Mechanics · Physics 2022-09-21 Niklas Grimm , Annette Zippelius , Matthias Fuchs

The composition-independent virial coefficients of a $d$-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture [Santos, A., Yuste, S. B., and L\'opez de Haro,…

Statistical Mechanics · Physics 2007-05-23 A. Santos , S. B. Yuste , M. López de Haro

In this paper, we consider numerical approximations of a binary fluid-surfactant phase-field model coupled with the fluid flow, in which the system is highly nonlinear that couples the incompressible Navier-Stokes equations and two…

Numerical Analysis · Mathematics 2018-04-13 Xiaofeng Yang

A new approach to thermodynamics of simple fluids is presented. The partition function is first expressed in the reciprocal space, it is argued that the links (p,q) between 2 molecules can reasonably in the thermodynamical limit be…

General Physics · Physics 2020-03-03 Richard Bonneville

We investigate the convective cooling of a fluid with a quadratic equation of state by performing three-dimensional direct numerical simulations of a flow with a fixed top-boundary temperature, which is lower than the initial fluid…

Fluid Dynamics · Physics 2021-07-01 Jason Olsthoorn , Edmund W. Tedford , Gregory A. Lawrence

An alternative to the well-known complete form of the Mie-Gr\"uneisen equation of state (EOS) for water is suggested. A closed analytical description of the self-consistent EOS for an arbitrary medium based only on the first law of…

Fluid Dynamics · Physics 2023-05-02 Sergey G. Chefranov

An alternative representation of an exact statistical field theory for simple fluids, based on the method of collective variables, is presented. The results obtained are examined from the point of another version of theory that was…

Statistical Mechanics · Physics 2009-11-11 Jean-Michel Caillol , Oksana Patsahan , Ihor Mryglod

We study periodic solutions to the Navier-Stokes equations. The transition phase of a dynamic Navier-Stokes solution to the periodic-in-time state can be excessively long and it depends on parameters like the domain size and the viscosity.…

Numerical Analysis · Mathematics 2019-12-30 Thomas Richter

The merits of different analytical equations of state for the hard-sphere system with respect to the recently computed high-accuracy value of the freezing-point packing fraction are assessed. It is found that the Carnahan-Starling-Kolafa…

Soft Condensed Matter · Physics 2014-04-08 Miguel Robles , Mariano López de Haro , Andrés Santos

In this note, we propose a simple derivation of the one dimensional hard rod equation of state, with and without a Kac tail (appended long range and weak potential). The case of hard spheres in higher dimension is also addressed and it is…

Statistical Mechanics · Physics 2009-11-13 E. Trizac , I. Pagonabarraga

We use video microscopy to study a two-dimensional (2D) model fluid of charged colloidal particles suspended in water and compute the pressure from the measured particle configurations. Direct experimental control over the particle density…

Soft Condensed Matter · Physics 2009-11-10 M. Brunner , C. Bechinger , U. Herz , H. H. von Grunberg