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A general method is presented for modeling high entropy alloys as ensembles of randomly sampled, ordered configurations on a given lattice. Statistical mechanics is applied post hoc to derive the ensemble properties as a function of…

Materials Science · Physics 2022-11-24 Andrew Novick , Quan Nguyen , Roman Garnett , Eric Toberer , Vladan Stevanović

The design of corrosion-resistant high entropy alloys (CR-HEAs) is challenging due to the alloys' virtually astrological composition space. To facilitate this, efficient and reliable high-throughput exploratory approaches are needed. Toward…

Materials Science · Physics 2021-04-22 Thien Duong , Yafei Wang , Xiaoli Yan , Adrien Couet , Santanu Chaudhuri

It has been shown that oxide ceramics containing multiple transition and/or rare-earth elements in equimolar ratios have a strong tendency to crystallize in simple single phase structures, stabilized by the high configurational entropy. In…

Materials Science · Physics 2019-03-27 Ralf Witte , Abhishek Sarkar , Robert Kruk , Benedikt Eggert , Richard A. Brand , Heiko Wende , Horst Hahn

High entropy alloys (HEAs) are a class of novel materials that exhibit superb engineering properties. It has been demonstrated by extensive experiments and first principles/atomistic simulations that short-range order in the atomic level…

Materials Science · Physics 2022-05-17 Yahong Yang , Luchan Zhang , Yang Xiang

The development of alloys that are hydrogenated and dehydrogenated quickly and actively at room temperature is a challenge for the safe and compact storage of hydrogen. In this study, a new high-entropy alloy (HEA) with AB-type…

Materials Science · Physics 2024-02-20 Shivam Dangwal , Kaveh Edalati

Crystals with low latent heat are predicted to melt from an entropically stabilized body-centered cubic symmetry. At this weakly first-order transition, strongly correlated fluctuations are expected to emerge, which could change the nature…

Soft Condensed Matter · Physics 2017-02-28 Joris Sprakel , Alessio Zaccone , Frans Spaepen , Peter Schall , David A. Weitz

Recently, high entropy alloys (HEAs) have emerged as a new platform for discovering superconducting materials and offer avenues to explore exotic superconductivity. The highly disordered nature of HEA suggests regular phonon required for…

Superconductivity · Physics 2021-09-29 Kapil Motla , Arushi , P. K. Meena , D. Singh , P. K. Biswas , A. D. Hillier , R. P. Singh

High-entropy-alloy (HEA) superconductors are a new class of disordered superconductors. In this study, we investigate the robustness of superconducting states in HEA-type metal telluride (MTe; M = Ag, In, Sn, Pb, Bi) under high pressure.…

The configurational entropy of several H-disordered ice polymorphs is calculated by means of a thermodynamic integration along a path between a totally H-disordered state and one fulfilling the Bernal-Fowler ice rules. A Monte Carlo…

Chemical Physics · Physics 2014-06-24 Carlos P. Herrero , Rafael Ramirez

The classic metallurgical systems -- noble metal alloys -- that have formed the benchmark for various alloy theories, are revisited. First-principles fully relaxed general potential LAPW total energies of a few ordered structures are used…

Materials Science · Physics 2009-10-30 V. Ozolins , C. Wolverton , A. Zunger

The successful synthesis of high entropy alloy (HEA) nanoparticles, a long-sought goal in materials science, opens a new frontier in materials science with applications across catalysis, electronics, structural alloys, and energetic…

Materials Science · Physics 2021-05-27 Wissam A. Saidi , Waseem Shadid , Götz Veser

Liquid metals at extreme pressures and temperatures are widely interested in the high-pressure community. Based on density functional theory molecular dynamics, we conduct first-principles investigations on the equation of state (EOS) and…

Materials Science · Physics 2020-11-06 Shuai Zhang , Miguel A. Morales

Refractory high-entropy alloys, RHEAs, are promising high-temperature structural materials. Their large compositional space poses great design challenges for phase control and high strength-ductility synergy. The present research pioneers…

Materials Science · Physics 2023-12-11 Jie Qi , Xuesong Fan , Diego Ibarra Hoyos , Michael Widom , Peter K. Liaw , Joseph Poon

High-entropy alloys (HEAs) based on tungsten (W) have emerged as promising candidates for plasma-facing components in future fusion reactors, owing to their excellent irradiation resistance. In this study, we construct an efficient…

Materials Science · Physics 2025-07-17 Jiahui Liu , Jesper Byggmastar , Zheyong Fan , Bing Bai , Ping Qian , Yanjing Su

The equation of state (EOS) of alloys at high pressures is generalized with the cluster expansion method. It is shown that this provides a more accurate description. The low temperature EOSs of Ni-Al alloys on FCC and BCC lattices are…

Materials Science · Physics 2012-03-06 H. Y. Geng , N. X. Chen , M. H. F. Sluiter

Cubic A15-type superconducting alloys continue to fascinate the academic and industrial fields because they mainly support the largest market for low-temperature superconducting applications and show exotic physical properties.…

Superconductivity · Physics 2026-03-02 Yucheng Li , Kuan Li , Lingyong Zeng , Rui Chen , Jingjun Qin , Shuangyue Wang , Huixia Luo

Precipitation in Mg-Zn alloys was analyzed by means of first principles calculations. Formation energies of symmetrically distinct hcp Mg1-xZnx (0 < x < 1) configurations were determined and potential candidates for Guinier-Preston zones…

Materials Science · Physics 2020-10-07 S. Liu , G. Esteban-Manzanares , J. LLorca

High-entropy alloys (HEAs) are an intriguing new class of metallic materials due to their unique mechanical behavior. Achieving a detailed understanding of structure-property relationships in these materials has been challenged by the…

Materials Science · Physics 2018-10-24 Jun Ding , Qin Yu , Mark Asta , Robert O. Ritchie

High-entropy oxide (HEO) thermodynamics transcend temperature-centric approaches, spanning a multidimensional landscape where oxygen chemical potential plays a decisive role. Here, we experimentally demonstrate how controlling the oxygen…

Two new refractory amorphous high-entropy alloys (RAHEAs) within the W--Ta--Cr--V and W--Ta--Cr--V--Hf systems were herein synthesized using magnetron-sputtering and tested under high-temperature annealing and displacing irradiation using…

Materials Science · Physics 2023-03-27 Matheus A. Tunes , Hi T. Vo , Jon K. S. Baldwin , Tarik A. Saleh , Saryu J. Fensin , Osman El-Atwani