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We compare Monte Carlo simulations of knotted and unknotted polymers whose ends are connected to two parallel walls. The force $f$ exerted on the polymer is measured as a function of the separation $R$ between the walls. For unknotted…

Statistical Mechanics · Physics 2009-11-07 Oded Farago , Yacov Kantor , Mehran Kardar

The depletion interaction between two parallel repulsive walls confining a dilute solution of long and flexible polymer chains is studied by field-theoretic methods. Special attention is paid to self-avoidance between chain monomers…

Soft Condensed Matter · Physics 2009-11-07 F. Schlesener , A. Hanke , R. Klimpel , S. Dietrich

We present an approach to studying directed polymers in interaction with a defect line and subject to a force, which pulls them away from the line. We consider in particular the case of inhomogeneous interactions. We first give a formula…

Disordered Systems and Neural Networks · Physics 2009-11-11 G. Giacomin , F. L. Toninelli

Based on transfer matrix techniques and finite size scaling, we study the oriented polymer (self-avoiding walk) with nearest neighbor interaction. In the repulsive regime, various critical exponents are computed and compared with exact…

Condensed Matter · Physics 2009-10-22 W. M. Koo

Frontal polymerization is a promising energy-saving method for rapid fabrication of polymer components with good mechanical properties. In these systems, a small energy input is sufficient to convert monomers, from a liquid or soft solid…

Soft Condensed Matter · Physics 2023-10-04 Xuanhe Li , Tal Cohen

We study theoretically the temporal evolution and the spatial structure of the interface between two polymer melts involving three different species (A, A* and B). The first melt is composed of two different polymer species A and A* which…

Soft Condensed Matter · Physics 2009-11-10 A. Aradian , F. Saulnier , E. Raphael , P. -G. de Gennes

While the large majority of theoretical and numerical studies of the jamming transition consider athermal packings of purely repulsive spheres, real complex fluids and soft solids generically display attraction between particles. By…

Soft Condensed Matter · Physics 2018-11-07 Dion J. Koeze , Brian P. Tighe

An infinite hierarchy of layering transitions exists for model polymers in solution under poor solvent or low temperatures and near an attractive surface. A flat histogram stochastic growth algorithm known as FlatPERM has been used on a…

Statistical Mechanics · Physics 2009-11-10 J. Krawczyk , A. L. Owczarek , T. Prellberg , A. Rechnitzer

We analyse the conformational behaviour of a linear semiflexible homo-polymer chain confined by two geometrical constraints under a good solvent condition in two dimensions. The constraints are stair shaped impenetrable surfaces. The…

Soft Condensed Matter · Physics 2014-07-14 Pramod Kumar Mishra

The surface tension, the adsorption, and the depletion thickness of polymers close to a single nonadsorbing colloidal sphere are computed by means of Monte Carlo simulations. We consider polymers under good-solvent conditions and in the…

Soft Condensed Matter · Physics 2014-05-06 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

The temperature dependence of the hydrodynamic boundary condition between a PDMS melt and two different non-attractive surfaces made of either an OTS (octadecyltrichlorosilane) self-assembled monolayer (SAM) or a grafted layer of short PDMS…

Experiments with polymer latex solutions show the coexistence of order-disorder structures of macroions. Because of the large macroions' sizes, this order-disorder phase coexistence imply the existence of very long-range attractive and…

Soft Condensed Matter · Physics 2019-02-20 Alfredo González-Calderón , Enrique González-Tovar , Marcelo Lozada-Cassou

Predicting the large-amplitude deformations of thin elastic sheets is difficult due to the complications of self-contact, geometric nonlinearities, and a multitude of low-lying energy states. We study a simple two-dimensional setting where…

Exact bounds are obtained for the quenched free energy of a polymer with random hydrophobicities in the presence of an interface separating a polar from a non polar solvent. The polymer may be ideal or have steric self-interactions. The…

Statistical Mechanics · Physics 2007-05-23 A. Maritan , M. P. Riva , A. Trovato

Understanding and computing the entropic forces exerted by polymer chains under confinement is important for many reasons, from research to applications. However, extracting properties related to the free energy, such as the force (or…

Soft Condensed Matter · Physics 2025-07-08 Marcio S. Gomes-Filho , Eugene M. Terentjev

By tracking small particles in the bulk of an intensely turbulent flow, we show that even a very small concentration of long-chain polymers disrupts the usual turbulent energy cascade. The polymers affect scales much larger than their…

Fluid Dynamics · Physics 2007-12-31 Nicholas T. Ouellette , Haitao Xu , Eberhard Bodenschatz

It is assumed that the primary interaction between two masses m1 and m2 is not attractive as postulated by Newton's law of gravitation, but repulsive. Both m1 and m2 emit and absorb gravitational radiation. Corresponding to the laws of…

General Physics · Physics 2008-02-03 Johann Albers

Particles embedded in a fluctuating interface experience forces and torques mediated by the deformations and by the thermal fluctuations of the medium. Considering a system of two cylinders bound to a fluid membrane we show that the…

Soft Condensed Matter · Physics 2011-05-31 Pierre Gosselin , Hervé Mohrbach , Martin Michael Müller

We address the response of a random heteropolymer to preferential solvation of certain monomer types at the globule-solvent interface. For each set of monomers that can comprise the molecule's surface, we represent the ensemble of allowed…

Soft Condensed Matter · Physics 2009-11-10 Philip Geissler , Eugene Shakhnovich , Alexander Grosberg

We study a model of two polymers confined to a slit with sticky walls. More precisely, we find and analyse the exact solution of two directed friendly walks in such a geometry on the square lattice. We compare the infinite slit limit, in…

Statistical Mechanics · Physics 2015-06-19 Thomas Wong , Aleksander L. Owczarek , Andrew Rechnitzer