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Sulfur is the tenth most abundant element in the universe and is known to play a significant role in biological systems. Accordingly, in recent years there has been increased interest in the role of sulfur in astrochemical reactions and…
This work aims to study the unexplained sulfur depletion observed toward dense clouds and protostars. We made simulation experiments of the UV-photoprocessing and sublimation of H2S and H2S:H2O ice in dense clouds and circumstellar regions,…
The sulfur content in dense molecular regions of the interstellar medium is highly depleted in comparison to diffuse clouds. The reason of this phenomenon is unclear, thus it is necessary to carry out observational studies of sulfur-bearing…
In this work, we reexamine sulfur chemistry occurring on and in the ice mantles of interstellar dust grains, and report the effects of two new modifications to standard astrochemical models; namely, (a) the incorporation of cosmic…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…
Hydrogen sulfide (H2S) is thought to be an important sulfur reservoir in interstellar ices. It serves as a key precursor to complex sulfur-bearing organics, and has been proposed to play a significant role in the origin of life. Although…
Sulfur has been observed to be severely depleted in dense clouds leading to uncertainty in the molecules that contain it and the chemistry behind their evolution. Here, we aim to shed light on the sulfur chemistry in young stellar objects…
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and…
Sulfur-bearing molecules are commonly detected in dense cores within star-forming regions, but the total sulfur budget is significantly low, when compared to the interstellar medium (ISM) value. The properties of sulfur-bearing molecules…
Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…
A fraction of the missing sulfur in dense clouds and circumstellar regions could be in the form of three species not yet de- tected in the interstellar medium: H2S2, HS2, and S2 according to experimental simulations performed under…
Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…
The elemental depletion of interstellar sulfur from the gas phase has been a recurring challenge for astrochemical models. Observations show that sulfur remains relatively non-depleted with respect to its cosmic value throughout the diffuse…
JWST has revealed sulfur chemistry in giant exoplanet atmospheres, where molecules such as SO2 trace photochemistry, metallicity, and formation and migration. To ascertain the conditions that determine whether (or how much) SO2, H2S, and…
The abundance of volatile sulfur in dense clouds is long-standing problem in studies of the physics and chemistry of star-forming regions. Sulfur is an important species because its low ionization potential may possibly make it an important…
Sulfur appears to be depleted by an order of magnitude or more from its elemental abundance in star-forming regions. In the last few years, numerous observations and experiments have been performed in order to to understand the reasons…
Io's intense volcanic activity results in one of the most colorful surfaces in the solar system. Ultraviolet and visible-wavelength observations of Io are critical to uncovering the chemistry behind its volcanic hues. Here, we present…
Sulfur is a critical element to life on Earth, and with detections of sulfur-bearing molecules in exoplanets and comets, questions arise as to how sulfur is incorporated into planets in the first place. In order to understand sulfur's…
Observations of JWST have revealed that several close-in exoplanets have sulfur-rich atmospheres through SO$_2$ detections. Atmospheric sulfur is often thought to originate from solid accretion during planet formation, whereas recent…
The astrochemistry of CO2 ice analogues has been a topic of intensive investigation due to the prevalence of CO2 throughout the interstellar medium and the Solar System, as well as the possibility of it acting as a carbon feedstock for the…