Related papers: Detection of Buckminsterfullerene emission in the …
We present the detection of fullerenes C60 and C70 in the star-forming region IC 348 of the Perseus molecular cloud. Mid-IR vibrational transitions of C60 and C70 in emission are found in Spitzer IRS spectra of individual stars (LRLL 1, 2,…
The C60 molecule has been recently detected in a wide range of astrophysical environments through its four active intramolecular vibrational modes (T1u) near 18.9, 17.4, 8.5, and 7.0 microns. The strengths of the mid-infrared emission bands…
Recently, the presence of fullerenes in the interstellar medium (ISM) has been confirmed especially with the first confirmed identification of two strong diffuse interstellar bands (DIBs) with C60+. This justifies reassesing the importance…
Since the first laboratory synthesis of C$_{60}$ in 1985, fullerene-related species have been proposed to interpret various astronomical features. After more than 25 years' efforts, several circumstellar and interstellar features have been…
Fullerenes are a particularly stable class of carbon molecules in the shape of a hollow sphere or ellipsoid that might be formed in the outflows of carbon stars. Once injected into the interstellar medium (ISM), these stable species survive…
We present seeing-limited narrow-band mid-IR GTC/CanariCam images of the spatially extended fullerene-containing planetary nebula (PN) IC 418. The narrow-band images cover the C60 fullerene band at 17.4 {\mu}m, the polycyclic aromatic…
Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red.…
One of the keys to interpreting the character and evolution of interstellar matter in the galaxy is understanding the distribution of the low density hot (10^5 K -10^6 K) phase of the interstellar medium (ISM). This phase is much more…
We search high-resolution and high-quality VLT/UVES optical spectra of the hot R Coronae Borealis (RCB) star DY Cen for electronic transitions of the C60 molecule and diffuse interstellar bands (DIBs). We report the non-detection of the…
Context. Insight into the conditions that drive the physics and chemistry in interstellar clouds is gained from determining the abundance and charge state of their components. Aims. We propose an evaluation of the C60:C60+ ratio in diffuse…
Buckminsterfullerene (C60) was recently confirmed to be the largest molecule identified in space. However, it remains unclear how, and where this molecule is formed. It is generally believed that C60 is formed from the build up of small…
Detections of C60 and C70 fullerenes in planetary nebulae (PNe) of the Magellanic Clouds and of our own Galaxy have raised the idea that other forms of carbon such as hydrogenated fullerenes (fulleranes like C60H36 and C60H18), buckyonions,…
A debate persists regarding the correlation between the DIBs 9577 and 9632 \r{A}, and whether they share a common molecular carrier (i.e., C$_{60}^{+}$). A robust high correlation determination emerges after bridging the baseline across an…
Small metal-containing molecules have been detected and recognized as one of the hybrid species efficiently formed in space; especially in the circumstellar envelopes of evolved stars. It has been predicted also that more complex hybrid…
We study, for the first time, the relations of two strong diffuse bands (DIBs) at 9633 and 9577~\AA, commonly attributed to C$_{60}^+$, to other interstellar features seen in optical and UV spectra including H{\sc i}, Ca{\sc i}, Fe{\sc ii},…
Using the Mid-Infrared Spectrometer on board the Infrared Telescope in Space and the low-resolution grating spectrometer (PHT-S) on board the Infrared Space Observatory, we obtained 820 mid-infrared (5 to 12 $\mu$m) spectra of the diffuse…
We study the rotation rates and electric dipole emission of hydrogenated icosahedral fullerenes (single and multishell) in various phases of the interstellar medium. Using the formalism of Draine and Lazarian for the rotational dynamics of…
We compare and analyze the Spitzer mid-infrared spectrum of three fullerene-rich planetary nebulae in the Milky Way and the Magellanic Clouds; Tc1, SMP SMC16, and SMP LMC56. The three planetary nebulae share many spectroscopic similarities.…
We have observed that C$_{60}^+$ ions isolated in cryogenic matrixes show pronounced near-IR photoluminescence upon excitation in the near-IR range. By contrast UV photoexcitation does not lead to measurable luminescence. After the recent…
The Diffuse Interstellar Bands (DIBs) are absorption features seen in the spectra of astronomical objects, that arise in the interstellar medium. Today more than 500 DIBs have been observed mostly in the optical and near-infrared…