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In transition-metal compounds with partially filled $4d$ and $5d$ shells spin-orbit entanglement, electronic correlations, and crystal-field effects conspire to give rise to a variety of novel forms of topological quantum matter. This…

Strongly Correlated Electrons · Physics 2017-01-26 Simon Trebst

Nearly two decades ago, Alexei Kitaev proposed a model for spin-$1/2$ particles with bond-directional interactions on a two-dimensional honeycomb lattice which had the potential to host a quantum spin-liquid ground state. This work…

Materials Science · Physics 2022-01-19 Faranak Bahrami , Mykola Abramchuk , Oleg I. Lebedev , Fazel Tafti

A decade ago, Alexei Kitaev proposed an exactly solvable $S$ = 1/2 model on a two-dimensional honeycomb lattice, where the spins fractionalize into Majorana fermions and form a topological quantum spin liquid (QSL) in the ground state. It…

Strongly Correlated Electrons · Physics 2022-01-21 Hidenori Takagi , Tomohiro Takayama , George Jackeli , Giniyat Khaliullin , Stephen E. Nagler

A range of honeycomb-lattice compounds has been proposed and investigated in the search for a topological Kitaev spin liquid. However, sizable Heisenberg interactions and additional symmetry-allowed exchange anisotropies in the magnetic…

Strongly Correlated Electrons · Physics 2018-10-18 Ravi Yadav , Stephan Rachel , Liviu Hozoi , Jeroen van den Brink , George Jackeli

Compounds of transition metal ions with strong spin-orbit coupling recently attracted attention due to the possibility to host frustrated bond-dependent anisotropic magnetic interactions. In general, such interactions lead to complex phase…

Strongly Correlated Electrons · Physics 2019-02-21 Juraj Rusnačko , Dorota Gotfryd , Jiří Chaloupka

There have been substantial recent efforts, both experimentally and theoretically, to find a material realization of the Kitaev spin-liquid--the ground state of the exactly solvable Kitaev model on the honeycomb lattice. Candidate materials…

Strongly Correlated Electrons · Physics 2023-07-12 Tessa Cookmeyer , Joel E. Moore

Fifteen years since its inception, the Kitaev model still boasts only a narrow group of material realizations. We review the progress in studying and understanding one of them, lithium iridate Li$_2$IrO$_3$ available in three polymorphs…

Strongly Correlated Electrons · Physics 2022-05-16 Alexander A. Tsirlin , Philipp Gegenwart

In this study, we reanalyze the magnetic interactions in the Kitaev spin liquid candidate materials Na$_2$IrO$_3$, $\alpha$-RuCl$_3$, and $\alpha$-Li$_2$IrO$_3$ using nonperturbative exact diagonalization methods. These methods are more…

Strongly Correlated Electrons · Physics 2016-07-06 Stephen M. Winter , Ying Li , Harald O. Jeschke , Roser Valenti

The Kitaev spin liquid, a ground state of the bond-dependent Kitaev model in a honeycomb lattice has been a centre of attraction, since a microscopic theory to realize such an interaction in solid-state materials was discovered. A challenge…

Strongly Correlated Electrons · Physics 2022-05-20 Jiefu Cen , Hae-Young Kee

The recently discovered three-dimensional hyperhoneycomb iridate, $\beta$-Li$_2$IrO$_3$, has raised hopes for the realization of dominant Kitaev interaction between spin-orbit entangled local moments due to its near-ideal lattice structure.…

Strongly Correlated Electrons · Physics 2016-01-15 Heung-Sik Kim , Eric Kin-Ho Lee , Yong Baek Kim

Kitaev's honeycomb spin-liquid model and its proposed realization in materials such as $\alpha$-RuCl$_3$, Li$_2$IrO$_3$ and Na$_2$IrO$_3$ continue to present open questions about how the dynamics of a spin-liquid are modified in the…

Strongly Correlated Electrons · Physics 2020-02-12 R. Sarkar , Z. Mei , A. Ruiz , G. Lopez , H. -H. Klauss , J. G. Analytis , I. Kimchi , N. J. Curro

Recently, realizations of Kitaev physics have been sought in the A2IrO3 family of honeycomb iridates, originating from oxygen-mediated exchange through edge-shared octahedra. However, for the j = 1/2 Mott insulator in these materials…

Strongly Correlated Electrons · Physics 2014-03-18 Jeffrey G. Rau , Eric Kin-Ho Lee , Hae-Young Kee

The search for a Kitaev quantum spin liquid in crystalline magnetic materials has fueled intense interest in the two-dimensional honeycomb systems. Many promising candidate Kitaev systems are characterized by a long range ordered magnetic…

Strongly Correlated Electrons · Physics 2024-10-16 V. Ovidiu Garlea , Colin L. Sarkis

We explore the potential experimental realization of the mixed-spin Kitaev model in materials such as Zr$_{0.5}$Ru$_{0.5}$Cl$_3$, where spin-1/2 and spin-3/2 ions occupy distinct sublattices of a honeycomb lattice. By developing a…

Strongly Correlated Electrons · Physics 2025-05-09 Willian Natori , Yang Yang , Hui-Ke Jin , Johannes Knolle , Natalia B. Perkins

Magnetic moments arranged at the corners of a honeycomb lattice are predicted to form a novel state of matter, Kitaev quantum spin liquid, under the influence of frustration effects between bond-dependent Ising interactions. Some layered…

Strongly Correlated Electrons · Physics 2022-03-09 Sean K. Takahashi , Jiaming Wang , Alexandre Arsenault , Mykola Abramchuk , Fazel Tafti , Philip M. Singer , Takashi Imai

Na$_2$IrO$_3$, a honeycomb 5$d^5$ oxide, has been recently identified as a potential realization of the Kitaev spin lattice. The basic feature of this spin model is that for each of the three metal-metal links emerging out of a metal site,…

Kitaev's honeycomb lattice spin model is a remarkable exactly solvable model, which has a particular type of spin liquid (Kitaev spin liquid) as the ground state. Although its possible realization in iridates and $\alpha$-RuCl$_3$ has been…

Strongly Correlated Electrons · Physics 2017-08-07 Masahiko G. Yamada , Hiroyuki Fujita , Masaki Oshikawa

Kitaev materials are promising materials for hosting quantum spin liquids and investigating the interplay of topological and symmetry-breaking phases. We use an unsupervised and interpretable machine-learning method, the tensorial-kernel…

Strongly Correlated Electrons · Physics 2021-04-06 Ke Liu , Nicolas Sadoune , Nihal Rao , Jonas Greitemann , Lode Pollet

Quantum spin liquids have fascinated condensed matter physicists for decades because of their unusual properties such as spin fractionalization and long-range entanglement. Unlike conventional symmetry breaking the topological order…

Strongly Correlated Electrons · Physics 2018-03-22 Maria Hermanns , Itamar Kimchi , Johannes Knolle

Heisenberg interactions are ubiquitous in magnetic materials and have been prevailing in modeling and designing quantum magnets. Bond-directional interactions offer a novel alternative to Heisenberg exchange and provide the building blocks…

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