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We propose an efficient dual boson scheme, which extends the DMFT paradigm to collective excitations in correlated systems. The theory is fully self-consistent both on the one- and on the two-particle level, thus describing the formation of…

Strongly Correlated Electrons · Physics 2016-01-12 E. A. Stepanov , E. G. C. P. van Loon , A. A. Katanin , A. I. Lichtenstein , M. I. Katsnelson , A. N. Rubtsov

The $GW$-Bethe-Salpeter Equation (BSE) method is promising for calculating the low-lying excited states of molecular systems. So far, it has only been applied to rather small molecules, and in the commonly implemented diagonal…

Chemical Physics · Physics 2022-08-10 Arno Förster , Lucas Visscher

In this work we explore the performance of approximations to electron correlation in reduced density-matrix functional theory (RDMFT) and of approximations to the observables calculated within this theory. Our analysis focuses on the…

Strongly Correlated Electrons · Physics 2015-02-26 Stefano Di Sabatino , Jan A. Berger , Lucia Reining , Pina Romaniello

We present algorithmic and implementation details for the fully self-consistent finite-temperature $GW$ method in Gaussian Bloch orbitals for solids. Our implementation is based on the finite-temperature Green's function formalism in which…

Materials Science · Physics 2022-12-14 Chia-Nan Yeh , Sergei Iskakov , Dominika Zgid , Emanuel Gull

A series of sigma models with torsion are analysed which generate their mass dynamically but whose ultra-violet fixed points are non-trivial conformal field theories -- in fact SU(2) WZW models at level $k$. In contrast to the more familiar…

High Energy Physics - Theory · Physics 2009-10-28 Jonathan M. Evans , Timothy J. Hollowood

Due to the infinite summation of bubble diagrams, the $GW$ approximation of Green's function perturbation theory has proven particularly effective in the weak correlation regime, where this family of Feynman diagrams is important. However,…

We propose a hybrid approach which employs the dynamical mean-field theory (DMFT) self-energy for the correlated, typically rather localized orbitals and a conventional density functional theory (DFT) exchange-correlation potential for the…

Strongly Correlated Electrons · Physics 2021-06-16 Sumanta Bhandary , Karsten Held

Two self-consistent schemes involving Hedin's $GW$ approximation are studied for a set of sixteen different atoms and small molecules. We compare results from the fully self-consistent $GW$ approximation (SC$GW$) and the quasi-particle…

Materials Science · Physics 2015-06-19 Peter Koval , Dietrich Foerster , Daniel Sánchez-Portal

The self-energy method for quantum impurity models expresses the correlation part of the self-energy in terms of the ratio of two Green's functions and allows for a more accurate calculation of equilibrium spectral functions than is…

Strongly Correlated Electrons · Physics 2021-11-24 H. T. M. Nghiem , T. A. Costi

We introduce a spectral embedding algorithm for finding proximal relationships between nodes in signed graphs, where edges can take either positive or negative weights. Adopting a physical perspective, we construct a Hamiltonian which is…

Physics and Society · Physics 2023-02-15 Shazia'Ayn Babul , Renaud Lambiotte

Soft Collinear Effective Theory (SCET) is an effective field theory of Quantum Chromodynamics (QCD) for processes where there are energetic, nearly lightlike degrees of freedom interacting with one another via soft radiation. SCET has found…

High Energy Physics - Phenomenology · Physics 2015-06-23 Christopher Lee

We give a detailed presentation of our recent scheme to include correlation effects in molecular transport calculations using the GW approximation within the non-equilibrium Keldysh formalism. We restrict the GW self-energy to the central…

Materials Science · Physics 2009-11-13 Kristian S. Thygesen , Angel Rubio

We extend our density matrix embedding theory (DMET) [Phys. Rev. Lett. 109 186404 (2012)] from lattice models to the full chemical Hamiltonian. DMET allows the many-body embedding of arbitrary fragments of a quantum system, even when such…

Strongly Correlated Electrons · Physics 2013-11-15 Gerald Knizia , Garnet Kin-Lic Chan

We discuss a parameter-free and computationally efficient ab initio simulation approach for moderately and strongly correlated materials, the multitier self-consistent $GW$+EDMFT method. This scheme treats different degrees of freedom, such…

Strongly Correlated Electrons · Physics 2017-10-02 Fredrik Nilsson , Lewin Boehnke , Philipp Werner , Ferdi Aryasetiawan

We present an extension of the quasiparticle self-consistent $GW$ approximation (QS$GW$) [Phys. Rev. B, 76 165106 (2007)] to include vertex corrections in the screened Coulomb interaction $W$. This is achieved by solving the Bethe-Salpeter…

Materials Science · Physics 2023-10-11 Brian Cunningham , Myrta Grüning , Dimitar Pashov , Mark van Schilfgaarde

This paper analyses the GW method for finite electronic systems. In a first step, we provide a mathematical framework for the usual one-body operators that appear naturally in many-body perturbation theory. We then discuss the GW equations…

Mathematical Physics · Physics 2025-05-20 Eric Cancès , David Gontier , Gabriel Stoltz

In this paper, we propose a new Green's function embedding method called PEXSI-$\Sigma$ for describing complex systems within the Kohn-Sham density functional theory (KSDFT) framework, after revisiting the physics literature of Green's…

Computational Physics · Physics 2016-10-20 Xiantao Li , Lin Lin , Jianfeng Lu

An ensemble Green's function formalism, based on the von Neumann density matrix approach, to calculate one-electron excitation spectra of a many-electron system with degenerate ground states is proposed. A set of iterative equations for the…

Strongly Correlated Electrons · Physics 2019-12-24 Erik Linnér , Ferdi Aryasetiawan

We develop a Green's function approach to quasiparticle excitations of open-shell systems within the GW approximation. It is shown that accurate calculations of the characteristic multiplet structure require a precise knowledge of the self…

Materials Science · Physics 2014-09-11 Johannes Lischner , Jack Deslippe , Manish Jain , Steven G. Louie

We study within the many-body Green's function GW and Bethe-Salpeter formalisms the excitation energies of a paradigmatic model dipeptide, focusing on the four lowest-lying local and charge-transfer excitations. Our GW calculations are…

Materials Science · Physics 2015-06-17 Carina Faber , Paul Boulanger , Ivan Duchemin , Claudio Attaccalite , Xavier Blase
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