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Temperature dependent synchrotron x-ray diffraction and extended x-ray absorption fine structure (EXAFS) studies were performed to understand the role of structural characteristics in driving the magnetoelectric mul- tiferoic properties of…

Materials Science · Physics 2018-07-04 Sudipta Mahana , U. Manju , Pronoy Nandi , Edmund Welter , K. R. Priolkar , D. Topwal

We report on the crystallographic information such as lattice parameters, atomic positions, bond lengths and angles, and local crystalline distortion size and mode of single-crystal YCrO$_3$ compound by a high-resolution synchrotron X-ray…

Materials Science · Physics 2024-03-08 Qian Zhao , Si Wu , Yinghao Zhu , Junchao Xia , Hai-Feng Li

The oxide heterostructure [(YFeO$_3$)$_5$(LaFeO$_3$)$_5$]$_{40}$, which is magnetically ordered and piezoelectric at room temperature, has been constructed from two weak ferromagnetic AFeO$_3$ perovskites with different A cations using…

Single-crystal synchrotron x-ray diffraction measurements in strong magnetic fields have been performed for magnetoelectric compounds GdMnO3 and TbMnO3. It has been found that the P || a ferroelectric phase induced by the application of a…

Strongly Correlated Electrons · Physics 2007-05-23 T. Arima , T. Goto , Y. Yamasaki , S. Miyasaka , K. Ishii , M. Tsubota , T. Inami , Y. Murakami , Y. Tokura

The incompatibility of partial d occupation on the perovskite B-site with the standard charge transfer mechanism for ferroelectricity has been a central paradigm in multiferroics research. Nevertheless, it was recently shown by density…

Materials Science · Physics 2013-05-29 Claude Ederer , Tim Harris , Roman Kovacik

The development of next generation perovskite-based optoelectronic devices relies critically on the understanding of the interaction between charge carriers and the polar lattice in out-of-equilibrium conditions. While it has become…

In contrast to the previous reports that the divalent perovskite SrCrO$_3$ was believed to be cubic structure and nonmagnetic metal, recent measurements suggest coexistence of majority tetragonally distorted weak antiferromagnetic phase and…

Strongly Correlated Electrons · Physics 2009-10-01 K. -W. Lee , W. E. Pickett

We report detailed temperature-dependent inelastic neutron scattering and ab-initio lattice dynamics investigation of magnetic perovskites YCrO3 and LaCrO3. The magnetic neutron scattering from the Cr ions exhibits significant changes with…

We present results of local spin density approximation pseudopotential calculations for the ferroelectromagnet, yttrium manganite (YMnO3). The origin of the differences between ferroelectric and non-ferroelectric perovskite manganites is…

Materials Science · Physics 2015-06-25 Alessio Filippetti , Nicola A. Hill

We present a systematic study of the structure and lattice dynamics at room temperature, and the phonon behavior at low temperatures in orthorhombic Gd$_{1-x}$Y$_{x}$MnO$_{3}$ manganites, with 0 $\leq$ x $\leq$ 0.4, using powder x-ray…

Strongly Correlated Electrons · Physics 2014-12-31 R. Vilarinho , E. C. Queirós , A. Almeida , P. B. Tavares , J. Agostinho Moreira

By means of single-crystal X-ray diffraction we have revealed the breaking of centrosymmetry when lowering the temperature under T$_s$ = 200 K concomitantly with the setting of a commensurate superstructure in the small A-site quadruple…

Materials Science · Physics 2022-11-24 M Verseils , F Mezzadri , D Delmonte , R Cabassi , B Baptiste , Y Klein , G Calestani , F Bolzoni , E Gilioli , A Gauzzi

We study the interplay of structural and polar distortions in hexagonal YMnO3 and short-period PbTiO3/SrTiO3 superlattices by means of first-principles calculations at constrained electric displacement field D. We find that in YMnO3 the…

Materials Science · Physics 2015-06-05 Massimiliano Stengel , Craig J. Fennie , Philippe Ghosez

The origin of the low-temperature ferromagnetic instability in YTiO3 driven by the interplay between lattice, orbital, spin, and charge degrees of freedom is on the background of lattice dynamics. We present a comprehensive study of…

Strongly Correlated Electrons · Physics 2022-02-16 N. N. Kovaleva , O. E. Kusmartseva , A. Maljuk

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted…

Materials Science · Physics 2015-06-17 R. X. Silva , H. Reichlova , X. Marti , D. A. B. Barbosa , M. W. Lufaso , A. P. Ayala , C. W. A. Paschoal

We discuss relative roles played by the magnetic inversion symmetry breaking and the ferroelectric (FE) atomic displacements in the multiferroic state of YMnO3. For these purposes we derive a realistic low-energy model, using results of…

Materials Science · Physics 2012-10-12 I. V. Solovyev , M. V. Valentyuk , V. V. Mazurenko

This work reports on magnetic, dielectric, thermodynamic and magnetoelectric properties of Gd$_{1-x}$Y$_{x}$MnO$_{3}$, with 0 \leq x \leq 0.4, with emphasis on the (x, T) phase diagram, towards unraveling the role of the driving mechanisms…

Strongly Correlated Electrons · Physics 2015-06-18 R. Vilarinho , A. Almeida , J. M. Machado da Silva , J. B. Oliveira , M. A. Sá , P. B. Tavares , J. Agostinho Moreira

Neutron scattering studies on a single crystal of the highly-correlated electron system, La1-xSrxMnO3 with x~0.3, have been carried out elucidating both the spin and lattice dynamics of this metallic ferromagnet. We report a large measured…

Condensed Matter · Physics 2009-10-28 Michael C. Martin , G. Shirane , Y. Endoh , K. Hirota , Y. Moritomo , Y. Tokura

Magnetic structures of metastable perovskites ScCrO3, InCrO3 and TlCrO3, stabilized under high-pressure and high-temperature conditions, have been studied by neutron powder diffraction. Similar to the other orthochromites LnCrO3…

Strongly Correlated Electrons · Physics 2021-01-13 Lei Ding , Pascal Manuel , Dmitry D. Khalyavin , Fabio Orlandi , Yu Kumagai , Fumiyasu Oba , Wei Yi , Alexei A. Belik

Identification of novel multiferroic materials with high-ordering temperatures remains at the forefront of condensed matter physics research. In this regard, the antiferromagnetic RCrO$_3$ compounds (like GdCrO$_3$) constitute a promising…

We use a combination of symmetry arguments and first-principles calculations to explore the connection between structural distortions and ferroelectricity in the perovskite family of materials. We explain the role of octahedral rotations in…

Materials Science · Physics 2013-08-01 Nicole A. Benedek , Craig J. Fennie
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