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We use theory and first-principles calculations to explore mechanisms for control of the translational and point group symmetries of crystals in ultrafast optical experiments. We focus in particular on mechanisms that exploit anharmonic…

Materials Science · Physics 2025-04-28 Guru Khalsa , Jeffrey Z. Kaaret , Nicole A. Benedek

Lattice dynamics in low-dimensional materials and, in particular, the quadratic behaviour of the flexural acoustic modes play a fundamental role in their thermomechanical properties. A first-principles evaluation of these can be very…

Materials Science · Physics 2020-10-28 Francesco Libbi , Nicola Bonini , Nicola Marzari

A new method for extracting force constants (FC) from first principles is introduced. It requires small supercells but very accurate forces. In principle, provided that forces are accurate enough, it can extract harmonic as well as…

Materials Science · Physics 2007-10-31 Keivan Esfarjani , Harold T. Stokes

The occurrence of thermal transport phenomena is widespread, exerting a pivotal influence on the functionality of diverse electronic and thermo-electric energy-conversion devices. The traditional first-principles theory governing the…

Materials Science · Physics 2026-05-20 Soham Mandal , Manish Jain , Prabal K. Maiti

The anharmonic lattice is a representative example of an interacting bosonic many-body system. The self-consistent harmonic approximation has proven versatile for the study of the equilibrium properties of anharmonic lattices. However, the…

Materials Science · Physics 2021-07-28 Jae-Mo Lihm , Cheol-Hwan Park

The exposure to intense electromagnetic radiation can induce distortions and symmetry breaking in the crystal structure of solids, providing a route for the all-optical control of their properties. In this manuscript, we formulate a unified…

Materials Science · Physics 2023-02-22 Fabio Caruso , Marios Zacharias

We demonstrate an approach for calculating temperature-dependent quantum and anharmonic effects with beyond density-functional theory accuracy. By combining machine-learned potentials and the stochastic self-consistent harmonic…

Materials Science · Physics 2023-03-03 Carla Verdi , Luigi Ranalli , Cesare Franchini , Georg Kresse

First principles predictions of lattice dynamics are of vital importance for a broad range of topics in materials science and condensed matter physics. The large-scale nature of lattice dynamics calculations and the desire to design novel…

Materials Science · Physics 2023-01-23 Jinliang Ning , James W. Furness , Jianwei Sun

We study the impact of phonon anharmonicity on the electronic dynamics of soft materials using a nonperturbative quantum-classical approach. The method is applied to a one-dimensional model of doped organic semiconductors with low-frequency…

Materials Science · Physics 2025-09-24 Jonathan H. Fetherolf , Petra Shih , Timothy C. Berkelbach

The impact of lattice type, period, porosity and thickness of two-dimensional silicon phononic crystals on the reduction of thermal conductance by coherent modification of phonon dispersion is investigated using the theory of elasticity and…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Roman Anufriev , Masahiro Nomura

Understanding and simulating the thermodynamic and dynamical properties of materials affected by strong ionic anharmonicity is a central challenge in material science. Much interest is in material displaying critical displacive behaviour,…

Materials Science · Physics 2025-04-18 Lorenzo Monacelli

The dynamical properties of nuclei, carried by the concept of phonon quasiparticles (QP), are central to the field of condensed matter. While the harmonic approximation can reproduce a number of properties observed in real crystals, the…

Materials Science · Physics 2023-12-19 Aloïs Castellano , J. P. Alvarinhas Batista , Matthieu J. Verstraete

Progress in the development of coupled atomistic-continuum methods for simulations of critical dynamic material behavior has been hampered by a spurious wave reflection problem at the atomistic-continuum interface. This problem is mainly…

Materials Science · Physics 2017-12-06 Xiang Chen , Adrian Diaz , Liming Xiong , David L. McDowell , Youping Chen

In this paper we extend the classical method of lattice dynamics to defective crystals with partial symmetries. We start by a nominal defect configuration and first relax it statically. Having the static equilibrium configuration, we use a…

Materials Science · Physics 2010-04-28 Arash Yavari , Arzhang Angoshtari

The high pressure lattice dynamics of rhombohedral antimony have been studied by a combination of diffuse scattering and inelastic x-ray scattering. The evolution of the phonon behavior as function of pressure was analyzed by means of two…

We compute the lattice-dynamical and thermal equation of state properties of ferromagnetic bcc iron using the first principles linear response linear-muffin-tin-orbital method in the generalized-gradient approximation. The calculated phonon…

Materials Science · Physics 2009-11-11 Xianwei Sha , R. E. Cohen

The temperature-dependent phonons are a generalization of interatomic force constants varying in T, which as found widespread use in computing the thermal transport of materials. A formal justification for using this combination to access…

Materials Science · Physics 2025-01-31 Aloïs Castellano , J. P. Alvarinhas Batista , Olle Hellman , Matthieu J. Verstraete

Understanding heat transport in semiconductors and insulators is of fundamental importance because of its technological impact in electronics and renewable energy harvesting and conversion. Anharmonic Lattice Dynamics provides a powerful…

Materials Science · Physics 2020-10-13 Giuseppe Barbalinardo , Zekun Chen , Nicholas W. Lundgren , Davide Donadio

We investigate the lattice dynamics and thermodynamics of nonmagnetic bcc vanadium as a function of temperature and pressure, using the first principles linear response linear-muffin-tin-orbital method. The calculated phonon density of…

Materials Science · Physics 2007-05-23 Xianwei Sha , R. E. Cohen

Theoretical frameworks used to qualitatively and quantitatively describe nuclear dynamics in solids are often based on the harmonic approximation. However, this approximation is known to become inaccurate or to break down completely in many…

Materials Science · Physics 2020-09-02 Florian Knoop , Thomas A. R. Purcell , Matthias Scheffler , Christian Carbogno