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The archetypal $3d$ Mott insulator hematite, Fe$_2$O$_3$, is one of the basic oxide components playing an important role in mineralogy of Earth's lower mantle. Its high pressure-temperature behavior, such as the electronic properties,…

Strongly Correlated Electrons · Physics 2019-10-07 I. Leonov , G. Kh. Rozenberg , I. A. Abrikosov

In this Letter we report the first LDA+DMFT (method combining Local Density Approximation with Dynamical Mean-Field Theory) results of magnetic and spectral properties calculation for paramagnetic phases of FeO at ambient and high pressures…

Strongly Correlated Electrons · Physics 2010-11-03 A. ~O. ~Shorikov , Z. ~V. ~Pchelkina , V. ~I. ~Anisimov , S. ~L. ~Skornyakov , M. ~A. ~Korotin

The insulator-metal transition in Mott insulators, known as the Mott transition, is usually accompanied with various novel quantum phenomena, such as unconventional superconductivity, non-Fermi liquid behavior and colossal…

Strongly Correlated Electrons · Physics 2023-04-21 Ye Yang , Fanghang Yu , Xikai Wen , Zhigang Gui , Yuqing Zhang , Fangyang Zhan , Rui Wang , Jianjun Ying , Xianhui Chen

We compute the electronic structure, spin and charge state of Fe ions, and structural phase stability of paramagnetic CaFeO$_3$ under pressure using a fully self-consistent in charge density DFT+dynamical mean-field theory method. We show…

Strongly Correlated Electrons · Physics 2022-02-01 I. Leonov

The layered metal phosphorous trisulfide FePS$_3$ is reported to be a Mott insulator at ambient conditions and to undergo structural and insulator-metal phase transitions under pressure. However, the character of the resulting metallic…

Strongly Correlated Electrons · Physics 2022-02-28 Minsung Kim , Heung-Sik Kim , Kristjan Haule , David Vanderbilt

BaFe$_2$S$_3$ is a quasi one-dimensional Mott insulator that orders antiferromagnetically below 117(5)\,K. The application of pressure induces a transition to a metallic state, and superconductivity emerges. The evolution of the magnetic…

Unusual metallic states involving breakdown of the standard Fermi-liquid picture of long-lived quasiparticles in well-defined band states emerge at low temperatures near correlation-driven Mott transitions. Prominent examples are…

Materials Science · Physics 2018-11-14 L. Craco , M. S. Laad , S. Leoni

A metal-insulator transition (MIT) in BiFeO$_3$ under pressure was investigated by a method combining Generalized Gradient Corrected Local Density Approximation with Dynamical Mean-Field Theory (GGA+DMFT). Our paramagnetic calculations are…

Strongly Correlated Electrons · Physics 2018-11-01 A. O. Shorikov , A. V. Lukoyanov , V. I. Anisimov , S. Y. Savrasov

We study the electronic structure, magnetic state, and phase stability of paramagnetic BiNiO$_3$ near a pressure-induced Mott insulator-to-metal transition (MIT) by employing a combination of density functional and dynamical mean-field…

Strongly Correlated Electrons · Physics 2019-11-06 I. Leonov , A. S. Belozerov , S. L. Skornyakov

V2O3 is the prototype system for the Mott transition, one of the most fundamental phenomena of electronic correlation. Temperature, doping or pressure induce a metal to insulator transition (MIT) between a paramagnetic metal (PM) and a…

The microscopic mechanism of the metal-insulator transition is studied by orbital-resolved 51V NMR spectroscopy in a prototype of the quasi-one-dimensional system V6O13. We uncover that the transition involves a site-selective d orbital…

Strongly Correlated Electrons · Physics 2015-04-24 Yasuhiro Shimizu , Satoshi Aoyama , Takaaki Jinno , Masayuki Itoh , Yutaka Ueda

We report a detail theoretical study of the electronic structure and phase stability of transition metal oxides MnO, FeO, CoO, and NiO in their paramagnetic cubic B1 structure by employing dynamical mean-field theory of correlated electrons…

Strongly Correlated Electrons · Physics 2016-10-26 I. Leonov , L. Pourovskii , A. Georges , I. A. Abrikosov

The spin-orbit Mott insulator Sr3Ir2O7 provides a fascinating playground to explore insulator-metal transition driven by intertwined charge, spin, and lattice degrees of freedom. Here, we report high pressure electric resistance and…

Two-dimensional materials have proven to be a prolific breeding ground of new and unstudied forms of magnetism and unusual metallic states, particularly when tuned between their insulating and metallic phases. In this paper we present work…

Strongly Correlated Electrons · Physics 2019-01-02 C. R. S. Haines , M. J. Coak , G. I. Lampronti , C. Liu , H. Hamidov , A. R. Wildes , D. Daisenberger , P. Nahai-Williamson , S. S. Saxena

While the phase diagrams of the one- and multi-orbital Hubbard model have been well studied, the physics of real Mott insulators is often much richer, material dependent, and poorly understood. In the prototype Mott insulator…

Strongly Correlated Electrons · Physics 2018-09-06 Frank Lechermann , Noam Bernstein , I. I. Mazin , Roser Valentí

We present results of combined density functional theory plus dynamical mean-field theory (DFT+DMFT) calculations, which show that the Mott insulator LaTiO3 undergoes an insulator-to-metal transition under compressive epitaxial strain of…

Strongly Correlated Electrons · Physics 2014-04-17 Krzysztof Dymkowski , Claude Ederer

In two-dimensional (2D) van der Waals (vdW) layered materials the application of pressure often induces a giant lattice collapse, which can subsequently drive an associated Mott transition. Here, we investigate room-temperature…

The metal-insulator and spin state transitions of CoO under high pressure are studied by using density functional theory combined with dynamical mean-field theory. Our calculations predict that the metal-insulator transition in CoO is a…

Strongly Correlated Electrons · Physics 2014-12-04 Li Huang , Yilin Wang , Xi Dai

The pressure-induced insulator to metal transition (IMT) of layered magnetic nickel phosphorous tri-sulfide NiPS3 was studied in-situ under quasi-uniaxial conditions by means of electrical resistance (R) and X-ray diffraction (XRD)…

Strongly Correlated Electrons · Physics 2021-11-23 Takahiro Matsuoka , Amanda Haglund , Rui Xue , Jesse S. Smith , Maik Lang , Antonio M. dos Santos , David Mandrus

FePS$_3$ is a prototype van der Waals layered antiferromagnet and a Mott insulator under ambient conditions, which has been recently reported to go through a pressure-induced dimensionality crossover and an insulator-to-metal transition.…

Strongly Correlated Electrons · Physics 2023-07-19 Shiyu Deng , Siyu Chen , Bartomeu Monserrat , Emilio Artacho , Siddharth S Saxena
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