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Piezoelectric nanowires are promising materials for sensing, actuation and energy harvesting, due to their enhanced properties at the nanoscale. However, quantitative characterization of piezoelectricity in nanomaterials is challenging due…

Mesoscale and Nanoscale Physics · Physics 2021-02-08 Yonatan Calahorra , Wonjong Kim , Jelena Vukajlovic Plestina , Anna Fontcuberta i Morral , Sohini Kar-Narayan

Room temperature coexistence of ferromagnetism and ferroelectricity in a thin film of a novel material of nominal composition PbTi0.5Fe0.5O3-d is probed by standard ferroelectric and ferromagnetic hysteresis loop measurements and by…

Materials Science · Physics 2009-11-11 V. R. Palkar , S. C. Purandare , S. Gohil , J. John , S. Bhattacharya

High-resolution X-ray photoemission electron microscopy (X-PEEM) is a well-established method for imaging ferroelectric domain structures. Here, we expand the scope of application of X-PEEM and demonstrate its capability for imaging and…

Understanding the mechanisms and spatial correlations of crystallographic symmetry breaking in ferroelectric materials is essential to tuning their functional properties. While optical second harmonic generation (SHG) has long been utilized…

Materials Science · Physics 2022-08-10 Wei Li , Yunpeng Ma , Tianyi Feng , Sergei V. Kalinin , Jing-Feng Li , Qian Li

Cryo-electron microscopy nowadays often requires the analysis of hundreds of thousands of 2D images as large as a few hundred pixels in each direction. Here we introduce an algorithm that efficiently and accurately performs principal…

Computer Vision and Pattern Recognition · Computer Science 2015-12-16 Zhizhen Zhao , Yoel Shkolnisky , Amit Singer

Analytical description of domain structure morphology and phase diagrams of ferroelectric nanoparticles is developed in the framework of Landau Ginzburg Devonshire approach. To model realistic conditions of incomplete screening of…

While piezoelectrics and ferroelectrics are playing a key role in many everyday applications, there are still a number of open questions related to the physics of those materials. In order to foster the understanding of piezoelectrics and…

Materials Science · Physics 2017-12-01 Andres Gomez , Marti Gich , Adrien Carretero-Genevrier , Teresa Puig , Xavier Obradors

Scanning Probe Microscopy is used to study and quantify the nanoscale electric phenomena in the two classes of oxide systems, namely transport at electroactive grain boundaries and surface behavior of ferroelectric materials. Scanning…

Materials Science · Physics 2007-05-23 Sergei V. Kalinin

Reducing the dimensions of ferroelectric materials down to the nanoscale has strong implications on the ferroelectric polarization pattern and on the ability to switch the polarization. As the size of ferroelectric domains shrinks to…

Ongoing advances in scanning probe microscopy techniques are continually expanding the possibilities for nanoscale characterization and correlated studies of functional materials. Here, we demonstrate how a recent extension of piezoresponse…

Materials Science · Physics 2026-01-21 Ruben Dragland , Jan Schultheiß , Ivan N. Ushakov , Roger Proksch , Dennis Meier

Domain-wall dynamics in ferroelectric materials are strongly position-dependent since each polar interface is locked into a unique local microstructure. This necessitates spatially resolved studies of the wall-pinning using scanning-probe…

Materials Science · Physics 2025-06-02 Kamyar Barakati , Yu Liu , Hiroshi Funakubo , Sergei V. Kalinin

Domain switching pathways in ferroelectric materials visualized by dynamic Piezoresponse Force Microscopy (PFM) are explored via variational autoencoder (VAE), which simplifies the elements of the observed domain structure, crucially…

Disordered Systems and Neural Networks · Physics 2021-04-14 Sergei V. Kalinin , James J. Steffes , Yongtao Liu , Bryan D. Huey , Maxim Ziatdinov

Tracing of the magnetic field with Velocity Gradient Technique (VGT) allows observers to probe magnetic field directions with spectroscopic data. In this paper, we employ the method of Principal Component Analysis (PCA) to extract the…

Astrophysics of Galaxies · Physics 2018-07-25 Yue Hu , Ka Ho Yuen , A. Lazarian

Polarization in ferroelectric domains arises from atomic-scale structural variations that govern macroscopic functionalities. The interfaces between these domains known as domain walls host distinct physical responses, making their…

Nanoscale polarization switching in ferroelectric materials by Piezoresponse Force Microscopy (PFM) in weak and strong indentation limits is analyzed using exact solutions for electrostatic and coupled electroelastic fields below the tip.…

Materials Science · Physics 2009-11-10 Sergei V. Kalinin , A. Gruverman , J. Shin , A. P. Baddorf , E. Karapetian , M. Kachanov

Polarization dynamics in ferroelectric materials are explored via the automated experiment in Piezoresponse Force Spectroscopy. A Bayesian Optimization framework for imaging is developed and its performance for a variety of acquisition and…

Disordered Systems and Neural Networks · Physics 2021-06-24 Rama K. Vasudevan , Kyle Kelley , Jacob Hinkle , Hiroshi Funakubo , Stephen Jesse , Sergei V. Kalinin , Maxim Ziatdinov

Low-temperature X-ray photoemission electron microscopy (X-PEEM) is used to measure the electric potential at domain walls in improper ferroelectric Er0.99Ca0.01MnO3. By combining X-PEEM with scanning probe microscopy and theory, we develop…

Monitoring structural changes in ferroelectric thin films during electric field-induced polarization switching is important for a full microscopic understanding of the coupled motion of charges, atoms and domain walls. We combine standard…

Materials Science · Physics 2017-10-18 C. Kwamen , M. Roessle , M. Reinhardt , W. Leitenberger , F. Zamponi , M. Alexe , M. Bargheer

We consider a typical heterostructure domain patterned ferroelectric film/ultra thin dielectric layer/ semiconductor, where the semiconductor can be an electrolyte, paraelectric or multi layered graphene. Unexpectedly we have found that the…

The image formation mechanism in Piezoresponse Force Microscopy (PFM) of capacitor structures is analyzed. We demonstrate that the spatial resolution is a bilinear function of film and top electrode thicknesses, and derive the corresponding…