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The dynamics of pigment-pigment and pigment-protein interactions in light-harvesting complexes is studied with a novel approach which combines molecular dynamics (MD) simulations with quantum chemistry (QC) calculations. The MD simulations…

Biological Physics · Physics 2009-11-07 Ana Damjanovic , Ioan Kosztin , Klaus Schulten

Non-Markovian and non-equilibrium phonon effects are believed to be key ingredients in the energy transfer in photosynthetic complexes, especially in complexes which exhibit a regime of intermediate exciton-phonon coupling. In this work, we…

Quantum Physics · Physics 2011-07-08 Patrick Rebentrost , Alán Aspuru-Guzik

The electrons and excitons multiple exciton generation dynamics in two silicon clusters, or more specifically the inelastic scattering rates of electronic and excitonic states in the two silicon clusters, Si26 and Si46, are calculated using…

Mesoscale and Nanoscale Physics · Physics 2020-07-14 Taofang Zeng , Yi He

A formulation for transport in an inhomogeneous, interacting electron gas is described. Electronic current is induced by a constraint condition imposed as a vector Lagrange multiplier. Constrained minimization of the total energy functional…

Condensed Matter · Physics 2009-11-07 D. S. Kosov , J. C. Greer

In an organic blend the vibrational normal mode excited by exciton splitting is the same as the one coupled to charge hopping. Excess driving force for exciton splitting can therefore aid charge transfer, if vibrational relaxation is slow…

Mesoscale and Nanoscale Physics · Physics 2010-04-05 James Kirkpatrick

We study the theory of itinerant-hole photoluminescence of two-dimensional electron systems in the regime of the magnetically induced Wigner crystal. We show that the exciton recombination transition develops structure related to the…

Condensed Matter · Physics 2009-10-28 N. R. Cooper

We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To…

Biological Physics · Physics 2015-05-28 Pulak Kumar Ghosh , Anatoly Yu. Smirnov , Franco Nori

The multipole expansion is a key tool in the study of light-matter interactions. All the information about the radiation of and coupling to electromagnetic fields of a given charge-density distribution is condensed into few numbers: The…

Optics · Physics 2018-05-08 R. Alaee , C. Rockstuhl , I. Fernandez-Corbaton

We theoretically investigate an exciton transfer process in a donor domain of organic photovoltaic cells focusing on the roles of local and nonlocal electron-phonon interactions. Our model consists of a three-level system described by the…

Materials Science · Physics 2021-01-25 Mauro Cainelli , Yoshitaka Tanimura

Natural light-harvesting antenna complexes efficiently capture solar energy using chlorophyll, i.e., magnesium porphyrin pigments, embedded in a protein matrix. Inspired by this natural configuration, artificial clay-porphyrin antenna…

The electron dynamics and the mechanisms of power absorption in radio-frequency (RF) driven, magnetically enhanced capacitively coupled plasmas (MECCPs) at low pressure are investigated. The device in focus is a geometrically asymmetric…

Photoexcited states are relaxed by transferring energy to the environments. In order to study which coupling allows fast energy transfer to lattice vibrations in correlated electron systems, we calculate the time evolutions of the kinetic…

Strongly Correlated Electrons · Physics 2009-04-27 Kenji Yonemitsu , Nobuya Maeshima

General expressions are obtained for the coefficient of light absorption by free carriers as well as the intensity of the spontaneous light emission by hot electrons in multivalley semiconductors. These expressions depend on the electron…

Quantum Physics · Physics 2008-11-19 P. M. Tomchuk

The effect of carrier multiplication (CM) in semiconductor nanocrystals is systematically treated by employing an exciton scattering approach. Using projection operators, we reduce the Coulomb coupled multi-exciton dynamics to scattering…

Mesoscale and Nanoscale Physics · Physics 2010-08-31 Andrei Piryatinski , Kirill A. Velizhanin

In this article, we use a many-body approach to study the absorption spectra of electron-doped two-dimensional semiconductors. Optical absorption is modeled by a many-body scattering Hamiltonian which describes an exciton immersed in a…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Yao-Wen Chang , David R. Reichman

A vibronic exciton model is developed to investigate the origin of long lived coherences in light-harvesting complexes. Using experimentally determined parameters and uncorrelated site energy fluctuations, the model predicts oscillations in…

Biological Physics · Physics 2012-06-07 Niklas Christensson , Harald F. Kauffmann , Tonu Pullerits , Tomas Mancal

The fundamental physical mechanisms of energy transfer in photosynthetic complexes is not yet fully understood. In particular, the degree of efficiency or sensitivity of these systems for energy transfer is not known given their…

Quantum Physics · Physics 2013-05-30 Alireza Shabani , Masoud Mohseni , Herschel Rabitz , Seth Lloyd

We investigate the excitonic energy transfer (EET) in the Fenna-Matthews-Olsen complex and obtain the linear absorption spectrum (at 300 K) by a phenomenological time-convolutionless (TCL) master equation which is validated by utilizing…

Chemical Physics · Physics 2013-01-10 Piet Schijven , Lothar Muehlbacher , Oliver Muelken

We theoretically investigate an exciton-coupled electron transfer (XCET) process that is conversion of an exciton into a charge transfer state. This conversion happens in an exciton transfer (XT) process, and the electron moves away in an…

Quantum Physics · Physics 2017-11-03 Souichi Sakamoto , Yoshitaka Tanimura

This paper considers the probability density and current distributions generated by a point-like, isotropic source of monoenergetic charges embedded into a uniform magnetic field environment. Electron sources of this kind have been realized…

Quantum Physics · Physics 2012-09-04 Christian Bracher , Arnulfo Gonzalez
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