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We present a rigorous theoretical description of excitonic dynamics in molecular light-harvesting aggregates photoexcited by weak-intensity radiation of arbitrary properties. While the interaction with light is included up to the second…

Chemical Physics · Physics 2021-01-01 Veljko Janković , Tomáš Mančal

We study carrier interaction induced many-body effects on the excitonic optical properties of highly photoexcited one-dimensional semiconductor quantum wire systems by solving the dynamically screened Bethe-Salpeter equation using realistic…

Strongly Correlated Electrons · Physics 2009-11-07 D. W. Wang , S. Das Sarma

The present review is devoted to our recent studies on the excitonic motion in photosynthetic systems. In photosynthesis, the light photon is absorbed to create an exciton in the antenna complex of the photosynthetic pigments. This exciton…

Statistical Mechanics · Physics 2012-03-02 Navinder Singh

We discuss our recent theoretical work on vibronic coupling mechanisms in a model energy transfer system in the context of previous 2DEV experiments on a natural light-harvesting system, light-harvesting complex II (LHCII), where vibronic…

Chemical Physics · Physics 2021-09-22 Eric A. Arsenault , Addison J. Schile , David T. Limmer , Graham R. Fleming

Photosynthesis, the process by which energy from sunlight drives cellular metabolism, relies on a unique organization of light-harvesting and reaction center complexes. Recently, the organization of light-harvesting LH2 complexes and…

Biological Physics · Physics 2011-11-02 Elad Harel

We provide a unified theoretical approach to the quantum dynamics of absorption of single photons and subsequent excitonic energy transfer in photosynthetic light-harvesting complexes. Our analysis combines a continuous mode <n>-photon…

Chemical Physics · Physics 2018-02-20 Herman C. H. Chan , Omar E. Gamel , Graham R. Fleming , K. Birgitta Whaley

Using the reduced density matrix formalism the exciton scattering in light-harvesting systems of purple bacteria is calculated. The static disorder (fluctuations of the site energies) as well as the dynamic disorder (dissipation) is taken…

Chemical Physics · Physics 2009-11-07 Pavel Herman , Ulrich Kleinekathoefer , Ivan Barvik , Michael Schreiber

We theoretically investigated the coupling between the exciton internal and center-of-mass motions in monolayer transition metal dichalcogenides subjected to a periodic electrostatic potential. The coupling leads to the emergence of…

Mesoscale and Nanoscale Physics · Physics 2024-04-16 Fujia Lu , Qianying Hu , Yang Xu , Hongyi Yu

Resonant energy transfer mechanisms have been observed in the sensitized luminescence of solids, in quantum dots and in molecular nanostructures, and they also play a central role in light harvesting processes in photosynthetic organisms.…

Quantum Physics · Physics 2009-11-07 Brendon Lovett , John H. Reina , Ahsan Nazir , Beeneet Kothari , Andrew Briggs

Light-harvesting and excitation energy transfer in photosynthesis generally involve chlorophyll-molecules, maintained by their host proteins at short distances from each other, this resulting in excitonic coupling. The transfer of…

Spectroscopic experiments have identified long-lived coherences in several light-harvesting systems, suggesting that coherent effects may be relevant to their performance. However, there is limited experimental evidence of coherence…

Chemical Physics · Physics 2019-10-30 Stefano Tomasi , Sima Baghbanzadeh , Saleh Rahimi-Keshari , Ivan Kassal

Intense light with frequencies above typical atomic or molecular ionization potentials as provided by free-electron lasers couples many photons into extended targets such as clusters and biomolecules. This implies, in contrast to…

Atomic and Molecular Clusters · Physics 2011-05-25 Christian Gnodtke , Ulf Saalmann , Jan-Michael Rost

The magnetic field dependence of photoabsorption provides direct insights into the band structure of semiconductors. It is perhaps surprising that there is a large discrepancy between electron, hole, and reduced mass reported in the recent…

Mesoscale and Nanoscale Physics · Physics 2025-01-22 Jack N. Engdahl , Harley D. Scammell , Dmitry K. Efimkin , Oleg P. Sushkov

Motivated by the experiment of electrostatic conveyor belt for indirect excitons [A. G. Winbow, \textit{et al.}, Phys. Rev. Lett. \textbf{106}, 196806 (2011)], we study the exciton patterns for understanding the exciton dynamics. By…

Quantum Gases · Physics 2024-06-19 T. T. Zhao , Rui Li , C. S. Liu

Organic molecules store the energy of absorbed light in the form of charge-neutral molecular excitations -- Frenkel excitons. Usually, in amorphous organic materials, excitons are viewed as quasiparticles, localized on single molecules,…

Mesoscale and Nanoscale Physics · Physics 2013-04-02 Semion K. Saikin , Alexander Eisfeld , Stéphanie Valleau , Alán Aspuru-Guzik

The conversion of an absorbed photon from the exciton energy into the reaction centre in the photosynthetic complex has a near unit efficiency. It is becoming clear that any classical model, where the exciton hopping is modeled by a…

Quantum Physics · Physics 2010-06-21 Vlatko Vedral , Tristan Farrow

We analyze the exciton dynamics in PhotosystemI from Thermosynechococcus elongatus using the distributed memory implementation of the hierarchical equation of motion (DM-HEOM) for the 96 Chlorophylls in the monomeric unit. The…

Photosynthetic organisms harvest light energy, utilizing the absorption and energy transfer properties of protein-bound chromophores. Controlling the harvesting efficiency is critical for the optimal function of the photosynthetic…

Recent experiments have shown that highly efficient energy transfer can take place in organic nanocrystals at extremely low acceptor densities. This striking phenomenon has been ascribed to the formation of exciton polaritons thanks to the…

Chemical Physics · Physics 2021-01-12 R. Sáez-Blázquez , J. Feist , F. J. García-Vidal , A. I. Fernández-Domínguez

Photosynthesis transfers energy efficiently through a series of antenna complexes to the reaction center where charge separation occurs. Energy transfer in vivo is primarily monitored by measuring fluorescence signals from the small…