Related papers: An Autoignition Study of iso-Butanol: Experiments …
When designing high-efficiency spark-ignition (SI) engines to operate at high compression ratios, one of the main issues that have to be addressed is detonation development from a pre-ignition front. In order to control this phenomenon, it…
Butanol has received significant research attention as a second-generation biofuel in the past few years. In the present study, skeletal mechanisms for four butanol isomers were generated from two widely accepted, well-validated detailed…
Experimental and computational investigations are carried out to elucidate the influence of ethanol addition on n-heptane auto-ignition in counterflows. An axisymmetric stream of air, temperature gradually increased, is directed onto the…
Five recently developed chemical kinetics mechanisms for ammonia oxidation are analysed and compared, in the context of homogeneous adiabatic autoignition. The analysis focuses on the ignition delay and is based on the explosive mode that…
This paper presents an approch for modeling with one single kinetic mechanism the chemistry of the autoignition and combustion processes inside an internal combustion engine, as well as the chemical kinetics governing the post-oxidation of…
The prediction of auto-ignition delay times in HCCI engines has risen interest on detailed chemical models. This paper described a validated kinetic mechanism for the oxidation of a model Diesel fuel (n-decane and α-methylnaphthalene).…
A systematic investigation on the effects of roaming radical reactions on global combustion properties for transportation fuels is presented. New software was developed that can automatically discover all the possible roaming pathways…
Ammonia is a promising zero-carbon fuel for industrial and transport applications, but its combustion is hindered by flame instabilities, incomplete oxidation, and the formation of nitrogen oxides. Accurate and detailed kinetic models are…
A method for computing minimum ignition energies for gaseous fuel mixtures with detailed and reduced chemistry, by numerical integration of time-dependent conservation equations in a spherically symmetrical configuration, is presented and…
Biofuels have shown to be a reliable source of energy and a replication of fossil fuels. A well-known branch of biofuels is oxygenated ones derived from lignin compounds. Although a wide range of studies was done on oxygenated fuels,…
The present study addresses the role of molecular non-equilibrium effects in thermal ignition problems. We consider a single binary reaction of the form A+B -> C+C. Molecular dynamics calculations were performed for activation energies…
Ignition of Jet-A/air mixtures was studied behind reflected shock waves. Heating of shock tube at temperature of 150 C was used to prepare a homogeneous fuel mixture. Ignition delay times were measured from OH emission at 309 nm and from…
We report the temperature, pressure and composition dependence of some basic properties of model liquid water-methanol mixtures. For this purpose the isobaric-isothermal molecular dynamics computer simulations are employed. Our principal…
The problem of thermal ignition in a homogeneous gas is revisited from a molecular dynamics perspective. A two-dimensional model is adopted, which assumes reactive disks of type A and B in a fixed area that react to form type C products if…
Fuel-lean hydrogen combustion systems hold significant potential for low pollutant emissions, but are also susceptible to intrinsic combustion instabilities. While most research on these instabilities has focused on flames without wall…
Mixing, ignition and combustion behavior in a rapid compression and expansion machine operated under Premixed Charge Compression Ignition (PCCI) relevant conditions are investigated by combined passive optical and laser-optical high-speed…
The effects of nanosecond pulsed non-equilibrium plasma discharges on ignition characteristics and low-temperature chemistry or LTC of DME/O2/Ar mixtures are numerically investigated in a plane-to-plane geometry at a reduced pressure of 76…
To better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar)…
Self-heating condition and following ignition in an Inertial Confinement Fusion (ICF) fuel pellet is evaluated by calculating the power equations, dynamically. In fact, the self-heating condition is a criterion that determines the minimum…
Ramp compression experiments characterize high-pressure states of matter at temperatures well below those present in shock compression. However, because temperature is typically not directly measured during ramp compression, it is uncertain…