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We have studied solid hydrogen up to pressures of 300 GPa and temperatures of 350 K using density functional theory methods and have found "mixed structures" that are more stable than those predicted earlier. Mixed structures consist of…

Materials Science · Physics 2012-06-20 Chris J. Pickard , Miguel Martinez-Canales , Richard J. Needs

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

Superconductivity · Physics 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Evolutionary structure searches are used to predict stable phases with unique stoichiometries in the hydrogen-rich region of the magnesium/hydrogen phase diagram under pressure. MgH$_4$, MgH$_{12}$ and MgH$_{16}$ are found to be…

Materials Science · Physics 2015-06-12 David C. Lonie , James Hooper , Bahadir Altintas , Eva Zurek

The recent discovery of superconductivity at 190~K in highly compressed H$_{2}$S is spectacular not only because it sets a record high critical temperature, but because it does so in a material that appears to be, and we argue here that it…

Superconductivity · Physics 2015-03-05 N. Bernstein , C. S. Hellberg , M. D. Johannes , I. I. Mazin , M. J. Mehl

The exploration of superconductivity dominated by structural units is of great interest in condense matter physics. MgB2, consisting of graphene-like B, becomes a typical representative of traditional superconductors. Phosphorus…

Superconductivity · Physics 2021-12-06 Xing Li , Xiaohua Zhang , Yong Liu , Guochun Yang

Search for stable high-pressure compounds in the Ti--H system reveals the existence of titanium hydrides with new stoichiometries, including Ibam-Ti$_2$H$_5$, I4/m-Ti$_5$H$_{13}$, I$\bar{4}$-Ti$_5$H$_{14}$, Fddd-TiH$_4$,…

Materials Science · Physics 2020-05-20 Jin Zhang , Jeffrey M. McMahon , Artem R. Oganov , Xinfeng Li , Xiao Dong , Huafeng Dong , Shengnan Wang

Pressurized hydrogen-rich compounds, which could be viewed as precompressed metallic hydrogen, exhibit high superconductivity, thereby providing a viable route toward the discovery of high-temperature superconductors. Of particular interest…

Superconductivity · Physics 2021-11-12 Hongyi Guan , Ying Sun , Hanyu Liu

Rare-earth hydrides can exhibit high-temperature superconductivity under high pressure. Here, we apply a crystal structure prediction method to the current record-holding $T_c$ material, LaH$_{10}$, and a candidate for even higher $T_c$,…

Optical conductivity s(w) of PrRu4P12 has been studied under high pressure to 14 GPa, at low temperatures to 8 K, and at photon energies 12 meV-1.1 eV. The energy gap in s(w) at ambient pressure, caused by a metal-insulator transition due…

The binary polyhydrides of heavy rare earth lutetium that shares a similar valence electron configuration to lanthanum have been experimentally discovered to be superconductive. The lutetium polyhydrides were successfully synthesized at…

Recently, coexistence of ferromagnetism (T_Curie = 2.8K) and superconductivity (T_sc = 0.8K) has been reported in UCoGe, a compound close to a ferromagnetic instability at ambient pressure P. Here we present resistivity measurements under…

Strongly Correlated Electrons · Physics 2011-08-26 Elena Hassinger , Dai Aoki , Georg Knebel , Jacques Flouquet

Following long-standing predictions associated with hydrogen, high-temperature superconductivity has recently been observed in several hydride-based materials. Nevertheless, these high-$T_c$ phases only exist at extremely high pressures,…

Motivated by the recent discovery of near-room temperature superconductivity in high-pressure superhydrides, we investigate from first-principles the high-pressure superconducting phase diagram of the ternary Ca-B-H system, using ab-initio…

Superconductivity · Physics 2020-08-26 Simone Di Cataldo , Wolfgang von der Linden , Lilia Boeri

The discovery of ambient superconductivity would mark an epochal breakthrough long-awaited for over a century, potentially ushering in unprecedented scientific and technological advancements. The recent findings on high-temperature…

Hydrogen in metals is a significant research area with far-reaching implications, encompassing diverse fields such as hydrogen storage, metal-insulator transitions, and the recently emerging phenomenon of room-temperature ($\textit{$T_C$}$)…

Superconductivity · Physics 2023-11-30 Heejung Kim , Ina Park , J. H. Shim , D. Y. Kim

Recently YH6, compound from a group of theoretically predicted stable compressed MH6 hydrides (M/ Ca, Mg, Y, Sc) with bcc Im-3m crystal structure, was successfully experimentally realized. Superconductivity of pressurized YH6 was confirmed…

Superconductivity · Physics 2021-11-12 Pavol Baňacký , Jozef Noga

Recent computational studies confirmed by experiment have established the occurrence of superconducting temperatures, $T_c$, near 200 K when the pressure is close to 200 GPa in the compound H$_3S$. Motivated by these findings we investigate…

Superconductivity · Physics 2017-03-10 D. A. Papaconstantopoulos

High pressure electrical resistance and x-ray diffraction measurements have been performed on ruthenium-doped Ba(Fe0.9Ru0.1)2As2, up to pressures of 32 GPa and down to temperatures of 10 K, using designer diamond anvils under…

Superconductivity · Physics 2014-04-15 Walter Uhoya , Georgiy M. Tsoi , Yogesh K. Vohra , Athena S. Sefat , Samuel T. Weir

Metallic hydrogen is capable of showing room temperature superconductivity, but its experimental syntheses are extremely hard. Therefore, it is desirable to reduce the synthesis pressure of metallic hydrogen by adding other chemical…

Superconductivity · Physics 2022-11-23 Zhongyu Wan , Ruiqin Zhang

BaFe2Se3 is a potential superconductor material exhibiting transition at 11 K and ambient pressure. Here we extended the structural and performed electrical resistivity measurements on this compound up to 51 GPa and 20 GPa, respectively, in…