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Application of current and near-term quantum hardware to the electronic structure problem is highly limited by qubit counts, coherence times, and gate fidelities. To address these restrictions within the variational quantum eigensolver…

Quantum Physics · Physics 2020-11-24 Robert A. Lang , Ilya G. Ryabinkin , Artur F. Izmaylov

Although a universal quantum computer is still far from reach, the tremendous advances in controllable quantum devices, in particular with solid-state systems, make it possible to physically implement "quantum simulators". Quantum…

Quantum Physics · Physics 2016-06-08 Zhixin Wang , Xiu Gu , Lian-Ao Wu , Yu-xi Liu

We have applied the Finite Element Method to the self-consistent electronic structure calculations of molecules and solids for the first time. In this approach all the calculations are performed in "real space" and the use of non-uniform…

mtrl-th · Physics 2009-10-28 Eiji Tsuchida , Masaru Tsukada

The authors present SHarmonic, a new implementation of the spherical harmonics targeted for electronic-structure calculations. Their approach is to use explicit formulas for the harmonics written in terms of normalized Cartesian…

Computational Physics · Physics 2025-10-08 Xavier Andrade , Jacopo Simoni , Yuan Ping , Tadashi Ogitsu , Alfredo A. Correa

Classical or quantum physical systems can simulate the Ising Hamiltonian for large-scale optimization and machine learning. However, devices such as quantum annealers and coherent Ising machines suffer an exponential drop in the probability…

Optics · Physics 2024-01-09 Marcello Calvanese Strinati , Claudio Conti

Solving the electronic Schr\"odinger equation for changing nuclear coordinates provides access to the Born-Oppenheimer potential energy surface. This surface is the key starting point for almost all theoretical studies of chemical processes…

Chemical Physics · Physics 2022-01-14 Markus Reiher

By expressing the electronic wavefunction in an explicitly-correlated (Jastrow-factorised) form, a similarity-transformed effective Hamiltonian can be derived. The effective Hamiltonian is non-Hermitian and contains three-body interactions.…

Chemical Physics · Physics 2019-08-09 Aron J. Cohen , Hongjun Luo , Kai Guther , Werner Dobrautz , David P. Tew , Ali Alavi

Simulation of quantum systems is notoriously challenging for classical computers, while quantum hardware is naturally well-suited for this task. However, the imperfections of contemporary quantum systems poses a considerable challenge in…

Quantum Physics · Physics 2025-01-10 Yotam Shapira , Jovan Markov , Nitzan Akerman , Ady Stern , Roee Ozeri

One of the main bottlenecks in solving combinatorial optimization problems with quantum annealers is the qubit connectivity in the hardware. A possible solution for larger connectivty is minor embedding. This techniques makes the…

Quantum Physics · Physics 2024-05-24 Michele Cattelan , Jemma Bennett , Sheir Yarkoni , Wolfgang Lechner

Hamiltonian simulation is a fundamental algorithm in quantum computing that has attracted considerable interest owing to its potential to efficiently solve the governing equations of large-scale classical systems. Exponential speedup…

Quantum Physics · Physics 2025-08-14 Shoya Sasaki , Katsuhiro Endo , Mayu Muramatsu

We present an exact simulation of a one-dimensional transverse Ising spin chain with a quantum computer. We construct an efficient quantum circuit that diagonalizes the Ising Hamiltonian and allows to obtain all eigenstates of the model by…

Quantum Physics · Physics 2018-12-24 Alba Cervera-Lierta

Solving the electronic structure problem via unitary evolution of the electronic Hamiltonian is one of the promising applications of digital quantum computers. One of the practical strategies to implement the unitary evolution is via…

Quantum Physics · Physics 2023-08-23 Luis A. Martínez-Martínez , Tzu-Ching Yen , Artur F. Izmaylov

Many combinatorial optimization problems can be mapped to finding the ground states of the corresponding Ising Hamiltonians. The physical systems that can solve optimization problems in this way, namely Ising machines, have been attracting…

Emerging Technologies · Computer Science 2017-10-16 Tianshi Wang , Jaijeet Roychowdhury

Digital-analog is a quantum computational paradigm that employs the natural interaction Hamiltonian of a system as the entangling resource, combined with single qubit gates, to implement universal quantum operations. As in the case of its…

Quantum Physics · Physics 2026-03-11 Mikel Garcia-de-Andoin , Thorge Müller , Gonzalo Camacho

Quantum computers have the potential for an exponential speedup of classical molecular computations. However, existing algorithms have limitations; quantum phase estimation (QPE) algorithms are intractable on current hardware while…

Quantum Physics · Physics 2023-03-03 Scott E. Smart , David A. Mazziotti

Ising machines are hardware solvers which aim to find the absolute or approximate ground states of the Ising model. The Ising model is of fundamental computational interest because it is possible to formulate any problem in the complexity…

Quantum Physics · Physics 2022-04-04 Naeimeh Mohseni , Peter L. McMahon , Tim Byrnes

A highly anticipated use of quantum computers is the simulation of complex quantum systems including molecules and other many-body systems. One promising method involves directly applying a linear combination of unitaries (LCU) to…

Quantum Physics · Physics 2022-02-02 Richard Meister , Simon C. Benjamin , Earl T. Campbell

The rigorous approach aimed at providing exact analytical results for hybrid classical-quantum models is elaborated on the grounds of generalized algebraic mapping transformations. This conceptually simple method allows one to obtain novel…

Statistical Mechanics · Physics 2015-05-19 Jozef Strecka

Recent improvements in control of quantum systems make it seem feasible to finally build a quantum computer within a decade. While it has been shown that such a quantum computer can in principle solve certain small electronic structure…

Quantum Physics · Physics 2016-09-27 Bela Bauer , Dave Wecker , Andrew J. Millis , Matthew B. Hastings , M. Troyer

We present a method for the calculation of electronic structure of systems that contain tens of thousands of atoms. The method is based on the division of the system into mutually overlapping fragments and the representation of the…

Materials Science · Physics 2011-03-09 Nenad Vukmirović , Lin-Wang Wang