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Modern electronic devices are unthinkable without the well-controlled formation of interfaces at heterostructures. These often involve at least one amorphous material. Modeling such interfaces poses a significant challenge, since a…

Computational Physics · Physics 2015-06-17 L. E. Hintzsche , C. M. Fang , M. Marsman , M. W. P. E. Lamers , A. W. Weeber , G. Kresse

Advancing new ideas of rechargeable batteries represents an important path to meeting the ever increasing energy storage needs. Recently we showed rechargeable sodium/chlorine (Na/Cl$_2$) (or lithium/chlorine Li/Cl$_2$) batteries that used…

Electrically induced reorientation of liquid crystals (LCs) is a fundamental phenomenon widely used in modern technologies. We observe experimentally an electro-optic effect in a cholesteric LC with a distinct oblique-helicoidal director…

Soft Condensed Matter · Physics 2015-06-19 Jie Xiang , Sergij V. Shiyanovskii , Corrie Imrie , Oleg D. Lavrentovich

Detailed understanding of solid-solid interface structure-function relations is critical for the improvement and wide deployment of all solid-state batteries. The interfaces between lithium phosphorous oxynitride ("LiPON") solid electrolyte…

Moving to larger cell formats in lithium-ion batteries increases overall useable energy but introduces inhomogeneities that influence aging. This study investigates degradation in 21700-type cells with NCM cathodes and graphite/SiOx anodes…

The rising demand for high-performing batteries requires new technological concepts. To facilitate fast charge and discharge, hierarchically structured electrodes offer short diffusion paths in the active material. However, there are still…

Achieving reversible anode-free solid-state batteries hinges on controlling alkali-metal plating and stripping at buried interfaces, yet the underlying nanoscale mechanisms remain unresolved. Here we introduce virtual-electrode low-energy…

Lithium-ion batteries rely on particulate porous electrodes to realize high performance, especially the fast-charging capability. To minimize the particle-wise reaction heterogeneities that may lead to local hot spots, deeper understandings…

Materials Science · Physics 2022-04-15 Shubham Agrawal , Peng Bai

Most next-generation Li-ion battery chemistries require a functioning lithium metal (Li) anode. However, its application in secondary batteries has been inhibited because of uncontrollable dendrite growth during cycling. Mechanical…

Materials Science · Physics 2017-01-11 Chen Xu , Zeeshan Ahmad , Asghar Aryanfar , Venkatasubramanian Viswanathan , Julia R. Greer

Photothermal (photonic) sintering crystallizes as-deposited amorphous LiCoO2 (LCO) cathodes for solid-state thin-film batteries using millisecond, surface-localized heating. However, process design often relies on 1D models with…

Materials Science · Physics 2026-04-28 Yang Hu , Benoit Sklénard , Wouter Vels , Yaroslav E. Romanyuk , Vladyslav Turlo

A 3D mechanical stable scaffold is shown to accommodate the volume change of a high specific capacity nickel-tin nanocomposite Li-ion battery anode. When the nickel-tin anode is formed on an electrochemically inactive conductive scaffold…

Materials Science · Physics 2015-04-28 Huigang Zhang , Tan Shi , Paul V. Braun

Wadsley--Roth crystallographic shear phases form a family of compounds that have attracted attention due to their excellent performance as lithium-ion battery electrodes. The complex crystallographic structure of these materials poses a…

Materials Science · Physics 2019-09-26 Can P. Koçer , Kent J. Griffith , Clare P. Grey , Andrew J. Morris

In the realm of colloidal nanostructures, with its immense capacity for shape and dimensionality control, the form is undoubtedly a driving factor for the tunability of optical and electrical properties in semiconducting or metallic…

The design of solid state batteries with lithium anodes is attracting attention for the prospect of high capacity and improved safety over liquid electrolyte systems. The nature of transport with lithium as the current carrier has as a…

Materials Science · Physics 2024-10-14 Mostafa Faghih Shojaei , Rahul Gulati , Krishna Garikipati

Amorphous silicon is a highly promising anode material for next-generation lithium-ion batteries. Large volume changes of the silicon particle have a critical effect on the surrounding solid-electrolyte interphase (SEI) due to repeated…

Numerical Analysis · Mathematics 2024-09-12 Raphael Schoof , Giuseppe Fabian Castelli , Willy Dörfler

The lithium (Li) metal anode is essential for next generation high energy density rechargeable Li metal batteries. Although extensive studies have been performed to prolong the cycle life of Li metal batteries, the calendar life, which…

Materials Science · Physics 2022-04-26 Bingyu Lu , Weikang Li , Diyi Cheng , Miguel Ceja , Wurigumula Bao , Chengcheng Fang , Ying Shirley Meng

A high reversible capacity is a key feature for any rechargeable battery. In the lithium-ion battery technology, tin-oxide anodes do fulfill this requirement, but a fast loss of capacity hinders a full commercialization. Using…

Materials Science · Physics 2015-09-23 Andreas Pedersen , Petr A. Khomyakov , Mathieu Luisier

Li-Ion Solid-State Electrolytes (Li-SSEs) are a promising solution that resolves the critical issues of conventional Li-Ion Batteries (LIBs) such as poor ionic conductivity, interfacial instability, and dendrites growth. In this study, a…

Materials Science · Physics 2022-02-15 Seungpyo Kang , Minseon Kim , Kyoungmin Min

Alkali metal ion batteries, and in particular Li-ion batteries, have become a key technology for current and future energy storage, already nowadays powering many devices of our daily lives. Due to the inherent complexity of batteries and…

Materials Science · Physics 2021-12-14 Holger Euchner , Axel Groß

Newly designed Li-ion battery cathode materials with high capacity and greater flexibility in chemical composition will be critical for the growing electric vehicles market. Cathode structures with cation disorder were once considered…

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