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Two novel two-dimensional carbon allotropes comprised of octagons and pentagons are proposed based on the first-principles calculations. The two carbon allotropes, named OPG-L and OPG-Z, are found to have distinct properties. OPG-L is…

Materials Science · Physics 2013-08-13 Cong Su , Hua Jiang , Ji Feng

A novel crystalline structure of hybrid monolayer hexagonal boron nitride (BN) and graphene is predicted by means of the first-principles calculations. This material can be derived via boron or nitrogen atoms substituted by carbon atoms…

Mesoscale and Nanoscale Physics · Physics 2013-10-25 Jinyun Li , Daqiang Gao , Xiaoning Niu , Mingsu Si , Desheng Xue

A three-dimensional elemental carbon Kagome lattice (CKL), made of only fourfold coordinated carbon atoms, is proposed based on first-principles calculations. Despite the existence of 60{\deg} bond angles in the triangle rings, widely…

Materials Science · Physics 2015-10-20 Yuanping Chen , Y. Y. Sun , H. Wang , D. West , Yuee Xie , J. Zhong , V. Meunier , Marvin L. Cohen , S. B. Zhang

We introduce 3D-DPhyne, a novel three-dimensional (3D) carbon allotrope derived from the dodecaphenylyne framework, and investigate its structural, electronic, optical, and mechanical properties using first-principles calculations. The…

Insulating-metallic transition mediated by substitutional atoms is predicted in a series of two-dimensional carbon-based structures. Introducing Si atoms in selected sites of tetrahexcarbon [Carbon 137 (2018) 266] according to rational…

Materials Science · Physics 2022-02-16 Alejandro Lopez-Bezanilla , Peter B. Littlewood

Three new novel phases of carbon nitride (CN) bilayer, which are named as \alpha-C$_{2}$N$_{2}$, \beta-C$_{2}$N$_{2}$ and \gamma-C$_{4}$N$_{4}$, respectively, have been predicted in this paper. All of them are consisted of two CN sheets…

Materials Science · Physics 2019-02-01 Wanxing Lin , Shi-Dong Liang , Chunshan He , Wucheng Xie , Haiying He , Quanxiang Mai , Jiesen Li , D. X. Yao

Using an evolutionary algorithm in combination with first-principles density functional theory calculations, we identify two-dimensional (2D) CaP$_3$ monolayer as a new Dirac semimetal due to inversion and nonsymmorphic spatial symmetries…

Materials Science · Physics 2023-03-06 Seoung-Hun Kang , Wei Luo , Sinchul Yeom , Yaling Zheng , Mina Yoon

We present the theory and implementation of a highly efficient relativistic third-order algebraic diagrammatic construction [ADC(3)] method based on a four-component (4c) Dirac-Coulomb (DC) Hamiltonian for the calculation of ionization…

Chemical Physics · Physics 2024-11-01 Sudipta Chakraborty , Tamoghna Mukhopadhyay , Malaya K. Nayak , Achintya Kumar Dutta

Carbon doping is used to obtain semi-insulating GaN crystals. If the carbon doping concentration exceeds $5*10^{17}$ $cm^{-3}$, the carbon atoms increasingly form triatomic clusters. The tri-carbon defect structure is unambiguously proven…

We analyze the effects of sp^2/sp^3 bond-aspect ratio on the transport properties of amorphous carbon quasi-1D structures where structural disorder varies in a very non-linear manner with the effective bandgap. Using a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Mikhail V. Katkov , Somnath Bhattacharyya

First-principles calculation was used to study the structural and electronic features of the low dimensional oxide structure, SrTiO_{3}/Sr_{1-x}La_{x}TiO_{3} (x=0.25) superlattices, constructed by submonolayer low dimensional La doping into…

Strongly Correlated Electrons · Physics 2015-05-27 P. V. Ong , Jaichan Lee , Warren E. Pickett

Silicon (Si) is one of the most extensively studied materials owing to its significance to semiconductor science and technology. While efforts to find a new three-dimensional (3D) Si crystal with unusual properties have made some progress,…

Materials Science · Physics 2018-02-23 Kisung Chae , Duck Young Kim , Young-Woo Son

Based on density functional theory the noncentrosymmetric superconductor Mo_3Al_2C in its well established {\beta}-Mn type ($P4_{1}32$) crystal structure is investigated. In particular, its thermodynamical and dynamical stabilities are…

Materials Science · Physics 2013-05-30 D. Reith , C. Blaas-Schenner , R. Podloucky

Recently, a new carbon 3D carbon allotrope named pentadiamond was proposed. Pentadiamond is composed of carbon atoms in mixed sp$^2$ and sp$^3$-like hybridization. In this work, we have carried out a detailed investigation of the electronic…

Materials Science · Physics 2021-02-03 Raphael M. Tromer , Levy C. Felix , Cristiano F. Woellner , Douglas S. Galvao

We propose previously unknown allotropes of phosphorus carbide (PC) in the stable shape of an atomically thin layer. Different stable geometries, which result from the competition between sp2 bonding found in graphitic C and sp3 bonding…

Materials Science · Physics 2016-05-25 Jie Guan , Dan Liu , Zhen Zhu , David Tomanek

The phonon properties, electronic structures and optical properties of novel carbon allotropes, such as monolayer penta-graphene (PG), double-layer PG and T12-carbon, were explored by means of first-principles calculations. Results of…

Using evolutionary algorithm for crystal structure prediction, we present a new stable two-dimensional (2D) carbon allotrope composed of polymerized as-indacenes (PAI) in a zigzag pattern, namely PAI-graphene whose energy is lower than most…

Materials Science · Physics 2020-09-11 Xin Chen , Adrien Bouhon , Linyang Li , François M. Peeters , Biplab Sanyal

Based on the first-principles calculations, we recover the silent topological nature of Cd3As2, a well known semiconductor with high carrier mobility. We find that it is a symmetry-protected topological semimetal with a single pair of…

Materials Science · Physics 2014-04-21 Zhijun Wang , Hongming Weng , Quansheng Wu , Xi Dai , Zhong Fang

Based on recently synthesized Ni3C12S12 class 2D metal-organic frameworks, we predict electronic properties of M3C12S12 and M3C12O12, where M is Zn, Cd, Hg, Be, or Mg with no M orbital contributions to bands near Fermi level. For M3C12S12,…

Materials Science · Physics 2016-12-22 Menghao Wu , Zhijun Wang , Junwei Liu , Huahua Fu , Lei Sun , Xin Liu , Minghu Pan , Hongming Weng , Mircea Dinca , Liang Fu , Ju Li

A small percentage of dopant atoms can completely change the physical properties of the host material. For example, chemical doping controls the electronic transport behavior of semiconductors and gives rise to a wide range of emergent…