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An extended electron model fully recovers many of the experimental results of quantum mechanics while it avoids many of the pitfalls and remains generally free of paradoxes. The formulation of the many-body electronic problem here resembles…

Computational Physics · Physics 2018-12-03 Thomas Pope , Werner Hofer

In this paper, we show how to study the evolution of a system, given imprecise knowledge about the state of the system and the dynamics laws. Our approach is based on Fuzzy Set Theory, and it will be shown that the \emph{Fuzzy Dynamics} of…

Data Analysis, Statistics and Probability · Physics 2015-06-19 Uziel Sandler

We present results showing an improvement of the accuracy of perturbation theory as applied to cosmological structure formation for a useful range of scales. The Lagrangian theory of gravitational instability of Friedmann--Lema\^\i tre…

Astrophysics · Physics 2009-09-25 A. L. Melott , T. Buchert , A. G. Weiß

Although the post-Newtonian Lagrangian formalism is widely used in relativistic dynamical and statistical studies of test bodies moving around arbitrary mass distributions, the corresponding general Hamiltonian formalism is still relatively…

General Relativity and Quantum Cosmology · Physics 2021-03-23 Ronaldo S. S. Vieira , Javier Ramos-Caro , Alberto Saa

Understanding the behaviour of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process…

Quantum Physics · Physics 2021-11-01 Sapphire Lally , Nicholas Werren , Jim Al-Khalili , Andrea Rocco

We present a new method to calculate formation of cosmological structure in the Newtonian limit. The method is based on Lagrangian perturbation theory plus two key theoretical extensions. One advance involves identifying and fixing a…

Cosmology and Nongalactic Astrophysics · Physics 2014-12-15 Sharvari Nadkarni-Ghosh , David F. Chernoff

Born-Oppenheimer Molecular Dynamics (BOMD) is a powerful but expensive technique. The main bottleneck in a density functional theory bomd calculation is the solution to the Kohn-Sham (KS) equations, that requires an iterative procedure that…

Chemical Physics · Physics 2021-09-23 Etienne Polack , Geneviève Dusson , Benjamin Stamm , Filippo Lipparini

We introduce a novel approach for a fully quantum description of coupled electron-ion systems from first principles. It combines the variational quantum Monte Carlo (QMC) solution of the electronic part with the path integral (PI) formalism…

Chemical Physics · Physics 2018-03-06 Félix Mouhat , Sandro Sorella , Rodolphe Vuilleumier , Antonino M. Saitta , Michele Casula

As a network-based functional approximator, we have proposed a "Lagrangian Density Space-Time Deep Neural Networks" (LDDNN) topology. It is qualified for unsupervised training and learning to predict the dynamics of underlying physical…

Quantum Physics · Physics 2022-07-26 Bhupesh Bishnoi

This work builds on the Volterra series formalism presented in [D. W. Dreisigmeyer and P. M. Young, J. Phys. A \textbf{36}, 8297, (2003)] to model nonconservative systems. Here we treat Lagrangians and actions as `time dependent' Volterra…

Classical Physics · Physics 2015-09-17 David W. Dreisigmeyer , Peter M. Young

To provide a unified theoretical framework ranging from a cellular-level excitation mechanism to organic-level geometric propagation, a new theory inspired by quantum electrodynamic theory for light propagation is proposed by describing the…

General Physics · Physics 2013-10-14 Sehun Chun

This paper concerns the representation of angular momentum operators in the Born-Oppenheimer theory of polyatomic molecules and the various forms of the associated conservation laws. Topics addressed include the question of whether these…

Chemical Physics · Physics 2023-03-22 Robert Littlejohn , Jonathan Rawlinson , Joseph Subotnik

Guided by the symmetries of the Euler-Lagrange equations of motion, a study of the constrained dynamics of singular Lagrangians is presented. We find that these equations of motion admit a generalized Lie symmetry, and on the Lagrangian…

Mathematical Physics · Physics 2020-06-05 Achilles D. Speliotopoulos

The success of first principles electronic structure calculation for predictive modeling in chemistry, solid state physics, and materials science is constrained by the limitations on simulated length and time scales due to computational…

Materials Science · Physics 2018-12-19 Albert P. Bartok , James Kermode , Noam Bernstein , Gabor Csanyi

Within the context of first principles techniques we present a theoretical and computational framework to quickly determine, at finite momentum, the self-consistent (longitudinal) charge response to an external perturbation, that enters the…

Materials Science · Physics 2025-06-10 Francesco Macheda , Paolo Barone , Francesco Mauri

Forty-five years after the point de d\'epart [1] of density functional theory, its applications in chemistry and the study of electronic structures keep steadily growing. However, the precise form of the energy functional in terms of the…

Chemical Physics · Physics 2019-10-29 Philippe Blanchard , José M. Gracia-Bondía , Joseph C. Várilly

This note provides an introduction to molecular dynamics, the computational implementation of the theory of statistical physics. The discussion is focused on the properties of Langevin dynamics, a degenerate stochastic differential equation…

Analysis of PDEs · Mathematics 2021-12-16 Gabriel Stoltz

The development and implementation of increasingly accurate methods for electronic structure calculations mean that, for many atomistic simulation problems, treating light nuclei as classical particles is now one of the most serious…

Materials Science · Physics 2016-02-12 Venkat Kapil , Joost VandeVondele , Michele Ceriotti

We explain why the conventional argument for deriving the time-dependent Born-Oppenheimer approximation is incomplete and review recent mathematical results, which clarify the situation and at the same time provide a systematic scheme for…

Mathematical Physics · Physics 2007-12-31 Gianluca Panati , Herbert Spohn , Stefan Teufel

A rigorous two-thermostat formulation for ab-initio molecular dynamics using the fictitious Lagrangian approach is presented. It integrates the concepts of mass renormalization and temperature control for the wave functions. The new…

Materials Science · Physics 2009-11-07 Peter E. Bloechl
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