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A combined mid-IR spectrum of five colliding-wind, massive, dust-producing Population I Wolf-Rayet (WR) binaries shows a wealth of absorption and emission details coming from the circumstellar dust envelopes, as well as from the…

Solar and Stellar Astrophysics · Physics 2017-04-19 S. V. Marchenko , A. F. J. Moffat

We present a new method to decompose the emission features of polycyclic aromatic hydrocarbons (PAHs) from mid-infrared spectra using theoretical PAH templates in conjunction with modified blackbody components for the dust continuum and an…

Astrophysics of Galaxies · Physics 2018-06-26 Yanxia Xie , Luis C. Ho , Aigen Li , Jinyi Shangguan

Emission from a class of benzene-based molecules known as Polycyclic Aromatic Hydrocarbons (PAHs) dominates the infrared spectrum of star-forming regions. The observed emission appears to arise from the combined emission of numerous PAH…

Instrumentation and Methods for Astrophysics · Physics 2014-03-20 Kevin H. Knuth , Man Kit Tse , Joshua Choinsky , Haley A. Maunu , Duane F. Carbon

The mid-infrared (IR; 5-15~$\mu$m) spectrum of a wide variety of astronomical objects exhibits a set of broad emission features at 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m. About 30 years ago it was proposed that these signatures are due to…

Astrophysics of Galaxies · Physics 2014-07-02 Marissa J. F. Rosenberg , Olivier Berné , Christiaan Boersma

It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…

Astrophysics of Galaxies · Physics 2018-01-22 Norio Ota

The electronic spectra of gas-phase cationic polycyclic aromatic hydrocarbons (PAHs), trapped in the Fourier Transform Ion Cyclotron Resonance cell of the PIRENEA experiment, have been measured by multiphoton dissociation spectroscopy in…

Chemical Physics · Physics 2015-03-13 F. Useli-Bacchitta , A. Bonnamy , G. Mulas , G. Malloci , D. Toublanc , C. Joblin

Polycyclic Aromatic Hydrocarbons (PAHs) have been detected throughout the universe where they play essential roles in the evolution of their environments. For example, they are believed to affect atmospheric loss rates of close-in planets…

Earth and Planetary Astrophysics · Physics 2024-11-13 Fabian Grübel , Karan Molaverdikhani , Barbara Ercolano , Christian Rab , Oliver Trapp , Dwaipayan Dubey , Rosa Arenales-Lope

We present the synthesis and laboratory rotational spectroscopy of the 7-ring polycyclic aromatic hydrocarbon (PAH) cyanocoronene (C$_{24}$H$_{11}$CN) using a laser-ablation assisted cavity-enhanced Fourier transform microwave spectrometer.…

The integrated luminosity from the features of the polycyclic aromatic hydrocarbons (PAHs) exceeds the luminosity from atomic and molecular emission lines in the star-forming regions in galaxies and is a potential tracer of galaxy-scale…

The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric…

Earth and Planetary Astrophysics · Physics 2016-05-20 Ahmed Mahjoub , Martin Schwell , Nathalie Carrasco , Yves Benilan , Guy Cernogora , Cyril Szopa , Marie-Claire Gazeau

Small organic molecules are thought to provide building blocks for the formation of complex interstellar polycyclic aromatic hydrocarbons (PAHs). However, the underlying chemical mechanisms remain unclear, particularly concerning the role…

Astrophysics of Galaxies · Physics 2020-09-17 Meriem Hanine , Zhisen Meng , Shiru Lu , Peng Xie , Sylvain Picaud , Michel Devel , Zhao Wang

Infrared (IR) absorption spectra of individual polycyclic aromatic hydrocarbons (PAHs) containing methyl (-CH3), methylene (>CH2), or diamond-like *CH groups and IR spectra of mixtures of methylated and hydrogenated PAHs prepared by gas…

Recent observations have shown the presence of dust and molecular material in galactic winds, but relatively little is known about the distribution of these outflow components. To shed some light on this issue, we have used IRAC images from…

Cosmology and Nongalactic Astrophysics · Physics 2013-07-25 Alexander McCormick , Sylvain Veilleux , David S. N. Rupke

Polycyclic aromatic hydrocarbons (PAHs) are among the most ubiquitous compounds in the universe, accounting for up to ~25% of all interstellar carbon. Since most unsubstituted PAHs do not possess permanent dipole moments, they are invisible…

While powerful techniques exist to accurately account for anharmonicity in vibrational molecular spectroscopy, they are computationally very expensive and cannot be routinely employed for large species and/or at non- zero vibrational…

Chemical Physics · Physics 2018-10-17 Giacomo Mulas , Cyril Falvo , Patrick Cassam-Chenaï , Christine Joblin

We investigate the evolution of polycyclic aromatic hydrocarbon (PAH) abundance in a galaxy, which is a crucial step to understand the evolution of bright emission features in the mid-infrared range. We calculate the evolution of dust grain…

Astrophysics of Galaxies · Physics 2019-09-25 Shiau-Jie Rau , Hiroyuki Hirashita , Maria Sergeevna Murga

Using the AKARI, Wide-field Infrared Survey Explorer (WISE), Infrared Astronomical Satellite (IRAS), Sloan Digital Sky Survey (SDSS) and Hubble Space Telescope (HST) data, we investigated the relation of polycyclic aromatic hydrocarbon…

The 11.3 $\mu$m emission feature is a prominent member of the family of unidentified infrared emission (UIE) bands and is frequently attributed to out-of-plane bending modes of polycyclic aromatic hydrocarbon (PAH) molecules. We have…

Solar and Stellar Astrophysics · Physics 2015-07-15 SeyedAbdolreza Sadjadi , Yong Zhang , Sun Kwok

The physical mechanism producing Anomalous Microwave Emission (AME) has been an unresolved puzzle for close to 30 years. One candidate mechanism is rotational emission from polycyclic aromatic hydrocarbons (PAHs) which can have the…

Astrophysics of Galaxies · Physics 2026-01-29 Dylan M. Pare , David T. Chuss , Danielle Sponseller , Brandon Hensley , Alan Kogut