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A systematic approach for the construction of a density functional for van der Waals interactions that also accounts for saturation effects is described, i.e. one that is applicable at short distances. A very efficient method to calculate…

Condensed Matter · Physics 2009-10-31 Henrik Rydberg , Bengt I. Lundqvist , David C. Langreth , Maxime Dion

It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no…

Materials Science · Physics 2009-11-11 Svetla D. Chakarova Kack , Elsebeth Schroder , Bengt I. Lundqvist , David C. Langreth

We present a new method for solving the Schrodinger equation using the Lossless Transmission Line Model (LTL). The LTL model although extensively used in fiber optics and optical fiber design, it has not yet found application in solid state…

General Physics · Physics 2016-06-16 C. D. Papageorgiou , A. C. Boucouvalas , T. E. Raptis

We present a computational scheme for orbital-free density functional theory (OFDFT) that simultaneously provides access to all-electron values and preserves the OFDFT linear scaling as a function of the system size. Using the projector…

Computational Physics · Physics 2014-12-23 J. Lehtomäki , I. Makkonen , M. A. Caro , A. Harju , O. Lopez-Acevedo

The random phase approximation (RPA) is attracting renewed interest as a universal and accurate method for first-principles total energy calculations. The RPA naturally accounts for long-range dispersive forces without compromising accuracy…

Materials Science · Physics 2013-03-04 Thomas Olsen , Kristian S. Thygesen

In this work, we present a computationally efficient methodology that utilizes a local real-space formulation of the projector augmented wave (PAW) method discretized with a finite-element (FE) basis to enable accurate and large-scale…

Computational Physics · Physics 2025-01-03 Kartick Ramakrishnan , Sambit Das , Phani Motamarri

Stacking and twisting 2D van der Waals (vdW) layers have become versatile platforms to tune electron correlation. These platforms rely on exfoliating vdW materials down to a single and few vdW layers. We calculate the intrinsic…

GW approximation is one of the most popular parameter-free many-body methods that goes beyond the limitations of the standard density functional theory (DFT) to determine the excitation spectra for moderately correlated materials and in…

Materials Science · Physics 2023-12-12 Kristjan Haule , Subhasish Mandal

We evaluate the van der Waals (vdW) interaction energy at zero temperature between two undoped strained graphene layers separated by a finite distance. We consider the following three models for the anisotropic case: (a) where one of the…

Materials Science · Physics 2014-06-25 Anand Sharma , Peter Harnish , Alexander Sylvester , Valeri N. Kotov , A. H. Castro Neto

We have computed the surface energies, work functions, and interlayer surface relaxations of clean (111), (110), and (100) surfaces of Al, Cu, Ru, Rh, Pd, Ag, Pt, and Au. Many of these metallic surfaces have technological or catalytic…

Materials Science · Physics 2022-06-01 Abhirup Patra , Jefferson E. Bates , Jianwei Sun , John P. Perdew

We describe a robust method for determining Pipek-Mezey (PM) Wannier functions (WF), recently introduced by J\'onsson et al. (J. Chem. Theor. Chem. 2017, 13, 460), which provide some formal advantages over the more common Boys (also known…

Chemical Physics · Physics 2024-07-30 Marjory C. Clement , Xiao Wang , Edward F. Valeev

A simplification of the VV10 van der Waals density functional [J. Chem. Phys. 133, 244103 (2010)] is made by an approximation of the integrand of the six-dimentional integral in terms of a few products of three-dimensional density-like…

Chemical Physics · Physics 2026-01-21 Dimitri N. Laikov

Energy functionals of the Green's function can simultaneously provide spectral and thermodynamic properties of interacting electrons' systems. Though powerful in principle, these formulations need to deal with dynamical…

Materials Science · Physics 2024-05-28 Tommaso Chiarotti , Andrea Ferretti , Nicola Marzari

The localisation of electrons in a lattice potential is an quantum-mechanical phenomenon and is often associated with remarkable physical properties of solids involving electron spins, electric polarisations and topological effects. In…

The quantity w^N(r) = ( 1/ k^2 T_el)[partial n(r, T_el) / partial T_el]_(v(r),N) is introduced as a convenient measure of the local isoelectronic reactivity of surfaces. It characterizes the local polarizability of the surface and it can be…

mtrl-th · Physics 2009-10-30 Steffen Wilke , Morrel H. Cohen , Matthias Scheffler

We formulate a Hartree-Fock-LAPW method for electronic band structure calculations. The method is based on the Hartree-Fock-Roothaan approach for solids with extended electron states and closed core shells where the basis functions of…

Materials Science · Physics 2016-08-31 A. V. Nikolaev , P. N. Dyachkov

An efficient numerical method to compute solitary wave solutions to the free surface Euler equations is reported. It is based on the conformal mapping technique combined with an efficient Fourier pseudo-spectral method. The resulting…

Fluid Dynamics · Physics 2020-02-20 Denys Dutykh , Didier Clamond

Unconstrained partial-wave amplitudes obtained at discrete energies from fits to complete sets of eight independent observables which are required to uniquely reconstruct reaction amplitudes do not vary smoothly with energy, and are in…

A local approximation for dynamic polarizability leads to a nonlocal functional for the long-range dispersion interaction energy via an imaginary-frequency integral. We analyze several local polarizability approximations and argue that the…

Chemical Physics · Physics 2015-03-17 Oleg A. Vydrov , Troy Van Voorhis

In order to increase the accuracy of the linearized augmented plane wave method (LAPW) we present a new approach where the plane wave basis function is augmented by two different atomic radial components constructed at two different…

Materials Science · Physics 2015-12-10 A. V. Nikolaev , D. Lamoen , B. Partoens