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Quantum interference can profoundly affect charge transport in single molecules, but experiments can usually measure only the conductance at the Fermi energy. Because in general the most pronounced features of the quantum interference are…

We study the transport through a molecular junction exhibiting interference effects. We show that these effects can still be observed in the presence of molecular vibrations if Coulomb repulsion is taken into account. In the Kondo regime,…

Strongly Correlated Electrons · Physics 2019-09-04 P. Roura-Bas , F. Güller , L. Tosi , A. A. Aligia

Destructive quantum interference in molecular junctions might be used to build molecular quantum rulers, allowing to quantify changes in external control parameters electrically. For this reason, it is important to understand which patterns…

Mesoscale and Nanoscale Physics · Physics 2025-07-10 Lukas Krieger , Gert-Ludwig Ingold , Fabian Pauly

We analyze quantum interference and decoherence effects in single-molecule junctions both experimentally and theoretically by means of the mechanically controlled break junction technique and density-functional theory. We consider the case…

Mesoscale and Nanoscale Physics · Physics 2012-09-26 Stefan Ballmann , Rainer Härtle , Pedro B. Coto , Marcel Mayor , Mark Elbing , Martin R. Bryce , Michael Thoss , Heiko B. Weber

Coherent electronic transport through individual molecules is crucially sensitive to quantum interference. Using exact diagonalization techniques, we investigate the zero-bias and zero-temperature conductance through $\pi$-conjugated…

Strongly Correlated Electrons · Physics 2015-05-14 Julian Rincon , K. Hallberg , S. Ramasesha

Destructive quantum interference in electron transport through molecules provides an unconventional route for suppressing electric current. In this work we introduce "interference vectors" for each interference and use them to characterize…

Mesoscale and Nanoscale Physics · Physics 2017-07-20 Panu Sam-ang , Matthew G. Reuter

Destructive quantum interference (DQI) in single molecule electronics is a purely quantum mechanical effect and entirely defined by inherent properties of the molecule in the junction such as its structure and symmetry. This definition of…

Mesoscale and Nanoscale Physics · Physics 2017-01-04 Xin Zhao , Victor Geskin , Robert Stadler

Quantum interference in coherent transport through single molecular rings may provide a mechanism to control current in molecular electronics. We investigate its applicability by using a single-particle Green function method combined with…

Mesoscale and Nanoscale Physics · Physics 2009-08-11 San-Huang Ke , Weitao Yang , Harold U. Baranger

The appealing feature of molecular electronics is the possibility of exploiting functionality built within a single molecule. This functionality can be employed, for example, for sensing or switching purposes. Thus, ideally, the associated…

Destructive quantum interference in single molecule electronics is an intriguing phe- nomenon; however, distinguishing quantum interference effects from generically low transmission is not trivial. In this paper, we discuss how quantum…

Mesoscale and Nanoscale Physics · Physics 2014-10-01 Jacob Lykkebo , Alessio Gagliardi , Alessandro Pecchia , Gemma C. Solomon

As the dimensions of a conductor approach the nano-scale, quantum effects will begin to dominate its behavior. This entails the exciting possibility of controlling the conductance of a device by direct manipulation of the electron wave…

Quantum interference effects and decoherence mechanisms in single-molecule junctions are analyzed employing a nonequilibrium Green's function approach. Electrons tunneling through quasi-degenerate states of a nanoscale molecular junction…

Mesoscale and Nanoscale Physics · Physics 2011-07-25 R. Härtle , M. Butzin , O. Rubio-Pons , M. Thoss

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

We look for manifestations of quantum interference effects in the Seebeck coefficient of a molecular junction, when the electronic conductance exhibits pronounced destructive interference features due to the presence of quasi-degenerate…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Lena Simine , Wei Jia Chen , Dvira Segal

An unresolved challenge facing electronics at a few-nm scale is that resistive channels start leaking due to quantum tunneling. This affects the performance of nanoscale transistors, with single-molecule devices displaying particularly low…

The realization of self-assembled molecular-electronic films, whose room-temperature transport properties are controlled by quantum interference (QI), is an essential step in the scale-up QI effects from single molecules to parallel arrays…

The subtle and fundamental issue of indistinguishability and interference between independent pathways to the same target state is examined in the context of coherent control of atomic and molecular processes, with emphasis placed on…

Quantum Physics · Physics 2015-05-18 Jiangbin Gong , Paul Brumer

Using exact-diagonalization techniques supplemented by a Dyson equation embedding procedure, the transport properties of multilevel quantum dots are investigated in the Kondo regime. The conductance can be decomposed into the contributions…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 C. A. Büsser , G. B. Martins , K. A. Al-Hassanieh , Adriana Moreo , Elbio Dagotto

Interference is widely regarded as a foundational attribute of quantum mechanics. However, for a given experimental arrangement, interference can either contribute or not contribute to the outcome depending upon the basis in which it is…

Atomic Physics · Physics 2024-02-08 Adrien Devolder , Timur V. Tscherbul , Paul Brumer

We give a detailed discussion of the Quantum Interference Effect Transistor (QuIET), a proposed device which exploits interference between electron paths through aromatic molecules to modulate current flow. In the off state, perfect…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Charles A. Stafford , David M. Cardamone , Sumit Mazumdar
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