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Attosecond chemistry involves developing strategies to manipulate electronic coherent waves in molecules, which can influence the outcome of photoinduced reactions. While recent progress in this field calls for investigations of…

Chemical Physics · Physics 2026-04-22 Evan Munaro-Langloÿs , Franck Lépine , Victor Despré

We theoretically investigate the transport properties of a weak coherent input field scattered by an ensemble of $\Lambda$-type atoms coupled to a one-dimensional photonic crystal waveguide. In our model, the atoms are randomly located in…

Quantum Physics · Physics 2018-08-15 Guo-Zhu Song , Ewan Munro , Wei Nie , Leong-Chuan Kwek , Fu-Guo Deng , Gui-Lu Long

Hybrid structures formed between organic molecules and inorganic quantum dots can accomplish unique photophysical transformations by taking advantage of their disparate properties. The electronic coupling between these materials is…

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

Using single-crystal transistors, we have performed a systematic experimental study of electronic transport through oxidized copper/rubrene interfaces as a function of temperature and bias. We find that the measurements can be reproduced…

Materials Science · Physics 2009-11-13 A. S. Molinari , I. Gutierrez Lezama , P. Parisse , T. Takenobu , Y. Iwasa , A. F. Morpurgo

We discuss the nature of charge transfer in molecular conductors upon connecting to two metallic contacts and imposing a voltage bias across them. The sign of the charge transfer (oxidation vs. reduction) depends on the position of the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Avik W. Ghosh , Ferdows Zahid , Supriyo Datta , Robert R. Birge

We report the fabrication and electron transport properties of nanoparticles self-assembled networks (NPSAN) of molecular switches (azobenzene derivatives) interconnected by Au nanoparticles, and we demonstrate optically-driven switchable…

Applied Physics · Physics 2018-10-09 Y. Viero , D. Guerin , A. Vladyka , F. Alibart , S. Lenfant , M. Calame , D. Vuillaume

We have investigated charge transport in ZnTPPdT-Pyr molecular junctions using the lithographic MCBJ technique at room temperature and cryogenic temperature (6K). We combined low-bias statistical measurements with spectroscopy of the…

Following the observation of coherent oscillations in non-linear spectra of photosynthetic pigment protein complexes, particularly phycobilliprotein such as PC645, coherent vibronic transport has been suggested as a design principle for…

Photoswitchable molecules display two or more isomeric forms that may be accessed using light. Separating the electronic absorption bands of these isomers is key to selectively addressing a specific isomer and achieving high photostationary…

We investigate the electron-transport properties of ethyne-bridged diphenyl zinc-porphyrin molecules suspended between gold (111) electrodes by first-principles calculations within the framework of density functional theory. It is found…

Materials Science · Physics 2024-01-09 Huy Duy Nguyen , Tomoya Ono

We investigate the possibility of optical current control through single molecules which are weakly coupled to leads. A master equation approach for the transport through a molecule is combined with a Floquet theory for the time-dependent…

Chemical Physics · Physics 2016-09-08 Jörg Lehmann , Sébastien Camalet , Sigmund Kohler , Peter Hänggi

Electromigrated nanoscale junctions have proven very useful for studying electronic transport at the single-molecule scale. However, confirming that conduction is through precisely the molecule of interest and not some contaminant or metal…

Mesoscale and Nanoscale Physics · Physics 2008-09-04 D. R. Ward , G. D. Scott , Z. K. Keane , N. J. Halas , D. Natelson

The realization of single-molecule thermal conductance measurements has driven the need for theoretical tools to describe conduction processes that occur over atomistic length scales. In macroscale systems, the principle that is typically…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Galen T. Craven , Abraham Nitzan

We report the formation of self-assembled monolayers of a molecular photoswitch (azobenzene-bithiophene derivative, AzBT) on cobalt via a thiol covalent bond. We study the electrical properties of the molecular junctions formed with the tip…

Coherent electron transport is investigated in a molecular device made of polymeric chain sandwiched between two metallic electrodes. Molecular system is described by a simple Huckel model, while the coupling to the electrodes is treated…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Kamil Walczak

Understanding electron transport processes in molecular wires connected between contacts is a central focus in the field of molecular electronics. Especially, the dephasing effect causing tunneling-to-hopping transition has great importance…

Mesoscale and Nanoscale Physics · Physics 2012-06-26 Daijiro Nozaki , Claudia Gomes da Rocha , Horacio M. Pastawski , Gianaurelio Cuniberti

The paper presents a short overview of research into properties of organic materials and structures that could be used in optoelectrical switches, i.e., switches in which changes in electrical properties are triggered by light of…

Chemical Physics · Physics 2011-12-06 Juliusz Sworakowski , Petro Lutsyk

We propose and analyze a new way of using $\pi$ stacking to design molecular junctions that either enhance or suppress a phononic heat current, but at the same time remain conductors for an electric current. Such functionality is highly…

Mesoscale and Nanoscale Physics · Physics 2015-02-10 Gediminas Kiršanskas , Qian Li , Karsten Flensberg , Gemma C. Solomon , Martin Leijnse

We present a simple model of electrical transport through a metal-molecule-metal nanojunction that includes charging effects as well as aspects of the electronic structure of the molecule. The interplay of a large charging energy and an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Matthias H. Hettler , Herbert Schoeller , Wolfgang Wenzel