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It has been suggested that hydrogen may metallise at lower pressures if it is ``precompressed''. Here we introduce a search strategy for predicting high-pressure structures and apply it to silane using first-principles electronic structure…

Materials Science · Physics 2009-11-11 Chris J. Pickard , R. J. Needs

Atomic layer deposition of ultrathin HfO2 on unmodified graphene from HfCl4 and H2O was investigated. Surface RMS roughness down to 0.5 nm was obtained for amorphous, 30 nm thick hafnia film grown at 180 degrees C. HfO2 was deposited also…

M-stars are the most common hosts of planetary systems in the Galaxy. Protoplanetary disks around M-stars thus offer a prime opportunity to study the chemistry of planet-forming environments. We present an ALMA survey of molecular line…

The possible occurrence of bound states of He-3 atoms in the vicinity of a weakly attractive substrate coated with a thin superfluid He-4film is investigated by first principle computer simulations. No evidence is seen of such bound states,…

Statistical Mechanics · Physics 2022-11-30 Massimo Boninsegni

Chemisorption of hydrogen on graphene is studied using atomistic simulations with the second generation of reactive empirical bond order Brenner inter-atomic potential. The lowest energy adsorption sites and the most important metastable…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 Abdiravuf A. Dzhurakhalov , Francois M. Peeters

The discovery of effective hydrogen storage materials is fundamental for the progress of a clean energy economy. Ammonia borane ($\mathrm{H_3BNH_3}$) has attracted great interest as a promising candidate but the reaction path that leads…

Chemical Physics · Physics 2019-01-30 Valerio Rizzi , Daniela Polino , Emilia Sicilia , Nino Russo , Michele Parrinello

The discovery of graphene and other two-dimensional (2-D) materials has stimulated a general interest in low-dimensional (low-D) materials. Whereas long time ago, Peierls and Landau's theoretical work demonstrated that any one- and…

Materials Science · Physics 2017-10-11 Jiapeng Chen , Biao Wang , Yangfan Hu

The assembly of molecules to form covalent networks can create varied lattice structures with distinct physical and chemical properties from conventional atomic lattices. Using the smallest stable [5,6]fullerene units as building blocks,…

Materials Science · Physics 2025-03-27 Jiaqi Wu , Bo Peng

Atomically thin metallenes are a new family of materials representing the ultimate limit of a thin free-electron gas for novel applications. Although metallene research has gained traction, limited attention has been paid to the properties…

Materials Science · Physics 2025-02-07 Kameyab Raza Abidi , Mohammad Bagheri , Sukhbir Singh , Pekka Koskinen

X-ray diffraction and Raman scattering measurements, and first-principles calculations are performed to search for the formation of NaCl-hydrogen compound. When NaCl and H$_{2}$ mixture is laser-heated to above 1500 K at pressures exceeding…

A promising material for hydrogen storage at room temperature-Al doped graphene was proposed theoretically by using density functional theory calculation. Hydrogen storage capacity of 5.13 wt% was predicted at T = 300 K and P = 0.1 Gpa with…

Materials Science · Physics 2009-11-13 Z. M. Ao , Q. Jiang , R. Q. Zhang , T. T. Tan , S. Li

The discovery of superconductivity at 200 K in the hydrogen sulfide system at large pressures [1] was a clear demonstration that hydrogen-rich materials can be high-temperature superconductors. The recent synthesis of LaH$_{10}$ with a…

The thermal conductivity of the methane hydrate CH4 (5.75 H2O) was measured in the interval 2-140 K using the steady-state technique. The thermal conductivity corresponding to a homogeneous substance was calculated from the measured…

Disordered Systems and Neural Networks · Physics 2009-11-10 A. I. Krivchikov , B. Ya. Gorodilov , O. A. Korolyuk , V. G. Manzhelii , H. Conrad , W. Press

A new class of materials is developed that is a liquid with both high conductivity and magnetic susceptibility for magnetohydrodynamic (MHD) applications. We develop a general method for making such suspensions and demonstrate that various…

Materials Science · Physics 2017-08-30 Florian Carle , Kunlun Bai , Joshua Casara , Kyle Vanderlick , Eric Brown

First-principles density functional calculations reveal that aluminum can form planar chains in zigzag and ladder structures. The most stable one has equilateral triangular geometry with four nearest neighbors; the other stable zigzag…

Materials Science · Physics 2009-11-07 Prasenjit Sen , S. Ciraci , A. Buldum , Inder P. Batra

Oxygen is in many ways a unique element: the only known diatomic molecular magnet and the capability of stabilization of the hitherto unexpected O8 cluster structure in its solid form at high pressure. Molecular dissociations upon…

Materials Science · Physics 2012-01-10 Li Zhu , Ziwei Wang , Yanchao Wang , Yanming Ma , Guangtian Zou , Ho-kwang Mao

Metallic hydrogen is expected to exhibit remarkable physics. Examples include high-temperature superconductivity and possible novel types of quantum fluids. These could have revolutionary practical applications. The pressures required to…

Materials Science · Physics 2017-05-16 Craig M. Tenney , Keeper L. Sharkey , Jeffrey M. McMahon

Continuous-time, random-walk Monte Carlo simulations of H2 formation on grains have been performed for surfaces that are stochastically heated by photons. We have assumed diffuse cloud conditions and used a variety of grains of varying…

Astrophysics · Physics 2009-11-11 H. M. Cuppen , O. Morata , Eric Herbst

We present a systematic study of the low-energy structures of zinc borohydride, a crystalline material proposed for the hydrogen storage purpose. In addition to the previously proposed structures, many new low-energy structures of zinc…

Materials Science · Physics 2013-03-29 Tran Doan Huan , Maximilian Amsler , Vu Ngoc Tuoc , Alexander Willand , Stefan Goedecker

The paper is dedicated to the mechanics of the methane bubbles in the gas hydrate stability zone of the basin. Transformation of deep-water methane bubbles into solid hydrate was investigated in Lake Baikal in situ. Released from the bottom…

Fluid Dynamics · Physics 2013-06-25 Alexander V. Egorov , Robert I. Nigmatulin , Aleksey N. Rozhkov