English
Related papers

Related papers: Direct Ensemble Estimation of Density Functionals

200 papers

We formulate the Kohn-Sham density functional theory (KS-DFT) as a statistical theory in which the electron density is deter-mined from an average of correlated stochastic densities in a trace formula. The key idea is that it is sufficient…

Materials Science · Physics 2015-06-15 Roi Baer , Daniel Neuhauser , Eran Rabani

How might a smooth probability distribution be estimated, with accurately quantified uncertainty, from a limited amount of sampled data? Here we describe a field-theoretic approach that addresses this problem remarkably well in one…

Data Analysis, Statistics and Probability · Physics 2018-10-24 Wei-Chia Chen , Ammar Tareen , Justin B. Kinney

Standard approaches to constructing nonparametric confidence bands for functions are frustrated by the impact of bias, which generally is not estimated consistently when using the bootstrap and conventionally smoothed function estimators.…

Statistics Theory · Mathematics 2014-01-30 Peter Hall , Joel Horowitz

We present an approach based on density-functional theory for the calculation of fundamental gaps of both finite and periodic two-dimensional (2D) electronic systems. The computational cost of our approach is comparable to that of total…

Materials Science · Physics 2021-08-11 Alberto Guandalini , Alice Ruini , Esa Räsänen , Carlo Andrea Rozzi , Stefano Pittalis

We study the problem of space and time efficient evaluation of a nonparametric estimator that approximates an unknown density. In the regime where consistent estimation is possible, we use a piecewise multivariate polynomial interpolation…

Statistics Theory · Mathematics 2020-11-11 Paxton Turner , Jingbo Liu , Philippe Rigollet

This papers presents a generalization of the Weitzman overlapping coefficient, originally defined for two probability density functions, to a setting involving k independent distributions, denoted by Delta. To estimate this generalized…

Methodology · Statistics 2026-03-24 Omar Eidous , Noura Almasri

We suggest to include the density of electron charge explicitly in the electron potential of density functional theory, rather than implicitly via exchange-correlation functionals. The advantages of the approach are conceptual and…

Materials Science · Physics 2007-05-23 Werner A. Hofer , Krisztian Palotas

The concept of biased data is well known and its practical applications range from social sciences and biology to economics and quality control. These observations arise when a sampling procedure chooses an observation with probability that…

Statistics Theory · Mathematics 2007-06-13 Sam Efromovich

Entropy-type integral functionals of densities are widely used in mathematical statistics, information theory, and computer science. Examples include measures of closeness between distributions (e.g., density power divergence) and…

Statistics Theory · Mathematics 2013-03-08 David Källberg , Oleg Seleznjev

Nonparametric learning is a fundamental concept in machine learning that aims to capture complex patterns and relationships in data without making strong assumptions about the underlying data distribution. Owing to simplicity and…

Machine Learning · Computer Science 2024-02-06 Amartya Banerjee , Christopher J. Hazard , Jacob Beel , Cade Mack , Jack Xia , Michael Resnick , Will Goddin

The use of principal component methods to analyze functional data is appropriate in a wide range of different settings. In studies of ``functional data analysis,'' it has often been assumed that a sample of random functions is observed…

Statistics Theory · Mathematics 2016-08-16 Peter Hall , Hans-Georg Müller , Jane-Ling Wang

Various studies have confirmed the possibility of identifying the location of a set of small inhomogeneities via a direct sampling method; however, when their permeability differs from that of the background, their location cannot be…

Numerical Analysis · Mathematics 2018-01-09 Won-Kwang Park

We propose a novel method for density estimation that leverages an estimated score function to debias kernel density estimation (SD-KDE). In our approach, each data point is adjusted by taking a single step along the score function with a…

Machine Learning · Computer Science 2025-06-24 Elliot L. Epstein , Rajat Dwaraknath , Thanawat Sornwanee , John Winnicki , Jerry Weihong Liu

Parameter estimation is one of the most important tasks in statistics, and is key to helping people understand the distribution behind a sample of observations. Traditionally parameter estimation is done either by closed-form solutions…

Machine Learning · Computer Science 2024-03-04 Xiaoxin Yin , David S. Yin

Dyadic data is often encountered when quantities of interest are associated with the edges of a network. As such it plays an important role in statistics, econometrics and many other data science disciplines. We consider the problem of…

Statistics Theory · Mathematics 2023-10-17 Matias D. Cattaneo , Yingjie Feng , William G. Underwood

Functional Data Analysis represents a field of growing interest in statistics. Despite several studies have been proposed leading to fundamental results, the problem of obtaining valid and efficient prediction sets has not been thoroughly…

Methodology · Statistics 2021-04-13 Jacopo Diquigiovanni , Matteo Fontana , Simone Vantini

Two-sample feature selection is the problem of finding features that describe a difference between two probability distributions, which is a ubiquitous problem in both scientific and engineering studies. However, existing methods have…

Kinetic energy functionals of the electronic density are used to model large systems in the context of density functional theory, without the need to obtain electronic wavefunctions. We discuss the problems associated with the application…

Condensed Matter · Physics 2009-11-07 Nicholas Choly , Efthimios Kaxiras

arXiv:2206.10812v1 [stat.ME] proposes a useful algorithm, named generalized Diversity Subsampling (g-DS) algorithm, to select a subsample following some target probability distribution from a finite data set and demonstrates its…

Methodology · Statistics 2023-09-06 Boyang Shang

We consider nonparametric estimation of $L_2$, Renyi-$\alpha$ and Tsallis-$\alpha$ divergences between continuous distributions. Our approach is to construct estimators for particular integral functionals of two densities and translate them…

Machine Learning · Statistics 2014-05-13 Akshay Krishnamurthy , Kirthevasan Kandasamy , Barnabas Poczos , Larry Wasserman