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We construct correlation-consistent effective core potentials (ccECPs) for a selected set of heavy atoms and f-elements that are of significant current interest in materials and chemical applications, including Y, Zr, Nb, Rh, Ta, Re, Pt,…

The effect of the electron-electron cusp on the convergence of configuration interaction (CI) wave functions is examined. By analogy with the pseudopotential approach for electron-ion interactions, an effective electron-electron interaction…

Strongly Correlated Electrons · Physics 2009-11-07 David Prendergast , M. Nolan , Claudia Filippi , Stephen Fahy , J. C. Greer

We report Hartree-Fock (HF) based pseudopotentials suitable for plane-wave calculations. Unlike typical effective core potentials, the present pseudopotentials are finite at the origin and exhibit rapid convergence in a plane-wave basis;…

Materials Science · Physics 2008-02-28 W. A. Al-Saidi , E. J. Walter , A. M. Rappe

The consistency between the exchange-correlation functional used in pseudopotential construction and in the actual density functional theory calculation is essential for the accurate prediction of fundamental properties of materials.…

Chemical Physics · Physics 2018-02-21 Jing Yang , Liang Z. Tan , Andrew M. Rappe

The pseudogap stands out in the phase diagram of the cuprate high-temperature superconductors because its origin and relationship to superconductivity remain elusive. The origin of the pseudogap has been debated, with competing hypotheses…

We outline a partial-fractions decomposition method for determining the one-particle spectral function and single-particle density of states of a correlated electronic system on a finite lattice in the non self-consistent T-matrix…

Strongly Correlated Electrons · Physics 2009-11-10 R. J. Gooding , F. Marsiglio , S. Verga , K. S. D. Beach

Nowadays pseudopotential density-functional theory calculations constitute the standard approach to tackle solid-state electronic problems. These rely on distributed pseudopotential tables that were built from all-electron atomic…

Computational Physics · Physics 2020-03-24 Pedro Borlido , Jan Doumont , Fabien Tran , Miguel Marques , Silvana Botti

The transcorrelated (TC) method performs a similarity transformation on the electronic Schr\"odinger equation via Jastrow factorization of the wave function. This has demonstrated significant advancements in computational electronic…

Correlated electron systems may give rise to multiple effective interactions whose combined impact on quasiparticle properties can be difficult to disentangle. We introduce an unambiguous decomposition of the electronic self-energy which…

Strongly Correlated Electrons · Physics 2025-07-11 Yang Yu , Sergei Iskakov , Emanuel Gull , Karsten Held , Friedrich Krien

Electron interactions are pivotal for defining the electronic structure of quantum materials. In particular, the strong electron Coulomb repulsion is considered the keystone for describing the emergence of exotic and/or ordered phases of…

We construct a new modification of correlation consistent effective potentials (ccECPs) for late $3d$ elements Cr-Zn with Ne-core that are adapted for efficiency and low energy cut-offs in plane wave calculations. The decrease in accuracy…

Materials Science · Physics 2022-11-23 Benjamin Kincaid , Guangming Wang , Haihan Zhou , Lubos Mitas

We introduce new correlation consistent effective core potentials (ccECPs) for the elements I, Te, Bi, Ag, Au, Pd, Ir, Mo, and W with $4d$, $5d$, $6s$ and $6p$ valence spaces. These ccECPs are given as a sum of spin-orbit averaged…

We present a general numerical approach to construct local Kohn-Sham potentials from orbital-dependent functionals within the all-electron full-potential linearized augmented-plane-wave (FLAPW) method, in which core and valence electrons…

Materials Science · Physics 2011-07-06 Markus Betzinger , Christoph Friedrich , Stefan Blügel , Andreas Görling

The package fhi98PP allows one to generate norm-conserving pseudopotentials adapted to density-functional theory total-energy calculations for a multitude of elements throughout the periodic table, including first-row and transition metal…

Materials Science · Physics 2009-10-31 Martin Fuchs , Matthias Scheffler

Pseudopotential theory has greatly driven first-principles calculations in materials, replacing the explicit treatment of the chemically inert core electrons with an effective potential acting only on the valence states. This is inherently…

Materials Science · Physics 2026-05-07 Matteo Quinzi , Tommaso Chiarotti , Nicola Marzari

The electronic correlations in oxide HTSC in the normal state are analyzed by the generalized Hartree-Fock theory of Nambu and Gorkov. It yields two kinds of pseudogaps, the small pseudogap (SPG) and the large pseudogap (LPG). The first is…

Superconductivity · Physics 2020-01-08 Moshe Dayan

We introduce a finite-range pseudopotential built as an expansion in derivatives up to next-to-next-to-next-to-leading order (N$^3$LO) and we calculate the corresponding nonlocal energy density functional (EDF). The coupling constants of…

Nuclear Theory · Physics 2015-06-18 F. Raimondi , K. Bennaceur , J. Dobaczewski

Valence energies for crystalline C, Si, Ge, and Sn with diamond structure have been determined using an ab-initio approach based on information from cluster calculations. Correlation contributions, in particular, have been evaluated in the…

Condensed Matter · Physics 2016-08-31 Beate Paulus , Peter Fulde , Hermann Stoll

Information on the nature of the dominant inelastic processes operative in correlated metallic systems can be obtained from an analysis of their AC optical response. An electron-boson spectral density can usefully be extracted. This density…

Superconductivity · Physics 2015-06-17 Jungseek Hwang , J. P. Carbotte

We demonstrate how to identify which physical processes dominate the low-energy spectral functions of correlated electron systems. We obtain an unambiguous classification through an analysis of the equation of motion for the electron…

Strongly Correlated Electrons · Physics 2015-06-17 O. Gunnarsson , T. Schäfer , J. P. F. LeBlanc , E. Gull , J. Merino , G. Sangiovanni , G. Rohringer , A. Toschi