Related papers: Activating spin-forbidden transitions in molecules…
We demonstrate to image asymmetric molecular orbitals via high-order harmonic generation in a one-color inhomogeneous field. Due to the broken inversion symmetry of the inhomogeneous field in space, the returning electrons with energy in a…
We show how additional constraints, restricting the spectrum of the optimized pulse or confining the system dynamics, can be used to steer optimization in quantum control towards distinct solutions. Our examples are multi-photon excitation…
We report on the local control of the transition frequency of a spin-$1/2$ encoded in two Rydberg levels of an individual atom by applying a state-selective light shift using an addressing beam. With this tool, we first study the spectrum…
Control of intramolecular spin alignment is studied theoretically in a model of polyene-based molecular magnets in which delocalized $\pi$ electrons are coupled with localized radical spins. In a previous paper [Phys. Rev. Lett. 90 (2003)…
The ability to control and understand the phase transitions of individual nanoscale building blocks is key to advancing the next generation of low-power reconfigurable nanophotonic devices. To address this critical challenge, molecular…
A strong, far-detuned laser can shift the energy levels of an optically active quantum system via the AC Stark effect. We demonstrate that the polarization of the laser results in a spin-selective modification to the energy structure of a…
This is a direct computation of the spectral representation of homogeneous spin-weighted spherical random fields with arbitrary integer spin. It generalises known results from Cosmology for the spin-2 Cosmic Microwave Background…
It has been shown elsewhere that two spatially separated atoms can jointly absorb one photon, whose frequency is equal to the sum of the transition frequencies of the two atoms. We describe this process in the presence of an ensemble of…
The strong-field control of plasmonic nanosystems opens up new perspectives for nonlinear plasmonic spectroscopy and petahertz electronics. Questions, however, remain regarding the nature of nonlinear light-matter interactions at…
We observe mixing between two-electron singlet and triplet states in a double quantum dot, caused by interactions with nuclear spins in the host semiconductor. This mixing is suppressed by applying a small magnetic field, or by increasing…
We describe a new approach to precision NMR with hyperpolarized gases designed to mitigate NMR frequency shifts due to the alkali spin exchange field. The electronic spin polarization of optically pumped alkali atoms is square-wave…
The manipulation of quantum many-body systems is a frontier challenge in quantum science. Entangled quantum states that are symmetric to permutation between qubits are of growing interest. Yet, the creation and control of symmetric states…
Sharp metal corners and tips support plasmons localized on the scale of the curvature radius -- superlocalized plasmons. We analyze plasmonic properties of nanoparticles with small and sharp corner- and tip-shaped surface perturbations in…
We employ a method involving coherent periodic modulation of Raman laser intensity to induce resonance transitions between energy levels of a spin-orbit coupled atom in a symmetric double-well trap. By integrating photon-assisted tunneling…
We suggest and experimentally realize a spectral photonic lattice - a signal can hop between discrete frequency channels, driven by nonlinear interaction with stronger pump lasers. By controlling the complex envelope and frequency…
Controlling structural transitions between molecular configurations is crucial for advancing functional molecular electronics. While reversible switching of bistable two-state molecules has been achieved, creating molecular systems that can…
We consider deflection of rotating symmetric molecules by inhomogeneous optical and static electric fields, compare results with the case of linear molecules, and find new singularities in the distribution of the scattering angle.…
Preserving quantum coherence with the increase of a system's size and complexity is a major challenge. Molecules, with their diverse sizes and complexities and many degrees of freedom, are an excellent platform for studying the transition…
The quantum mechanical screening of a spin via conduction electrons depends sensitively on the environment seen by the magnetic impurity. A high degree of responsiveness can be obtained with metal complexes, as the embedding of a metal ion…
Topological transitions are fundamental phenomena in electronics, photonics, and quantum technologies. However, the scalability and tunability of Topological transitions in these systems have still been constrained by their material…