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We analyze how functionality could be obtained within single-molecule devices by using a combination of non-equilibrium Green's functions and ab-initio calculations to study the inelastic transport properties of single-molecule junctions.…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 L. K. Dash , H. Ness , M. J. Verstraete , R. W. Godby

We present implementation of second- and third-order algebraic diagrammatic construction theory for efficient and accurate computations of molecular electron affinities (EA), ionization potentials (IP), and densities of states…

Chemical Physics · Physics 2020-07-28 Samragni Banerjee , Alexander Yu. Sokolov

The accuracy of probability distributions inferred using machine-learning algorithms heavily depends on data availability and quality. In practical applications it is therefore fundamental to investigate the robustness of a statistical…

Machine Learning · Statistics 2018-10-01 Christiane Goergen , Manuele Leonelli

We study a graph partitioning problem motivated by the simulation of the physical movement of multi-body systems on an atomistic level, where the forces are calculated from a quantum mechanical description of the electrons. Several advanced…

Vibrationally inelastic electron transport through a molecular bridge that is connected to two leads is investigated. The study is based on a generic model of vibrational excitation in resonant transmission of electrons through a molecular…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Martin Cizek , Michael Thoss , Wolfgang Domcke

The prediction of physicochemical properties from molecular structures is a crucial task for artificial intelligence aided molecular design. A growing number of Graph Neural Networks (GNNs) have been proposed to address this challenge.…

Machine Learning · Computer Science 2020-11-17 Shuo Zhang , Yang Liu , Lei Xie

We describe an ab initio method for calculating the electronic structure, electronic transport, and forces acting on the atoms, for atomic scale systems connected to semi-infinite electrodes and with an applied voltage bias. Our method is…

Materials Science · Physics 2009-11-07 Mads Brandbyge , Jose-Luis Mozos , Pablo Ordejon , Jeremy Taylor , Kurt Stokbro

Inelastic effects in electron transport through nano-sized devices are addressed with a method based on nonequilibrium Green's functions (NEGF) and perturbation theory to infinite order in the electron-vibration coupling. We discuss the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thomas Frederiksen , Mads Brandbyge , Nicolas Lorente , Antti-Pekka Jauho

The Green function method developed in Ref.[S. B. Chernyshuk and B. I. Lev, Phys. Rev. E \textbf{81}, 041707 (2010)] is used to describe elastic interactions between axially symmetric colloidal particles in the nematic cell in the presence…

Soft Condensed Matter · Physics 2015-05-30 S. B. Chernyshuk , O. M. Tovkach , B. I. Lev

Using the tight-binding model with long-range Coulomb interactions between electrons, we study some of the electronic properties of graphene. The Coulomb interactions are treated with the renormalized-ring-diagram approximation. By…

Strongly Correlated Electrons · Physics 2011-11-09 Xin-Zhong Yan , C. S. Ting

Modeling nanoscale devices quantum mechanically is a computationally challenging problem where new methods to solve the underlying equations are in a dire need. In this paper, we present an approach to calculate the charge density in…

Numerical Analysis · Mathematics 2013-05-07 U. Hetmaniuk , Y. Zhao , M. P. Anantram

In this paper, we present the extended dissipaton theory, including the dissipaton-equation-of-motion formalism and the equivalent dissipaton-embedded quantum master equation. These are exact, non-Markovian, and non-perturbative theories,…

Mesoscale and Nanoscale Physics · Physics 2025-04-08 Yu Su , Yao Wang , Zi-Fan Zhu , Yuan Kong , Rui-Xue Xu , Xiao Zheng , YiJing Yan

We study wave function structure for quantum graphs in the chaotic and disordered regime, using measures such as the wave function intensity distribution and the inverse participation ratio. The result is much less ergodicity than expected…

Chaotic Dynamics · Physics 2009-08-14 L. Kaplan

We present a novel hybrid quantum/classical (QM/MM) approach to the calculation of charged excitations in molecular solids based on the many-body Green's function $GW$ formalism. Molecules described at the $GW$ level are embedded into the…

Chemical Physics · Physics 2018-02-14 Jing Li , Gabriele D'Avino , Ivan Duchemin , David Beljonne , Xavier Blase

Graph neural networks (GNNs) demonstrate great performance in compound property and activity prediction due to their capability to efficiently learn complex molecular graph structures. However, two main limitations persist including…

Biomolecules · Quantitative Biology 2023-10-10 Apakorn Kengkanna , Masahito Ohue

For D-dimensional weakly interacting topological insulators in certain symmetry classes, the topological invariant can be calculated from a D- or (D+1)-dimensional integration over a certain curvature function that is expressed in terms of…

Strongly Correlated Electrons · Physics 2018-03-15 Wei Chen

Designing molecules with specific properties is a long-lasting research problem and is central to advancing crucial domains such as drug discovery and material science. Recent advances in deep graph generative models treat molecule design…

Machine Learning · Computer Science 2022-03-02 Yuanqi Du , Xiaojie Guo , Amarda Shehu , Liang Zhao

Using a path integral approach and bosonization, we calculate the low energy asymptotics of the one particle Green's function for a ``magnetically incoherent'' one dimensional strongly interacting electron gas at temperatures much greater…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Gregory A. Fiete , Leon Balents

We present a computationally efficient method to incorporate density-functional theory into the calculation of reflectivity in low-energy electron microscopy. The reflectivity is determined by matching plane waves representing the electron…

Materials Science · Physics 2013-11-13 John F. McClain , Jiebing Sun , Karsten Pohl , Jian-Ming Tang

In this paper we discuss the question of how to decide when a general chemical reaction system is incapable of admitting multiple equilibria, regardless of parameter values such as reaction rate constants, and regardless of the type of…

Dynamical Systems · Mathematics 2009-07-17 Murad Banaji , Gheorghe Craciun