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Classical nucleation theory offers a good framework for understanding the common features of new phase formation processes in metastable homogeneous media at rest. However, nucleation processes in liquids are ubiquitously affected by…

Soft Condensed Matter · Physics 2016-04-18 F. Mura , A. Zaccone

We develop a unified kinetic theory for ordered fluids, which systematically extends the phase space with the appropriate generalized angular momenta. Our theory yields a uniquely determined mesoscopic model for any continuum with…

Mathematical Physics · Physics 2026-04-02 José A. Carrillo , Patrick E. Farrell , Andrea Medaglia , Umberto Zerbinati

Fluid phase equilibria involving nano-dispersed phases, where at least one of the coexisting phases is confined to a small volume, are investigated by molecular dynamics simulation. Complementing previous studies on nanoscopic droplets,…

Mesoscale and Nanoscale Physics · Physics 2013-07-23 Martin Horsch , Hans Hasse

In this paper, we present a general numerical platform for designing accurate, efficient, and stable numerical algorithms for incompressible hydrodynamic models that obeys the thermodynamical laws. The obtained numerical schemes are…

Numerical Analysis · Mathematics 2021-03-04 Jia Zhao

The kinetic theory for a fluid of hard spheres which undergo endothermic and/or exothermic reactions with mass transfer is developed. The exact balance equations for concentration, density, velocity and temperature are derived. The Enskog…

Statistical Mechanics · Physics 2007-05-23 James F. Lutsko

A collisional model of a confined quasi-two-dimensional granular mixture is considered to analyze homogeneous steady states. The model includes an effective mechanism to transfer the kinetic energy injected by vibration in the vertical…

Statistical Mechanics · Physics 2020-12-30 Ricardo Brito , Rodrigo Soto , Vicente Garzó

Molecular dynamics simulation has been used to model pattern formation in three-dimensional Rayleigh--Benard convection at the discrete-particle level. Two examples are considered, one in which an almost perfect array of hexagonally-shaped…

Other Condensed Matter · Physics 2009-11-11 D. C. Rapaport

By using the Onsager principle as an approximation tool, we give a novel derivation for the moving finite element method for gradient flow equations. We show that the discretized problem has the same energy dissipation structure as the…

Numerical Analysis · Mathematics 2020-09-04 Xianmin Xu

This work reconsiders the Becker-Doering model for nucleation under isothermal conditions in the presence of phase transitions. Based on thermodynamic principles a modified model is derived where the condensation and evaporation rates may…

Mathematical Physics · Physics 2019-05-01 Thomas Blesgen , Ada Amendola , Fernando Fraternali

The paper studies a higher-order diffusion model of Maxwell-Stefan kind. The model is based upon higher-order moment equations of kinetic theory of mixtures, which include viscous dissipation in the model. Governing equations are analyzed…

Analysis of PDEs · Mathematics 2023-05-16 Bérénice Grec , Srboljub Simic

Liquid crystals with molecules constrained to the tangent bundle of a curved surface show interesting phenomena resulting from the tight coupling of the elastic and bulk free energies of the liquid crystal with geometric properties of the…

Soft Condensed Matter · Physics 2021-03-17 Ingo Nitschke , Sebastian Reuther , Axel Voigt

Granular gaseous mixtures under rapid flow conditions are usually modeled by a multicomponent system of smooth inelastic hard spheres with constant coefficients of normal restitution. In the low density regime an adequate framework is…

Statistical Mechanics · Physics 2009-11-13 Francisco Vega Reyes , Vicente Garzo , Andres Santos

We derive thermodynamically consistent models of reaction-diffusion equations coupled to a heat equation. While the total energy is conserved, the total entropy serves as a driving functional such that the full coupled system is a gradient…

Analysis of PDEs · Mathematics 2018-10-16 Jan Haskovec , Sabine Hittmeir , Peter Markowich , Alexander Mielke

In this work we investigate the dynamical properties of a mixture of mutually interacting spherical molecules of different masses and sizes. From an analysis of the microscopic laws governing the motion of the molecules we derive a set of…

Soft Condensed Matter · Physics 2011-02-15 Umberto Marini Bettolo Marconi

We present a new hydrodynamic model for incompressible binary fluids that is thermodynamically consistent and non-isothermal. This model follows the generalized Onsager principle and Boussinesq approximation and preserves the volume of each…

Fluid Dynamics · Physics 2023-08-14 Shouwen Sun , Liangliang Lei , Qi Wang

This chapter is about the modeling of nematic liquid crystals (LCs) and their numerical simulation. We begin with an overview of the basic physics of LCs and discuss some of their many applications. Next, we delve into the modeling…

Numerical Analysis · Mathematics 2020-01-13 Juan Pablo Borthagaray , Shawn W. Walker

We carry out Monte Carlo simulations to investigate the effect of molecular shape on liquid-crystal order. In our approach, each model mesogen consists of several soft spheres bonded rigidly together. The arrangement of the spheres may be…

Soft Condensed Matter · Physics 2009-11-07 J. Xu , R. L. B. Selinger , J. V. Selinger , R. Shashidhar

Motivated by the reported peculiar dynamics of a red blood cell in shear flow, we develop an analytical theory for the motion of a nearly--spherical fluid particle enclosed by a visco--elastic incompressible interface in linear flows. The…

Fluid Dynamics · Physics 2010-07-06 Petia M. Vlahovska , Yuan-nan Young , Gerrit Danker , Chaouqi Misbah

A thermodynamically consistent particle-based model for fluid dynamics with continuous velocities and a non-ideal equation of state is presented. Excluded volume interactions are modeled by means of biased stochastic multiparticle…

Soft Condensed Matter · Physics 2009-11-11 Thomas Ihle , Erkan Tuzel , Daniel M. Kroll

Motivated by problems arising in tear film dynamics, we present a model for the extensional flow of thin sheets of nematic liquid crystal. The rod-like molecules of these substances impart an elastic contribution to its response. We rescale…

Fluid Dynamics · Physics 2023-06-28 M. J. Taranchuk , L. J. Cummings , T. A. Driscoll , R. J. Braun