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Strongly-correlated transition-metal oxides are widely known for their various exotic phenomena. This is exemplified by rare-earth nickelates such as LaNiO$_{3}$, which possess intimate interconnections between their electronic, spin, and…

While most of the rare-earth nickelates exhibit a temperature-driven sharp metal-insulator transition, LaNiO$_3$ is the only exception remaining metallic down to low temperatures. Using local density approximation as an input to dynamical…

Strongly Correlated Electrons · Physics 2014-03-04 Debolina Misra

The observation of superconductivity in infinite layer nickelate (Nd,Sr)NiO$_{2}$ thin films has led to rapid theoretical and experimental investigations of these copper-oxide-analogue systems [1-15]. Superconductivity has also been found…

We report the first single crystal growth of the correlated metal LaNiO3 using a high-pressure optical-image floating zone furnace. The crystals were studied using single crystal/powder x-ray diffraction, resistivity, specific heat, and…

Materials Science · Physics 2017-10-17 Junjie Zhang , Hong Zheng , Yang Ren , J. F. Mitchell

Nickelates are a rich class of materials, ranging from insulating magnets to superconductors. But for stoichiometric materials, insulating behavior is the norm, as for most late transition metal oxides. Notable exceptions are the 3D…

Amongst the rare-earth perovskite nickelates, LaNiO$_3$ (LNO) is an exception. While the former have insulating and antiferromagnetic ground states, LNO remains metallic and non-magnetic down to the lowest temperatures. It is believed that…

The rare earth nickelates RNiO3 are metallic at high temperatures and insulating and magnetically ordered at low temperatures. The low temperature phase has been predicted to be type II multiferroic, i.e. ferroelectric and magnetic order…

Strongly Correlated Electrons · Physics 2021-07-05 I. Ardizzone , J. Teyssier , I. Crassee , A. B. Kuzmenko , D. G. Mazzone , D. J. Gawryluk , M. Medarde , D. van der Marel

Nickelates have attracted enormous attention since the discovery of high-temperature superconductivity in La3Ni2O7 under high pressure. However, whether superconducting nickelate single crystals can be prepared at ambient pressure remains…

Superconductivity · Physics 2025-08-26 Feiyu Li , Yinqiao Hao , Ning Guo , Jian Zhang , Qiang Zheng , Guangtao Liu , Junjie Zhang

The prediction of high $T_c$ superconductivity in layers of LaNiO$_3$ through orbital engineering has led to extensive research efforts over the last fifteen years. During this period, a plethora of thin films and heterostructures based…

Strongly Correlated Electrons · Physics 2022-05-10 J. Chakhalian , S. Middey

Rare-earth nickelates RNiO3 (R=rare-earth element) exhibit three kinds of phase transitions with decreasing temperature: a structural transition from a pseudo-cubic to a monoclinic phase, a metal- insulator transition (MIT), and a magnetic…

Rare-earth nickelates form an intriguing series of correlated perovskite oxides. Apart from LaNiO3, they exhibit on cooling a sharp metal-insulator electronic phase transition, a concurrent structural phase transition and a magnetic phase…

Materials Science · Physics 2018-02-07 Alain Mercy , Jordan Bieder , Jorge Iniguez , Philippe Ghosez

Although rare earth nickelates (ReNiO3) exhibit abundant electronic phases and widely adjustable metal to insulator electronic transition properties, their practical electronic applications are largely impeded by their intrinsic meta…

Materials Science · Physics 2021-11-29 Fengbo Yan , Zhishan Mi , Jinhao Chen , Haiyang Hu , Lei Gao , Jiaou Wang , Nuofu Chen , Yong Jiang , Lijie Qiao , Jikun Chen

The perovksite rare-earth nickelates, RNiO$_3$ (R=La ... Lu), are a class of materials displaying a rich phase-diagram of metallic and insulating phases associated with charge and magnetic order. Being in the charge transfer regime,…

Strongly Correlated Electrons · Physics 2015-04-14 John W. Freeland , Michel van Veenendaal , Jak Chakhalian

Long viewed as passive elements, antiferromagnetic materials have emerged as promising candidates for spintronic devices due to their insensitivity to external fields and potential for high-speed switching. Recent work exploiting spin and…

The recent observation of unconventional superconductivity in thin films of LaNiO2 (critical temperature, Tc~10 K) and in bulk single crystals of La3Ni2O7 (327) under pressure (Tc~80 K), has brought to light a long sought-after class of…

Superconductivity · Physics 2024-03-18 S. Rathnayaka , S. Yano , K. Kawashima , J. Akimitsu , C. M. Brown , J. Neuefeind , D. Louca

We report on tunneling measurements that reveal for the first time the evolution of the quasi-particle state density across the bandwidth controlled Mott metal to insulator transition in the rare earth perovskite nickelates. In this, a…

The electronic properties of transition-metal oxides with highly correlated electrons are of central importance in modern condensed matter physics and chemistry, both for their fundamental scientific interest, and for their potential for…

Although discovery in hydrogen induced electronic transition within perovskite family of rare-earth nickelate (ReNiO3) opens up a new paradigm in exploring both the new materials functionality and device applications, the existing research…

Materials Science · Physics 2022-03-14 Yi Bian , Haiyan Li , Fengbo Yan , Haifan Li , Jiaou Wang , Hao Zhang , Yong Jiang , Nuofu Chen , Jikun Chen

Three low-valence layered nickelates with general formula La$_3$Ni$_2$O$_{7-\delta}$ ($\delta$=0.0, 0.5, 1) are studied by ab initio techniques. Both the insulating and metallic limits are analyzed, together with the compound at the Mott…

Strongly Correlated Electrons · Physics 2012-06-29 Victor Pardo , Warren E. Pickett

We interpret via advanced ab initio calculations the multiple phase transitions observed recently in ultra-thin LaNiO$_{3}$/LaAlO$_{3}$ superlattices. The ground state is insulating, charge-ordered, and antiferromagnetic due to concurrent…

Materials Science · Physics 2012-11-22 Danilo Puggioni , Alessio Filippetti , Vincenzo Fiorentini
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