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In this work, we calculate the electron and the current density distributions both at the edges and the bulk of a two dimensional electron system, focusing on ideal and non-ideal contacts. A three dimensional Poisson equation is solved…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 D. Eksi , O. Kilicoglu , O. Goektas , A. Siddiki

The problem of the one dimensional electro-diffusion of ions in a strong binary electrolyte is considered. In such a system the solute dissociates completely into two species of ions with unlike charges. The mathematical description…

Chemical Physics · Physics 2012-03-28 Sandip Ghosal , Zhen Chen

This is an early but comprehensive review of the PNP Poisson Nernst Planck theory of ion channels. Extensive reference is made to the earlier literature. The starting place for this theory of open channels is a theory of electrodiffusion…

Biomolecules · Quantitative Biology 2010-09-16 Bob Eisenberg

For the structure of the thin electrical double layer~(EDL) and the property related to the EDL capacitance, we analyze boundary layer solutions (corresponding to the electrostatic potential) of a non-local elliptic equation which is a…

Analysis of PDEs · Mathematics 2018-07-31 Chiun-Chang Lee

We consider the Nernst-Planck equations describing the nonlinear time evolution of multiple ionic concentrations in a two-dimensional incompressible fluid. The velocity of the fluid evolves according to either the Euler or Darcy's…

Analysis of PDEs · Mathematics 2022-11-16 Elie Abdo , Fizay-Noah Lee , Weinan Wang

Cells and cellular organelles are encapsulated by nanometrically thin membranes whose main component is a lipid bilayer. In the presence of electric fields, the ion-impermeable lipid bilayer acts as a capacitor and supports a potential…

Soft Condensed Matter · Physics 2025-02-18 Shuozhen Zhao , Bhavya Balu , Zongxin Yu , Michael J. Miksis , Petia M. Vlahovska

Periodic configurations of electrodes, in particular of microelectrodes, have been of interest since the advent of microfabrication. In this report, theory which is common to any periodic cell (or any cell that can be extended periodically)…

Chemical Physics · Physics 2018-02-13 Cristian F. Guajardo Yévenes , Werasak Surareungchai

We propose a modified Poisson-Nernst-Planck (PNP) model to investigate charge transport in electrolytes of inhomogeneous dielectric environment. The model includes the ionic polarization due to the dielectric inhomogeneity and the ion-ion…

Computational Physics · Physics 2015-06-19 Zhenli Xu , Manman Ma , Pei Liu

The electrostatic contribution to spontaneous membrane curvature is calculated within Poisson-Boltzmann theory under a variety of assumptions and emphasizing parameters in the physiological range. Asymmetric surface charges, either fixed…

Condensed Matter · Physics 2009-10-28 Tom Chou , Marko V. Jaric' , Eric D. Siggia

Voltage distribution in sub-cellular micro-domains such as neuronal synapses, small protrusions or dendritic spines regulates the opening and closing of ionic channels, energy production and thus cellular homeostasis and excitability. Yet…

Subcellular Processes · Quantitative Biology 2024-07-23 Frédéric Paquin-Lefebvre , David Holcman

The Poisson-Nernst-Planck (PNP) equations are fundamental for modeling ion transport in electrochemical systems, capturing the intricate interplay of concentration gradients, electric fields, and ion fluxes essential for applications such…

Chemical Physics · Physics 2025-01-13 Yitao He , Dan Zhao

Effective Poisson-Nernst-Planck (PNP) equations are derived for macroscopic ion transport in charged porous media under periodic fluid flow by an asymptotic multi-scale expansion with drift. The microscopic setting is a two-component…

Mathematical Physics · Physics 2014-07-16 Markus Schmuck , Martin Z. Bazant

A system modeling the electrophoretic motion of a charged rigid macromolecule immersed in a incompressible ionized fluid is considered. The ionic concentration is governing by the Nernst-Planck equation coupled with the Poisson equation for…

Analysis of PDEs · Mathematics 2014-02-20 Luciano Bedin , Mark Thompson

The ion distribution of electrolytes near interfaces with dielectric contrast has important consequences for electrochemical processes and many other applications. To date, most studies of such systems have focused on geometrically simple…

Soft Condensed Matter · Physics 2018-11-14 Huanxin Wu , Honghao Li , Francisco J. Solis , Monica Olvera de la Cruz , Erik Luijten

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

A transient Poisson-Nernst-Planck system with steric effects is analyzed in a bounded domain with no-flux boundary conditions for the ion concentrations and mixed Dirichlet-Neumann boundary conditions for the electric potential. The steric…

Analysis of PDEs · Mathematics 2024-11-27 Peter Hirvonen , Ansgar Jüngel

Electrical double layer (EDL) is formed when an electrode is in contact with an electrolyte solution, and is widely used in biophysics, electrochemistry, polymer solution and energy storage. Poisson-Boltzmann (PB) coupled equations provides…

Mesoscale and Nanoscale Physics · Physics 2022-03-02 Cherq Chua , Chun Yun Kee , L. K. Ang , Yee Sin Ang

We theoretically study electrostatic properties of electric double layer using a generalized Poisson-Boltzmann approach taking into account the orientational ordering of water dipoles and the excluded volume effect of water molecules as…

Soft Condensed Matter · Physics 2022-02-14 Jun-Sik Sin , Song-Jin Im , Kwang-Il Kim

The linear Boltzmann equation for elastic and/or inelastic scattering is applied to derive the distribution function of a spatially homogeneous system of charged particles spreading in a host medium of two-level atoms and subjected to…

Statistical Mechanics · Physics 2009-11-13 A. Rossani , A. M. Scarfone

The short diffusion lengths in insertion battery nanoparticles render the capacitive behavior of bounded diffusion, which is rarely observable with conventional larger particles, now accessible to impedance measurements. Coupled with…

Chemical Physics · Physics 2012-05-31 J. Song , M. Z. Bazant