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Pressure provides a powerful parameter to control the protein conformation state, which at sufficiently high values can lead to unfolding. Here, we investigate the effects of increasing pressure up to $0.4$ GPa on hydrated lysozyme…

Glasses acquire their solid-like properties by cooling from the supercooled liquid via a continuous transition known as the glass transition. Recent research on soft glasses indicates that besides temperature, another route to liquify…

Soft Condensed Matter · Physics 2015-07-17 D. V. Denisov , M. T. Dang , B. Struth , A. Zaccone , G. H. Wegdam , P. Schall

Thanks to the remarkable developments of ultrafast science, one of today's challenges is to modify material state by controlling with a light pulse the coherent motions that connect two different phases. Here we show how strain waves,…

Photoexcited GeTe undergoes a non-thermal phase transition from a rhombohedral to a rocksalt crystalline phase. The microscopic mechanism and the nature of the transition are unclear. By using constrained density functional perturbation…

Materials Science · Physics 2024-05-01 Matteo Furci , Giovanni Marini , Matteo Calandra

We demonstrate that application of an increasing shear field on a glass leads to an intriguing dynamic first order transition in analogy to equilibrium transitions. By following the particle dynamics as a function of the driving field in a…

Soft Condensed Matter · Physics 2015-06-18 V. Chikkadi , D. M. Miedema , B. Nienhuis , P. Schall

We study the effect of applied strain as a physical control parameter for the phase transitions of Ca(Fe1-xCox)2As2 using resistivity, magnetization, x-ray diffraction and 57Fe M\"ossbauer spectroscopy. Biaxial strain, namely compression of…

Synchrotron x-ray diffraction experiments were performed on BaFe$_2$As$_2$ and Sr(Fe$_{1-x}$Co$_{x}$)$_2$As$_2$ single crystals as a function of temperature and applied magnetic field along the tetragonal $[1 \bar{1} 0]$ direction,…

Superconductivity · Physics 2018-07-02 U. F. Kaneko , C. B. R. Jesus , M. E. Saleta , P. G. Pagliuso , R. R. Urbano , E. Granado

We unveil the diamondization mechanism of few-layer graphene compressed in the presence of water, providing robust evidence for the pressure-induced formation of 2D diamond. High-pressure Raman spectroscopy provides evidence of a phase…

Resonant optical excitation of apical oxygen vibrational modes in the normal state of underdoped YBa2Cu3O6+x induces a transient state with optical properties similar to those of the equilibrium superconducting state. Amongst these, a…

Using X-ray absorption spectroscopy (XAS), we studied the local structure in LaMnO3 under applied pressure across and well above the insulator to metal (IM) transition. A hysteretic behavior points to the coexistence of two phases within a…

We investigate the crystal structure and lattice vibrations of Sr$_2$IrO$_4$ by a combined phonon Raman scattering and x-ray powder diffraction experiment under pressures up to $66$ GPa and room temperature. Density functional theory (DFT)…

Strongly Correlated Electrons · Physics 2018-09-05 K. Samanta , F. M. Ardito , N. M. Souza-Neto , E. Granado

Room temperature angle-dispersive x-ray diffraction measurements on zircon-type TbVO4 and CeVO4 were performed in a diamond-anvil cell up to 50 GPa using neon as pressure-transmitting medium. In TbVO4 we found at 6.4 GPa evidence of a…

Materials Science · Physics 2012-01-26 D. Errandonea , R. S. Kumar , S. N. Achary , A. K. Tyagi

Unknown changes in the crystalline order of regular TiO$_2$ result in the formation of black titania, which has garnered significant interest as a photocatalytic material due to the accompanying electronic changes. Herein, we determine the…

Materials Science · Physics 2019-08-08 Brett Leedahl , Tristan de Boer , Xiaotao Yuan , Alexander Moewes

We have studied the amorphization process of SnI4 up to 26.8GPa with unprecedented experimental details by combining Sn and I K edge X-ray absorption spectroscopy and powder X-ray diffraction. Standards and reverse Monte Carlo extended…

Materials Science · Physics 2020-05-06 Emiliano Fonda , Alain Polian , Toru Shinmei , Tetsuo Irifune , Jean-Paul Itié

High-entropy oxides (HEOs) are a promising class of multicomponent ceramics with tunable structural and electronic properties. In this study, we investigate the local electronic structure of rare-earth HEOs in the (Ce, Sm, Pr, La, Y)O2…

Pressure-induced phase transitions of multiferroic BiFeO3 have been investigated using synchrotron radiation X-ray diffraction with diamond anvil cell technique at room temperature. Present experimental data clearly show that rhombohedral…

Materials Science · Physics 2013-08-30 Zhang XiaoLi , Wu Ye , Zhang Qian , Dong JunCai , Wu Xiang , Liu Jing , Wu ZiYu , Chen DongLiang

Iron-bearing oxides undergo a series of pressure-induced electronic, spin and structural transitions that can cause seismic anomalies and dynamic instabilities in Earth's mantle and outer core. We employ x-ray diffraction and x-ray emission…

Strongly Correlated Electrons · Physics 2023-07-10 E. Greenberg , R. Nazarov , A. Landa , J. Ying , R. Q. Hood , B. Hen , R. Jeanloz , V. B. Prakapenka , V. V. Struzhkin , G. Kh. Rozenberg , I. Leonov

The local environment of nickel atoms in Y NiO3 across the pressure- induced insulator to metal (IM) transition was studied using X-ray absorption spectroscopy (XAS) supported by ab initio calculations. The monotonic contraction of the NiO6…

Strongly Correlated Electrons · Physics 2015-06-03 A. Y. Ramos , C. Piamonteze , H. C. N. Tolentino , O. Bunau , Y. Joly , S. Grenier , J. -P. Itie , N. E. Massa , J. A. Alonso , M. J. Martinez-Lope

Traditional trial-and-error methods are obstacles for large-scale searching of new optoelectronic materials. Here, we introduce a method combining high-throughput ab initio calculations and machine-learning approaches to predict…

Materials Science · Physics 2021-02-24 Xing-Yu Ma , James P. Lewis , Qing-Bo Yan , Gang Su

We report a room-temperature optical reflectivity study performed on [112]-oriented Cd$_3$As$_2$ single crystals over a broad energy range under external pressure up to 10 GPa. The abrupt drop of the band dispersion parameter…

Materials Science · Physics 2018-05-23 E. Uykur , R. Sankar , D. Schmitz , C. A. Kuntscher
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