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Effects of relative orientation of the molecules on electron transport in molecular devices are studied by non-equilibrium Green's function method based on density functional theory. In particular, two molecular devices, with the planer…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Yan-Hong Zhou , Xiao-Hong Zheng , Ying Xu , Zhao Yang Zeng , Zhi Zeng

We investigate the non-equilibrium transport properties of a disordered molecular nanowire. The nanowire is regarded as a quasi-one-dimensional organic crystal composed of self-assembled molecules. One orbital and a single random energy are…

Mesoscale and Nanoscale Physics · Physics 2017-06-07 P. Thiessen , E. Diaz , R. A. Roemer , F. Dominguez-Adame

Highly conductive molecular junctions were formed by direct binding of benzene molecules between two Pt electrodes. Measurements of conductance, isotopic shift in inelastic spectroscopy and shot noise compared with calculations provide…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Kiguchi , O. Tal , S. Wohlthat , F. Pauly , M. Krieger , D. Djukic , J. C. Cuevas , J. M. van Ruitenbeek

Electron transport through a diatomic molecular tunnel junction shows wave like interference phenomenon. By using Keldysh non-equilibrium Green's function (NEGF) theory, we have explicitly presented current and differential conductance…

Mesoscale and Nanoscale Physics · Physics 2012-12-18 Muhammad Imran

We present a novel implementation of the first-principles approach to molecular charge transport using the non-equilibrium Green's function formalism in combination with the ADF/BAND periodic band-structure DFT code, together with results…

Materials Science · Physics 2014-03-18 C. J. O. Verzijl , J. M. Thijssen

We simulate the electronic and transport properties of metal/two-dimensional material/metal vertical heterostructures, with a focus on graphene, hexagonal boron nitride and two phases of molybdenum diselenide. Using density functional…

Mesoscale and Nanoscale Physics · Physics 2025-02-06 Gaëlle Bigeard , Zineb Kerrami , François Triozon , Alessandro Cresti

We consider tunneling transport through a Mn$_{12}$ molecular magnet using spin density functional theory. A tractable methodology for constructing many-body wavefunctions from Kohn-Sham orbitals allows for the determination of…

Mesoscale and Nanoscale Physics · Physics 2010-02-08 L. Michalak , C. M. Canali , M. R. Pederson , M. Paulsson , V. G. Benza

Equilibrium structure, local densities of states, and electronic transport in a gold nanowire made of a four-atom chain supported by two gold electrodes, which has been imaged recently by high-resolution electron microscopy, and chemical…

Materials Science · Physics 2007-05-23 Hannu Hakkinen , Robert N. Barnett , Uzi Landman

We present quantum electron transport theory that incorporates dynamical effects of motion of atoms on electrode-molecule interfaces in the calculations of the electric current. The theory is based on non-equilibrium Green's functions. We…

Mesoscale and Nanoscale Physics · Physics 2018-08-14 Vincent F. Kershaw , Daniel S. Kosov

We study the electron transport through the quantum dot coupled to the normal metal and BCS-like superconductor (N - QD - S) in the presence of the Kondo effect and Andreev scattering. The system is described by the single impurity Anderson…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 M. Krawiec , K. I. Wysokinski

This paper reviews some selected approaches to the description of transport properties, mainly electroconductivity, in crystalline and disordered metallic systems. A detailed qualitative theoretical formulation of the electron transport…

Statistical Mechanics · Physics 2011-09-27 A. L. Kuzemsky

We present an atomistic theory of electronic transport through single organic molecules that reproduces the important features of the current-voltage characteristics observed in recent experiments. We trace these features to their origin in…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Heurich , J. C. Cuevas , W. Wenzel , G. Schoen

Magneto-transport properties are investigated in a binary alloy ring subjected to an Aharonov-Bohm (AB) flux \phi within a single-band non-interacting tight-binding framework. In the first part, we expose analytically the behavior of…

Mesoscale and Nanoscale Physics · Physics 2012-04-10 Paramita Dutta , Santanu K. Maiti , S. N. Karmakar

We study non-equilibrium electron transport through a quantum dot coupled to metallic leads. We use an alternative equation of motion approach in which we calculate the retarded Green function of the impurity by differentiating Green…

Mesoscale and Nanoscale Physics · Physics 2014-12-23 Grzegorz Górski , Jerzy Mizia , Krzysztof Kucab

First principles approaches have been successful in solving many-body Hamiltonians for real materials to an extent when correlations are weak or moderate. As the electronic correlations become stronger often embedding methods based on first…

We consider a model of a molecular junction made of BDT (benzene dithiol) molecule trapped between two Au(100) leads. Using the ab initio approach implemented in the SIESTA package we look for the optimal configuration of the molecule as a…

Materials Science · Physics 2015-06-25 Victor M. Garcia-Suarez , Tomasz Kostyrko , Steven Bailey , Colin Lambert , Bogdan R. Bulka

Nonequilibrium electronic transport through a quantum dot coupled to ferromagnetic leads (electrodes) is studied theoretically by the nonequilibrium Green function technique. The system is described by the Anderson model with arbitrary…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 R. Swirkowicz , M. Wilczynski , J. Barnas

We present a first-principles method for calculating the charging energy of a molecular single-electron transistor operating in the Coulomb blockade regime. The properties of the molecule are modeled using density-functional theory, the…

Mesoscale and Nanoscale Physics · Physics 2012-04-04 Kurt Stokbro

The electrical transport properties of atomic-scale conductors are reviewed, with an emphasis on the relations of this problem with studies on quantum size effects in metallic clusters. A brief introduction is given of the natural formalism…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. M. van Ruitenbeek

Inelastic effects in electron transport through nano-sized devices are addressed with a method based on nonequilibrium Green's functions (NEGF) and perturbation theory to infinite order in the electron-vibration coupling. We discuss the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thomas Frederiksen , Mads Brandbyge , Nicolas Lorente , Antti-Pekka Jauho