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The remarkable properties of graphene stem from its two-dimensional (2D) structure, with a linear dispersion of the electronic states at the corners of the Brillouin zone (BZ) forming a Dirac cone. Since then, other 2D materials have been…

Materials Science · Physics 2018-11-06 S. Sadeddine , H. Enriquez , A. Bendounan , P. Das , I. Vobornik , A. Kara , A. Mayne , F. Sirotti , G. Dujardin , H. Oughaddou

Two-dimensional (2D) Dirac-like electron gases have attracted tremendous research interest ever since the discovery of free-standing graphene. The linear energy dispersion and non-trivial Berry phase play the pivotal role in the remarkable…

2D materials are well-known to exhibit interesting phenomena due to quantum confinement. Here, we show that quantum confinement, together with structural anisotropy, result in an electric-field-tunable Dirac cone in 2D black phosphorus.…

Materials Science · Physics 2015-08-18 Kapildeb Dolui , Su Ying Quek

Among exciting recent advances in the field of two-dimensional (2D) materials, the successful fabrications of the C60 fullerene networks has been a particularly inspiring accomplishment. Motivated by the recent achievements, herein we…

Materials Science · Physics 2023-08-11 Bohayra Mortazavi , Yves Remond , Hongyuan Fang , Timon Rabczuk , Xiaoying Zhuang

Boron is the fifth element in the periodic table and possesses rich chemistry second only to carbon. A striking feature of boron is that B12 icosahedral cages occur as the building blocks in bulk boron and many boron compounds. This is in…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 Baojie Feng , Jin Zhang , Qing Zhong , Wenbin Li , Shuai Li , Hui Li , Peng Cheng , Sheng Meng , Lan Chen , Kehui Wu

We propose previously unknown allotropes of phosphorus carbide (PC) in the stable shape of an atomically thin layer. Different stable geometries, which result from the competition between sp2 bonding found in graphitic C and sp3 bonding…

Materials Science · Physics 2016-05-25 Jie Guan , Dan Liu , Zhen Zhu , David Tomanek

Two-dimensional (2D) carbon nitride materials play an important role in energy-harvesting, energy-storage and environmental applications. Recently, a new carbon nitride, 2D polyaniline (C3N) was proposed [PNAS 113 (2016) 7414-7419]. Based…

Materials Science · Physics 2016-12-13 Linyang Li , Xiangru Kong , Ortwin Leenaerts , Xin Chen , Biplab Sanyal , François M. Peeters

We propose two novel two-dimensional topological Dirac materials, planar PtN4C2 and Pt2N8C6, which exhibit graphene-like electronic structures with linearly dispersive Dirac-cone states exactly at the Fermi level. Moreover, the Dirac cone…

Materials Science · Physics 2022-07-20 Jingping Dong , Chuhan Wang , Xinlei Zhao , Miao Gao , Xun-Wang Yan , Fengjie Ma , Zhong-Yi Lu

We study the mechanical properties of two-dimensional (2D) boron, borophenes, by first-principles calculations. The recently synthesized borophene with 1/6 concentration of hollow hexagons (HH) is shown to have in-plane modulus C up to 210…

Materials Science · Physics 2017-01-12 Zhuhua Zhang , Yang Yang , Evgeni S. Penev , Boris I. Yakobson

Emergent Dirac fermion states underlie many intriguing properties of graphene, and the search for them constitute one strong motivation to explore two-dimensional (2D) allotropes of other elements. Phosphorene, the ultrathin layers of black…

Anthracyne (2DDA). 2DDA consists of chains of Dewar-anthracenes connected by acetylenic linkages. DFT-based simulations show that 2DDA is thermally stable and exhibits no imaginary phonon modes, confirming its dynamic stability. 2DDA is…

Two-dimensional (2D) materials may exhibit intriguing band structure features (e.g., Dirac points), that lay far away from the Fermi level. They are, thus, not usable in applications. The semiconducting 2D material PC6 has two Dirac cones…

Materials Science · Physics 2021-10-01 Maximilian A. Springer , Thomas Brumme , Agnieszka Kuc , Thomas Heine

Two-dimensional (2D) Dirac cone materials exhibit linear energy dispersion at the Fermi level, where the effective masses of carriers are very close to zero and the Fermi velocity is ultrahigh, only 2 ~ 3 orders of magnitude lower than the…

Materials Science · Physics 2019-10-15 Yang Zhang , Jun Kang , Fan Zheng , Peng-Fei Gao , Sheng-Li Zhang , Lin-Wang Wang

Borophene (two-dimensional boron sheet) is a new type of two-dimensional material, which was recently grown successfully on single crystal Ag substrates. In this paper, we investigate the electronic structure and bonding characteristics of…

Mesoscale and Nanoscale Physics · Physics 2016-06-23 Bo Peng , Hao Zhang , Hezhu Shao , Yuanfeng Xu , Rongjun Zhang , Heyuan Zhu

Topological metal/semimetals (TMs) have emerged as a new frontier in the field of quantum materials. A few two-dimensional (2D) boron sheets have been suggested as Dirac materials, however, to date TMs made of three-dimensional (3D) boron…

Materials Science · Physics 2018-10-17 Yan Gao , Yuee Xie , Yuanping Chen , Jinxing Gu , Zhongfang Chen

Potentially new, single-atom thick semiconducting 2D-graphene-like material, called Anisotropic-cyclicgraphene, have been generated by the two stage searching strategy linking molecular and ab initio approach. The candidate derived from the…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Marcin Maździarz , Adam Mrozek , Wacław Kuś , Tadeusz Burczyński

Recent synthesis of monolayer borophene (triangle boron monolayer) on the substrate opens the era of boron nanosheet (Science, 350, 1513, $\mathbf{2015}$), but the structural stability and novel physical properties are still open issues.…

Materials Science · Physics 2016-02-12 Lichun Xu , Aijun Du , Liangzhi Kou

Strong band engineering in two-dimensional (2D) materials can be achieved by introducing moir\'e superlattices, leading to the emergence of various novel quantum phases with promising potential for future applications. Presented works to…

Mesoscale and Nanoscale Physics · Physics 2023-03-27 Shimin Cao , Mantang Chen , Jiang Zeng , Ning Ma , Runjie Zheng , Ya Feng , Shili Yan , Jing Liu , Kenji Watanabe , Takashi Taniguchi , X. C. Xie , Jian-Hao Chen

Atomic scale engineering of two-dimensional materials could create devices with rich physical and chemical properties. External periodic potentials can enable the manipulation of the electronic band structures of materials. A prototypical…

Materials Science · Physics 2019-05-22 B. Feng , H. Zhou , Y. Feng , H. Liu , S. He , I. Matsuda , L. Chen , E. F. Schwier , K. Shimada , S. Meng , K. Wu

Hydrogen, a simple and magic element, has attracted increasing attention for its effective incorporation within solids and powerful manipulation of electronic states. Here, we show that hydrogenation tackles common problems in…

Mesoscale and Nanoscale Physics · Physics 2023-02-10 Botao Fu , Run-Wu Zhang , Xiaotong Fan , Si Li , Da-Shuai Ma , Cheng-Cheng Liu