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The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between…
Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…
Efforts to characterize extrasolar giant planet (EGP) atmospheres have so far emphasized planets within 0.05 AU of their stars. Despite this focus, known EGPs populate a continuum of orbital separations from canonical hot Jupiter values…
With the recent discoveries of terrestrial planets around active M-dwarfs, destruction processes masking the possible presence of life are receiving increased attention in the exoplanet community. We investigate potential biosignatures of…
We demonstrate the effectiveness of the Exoplanet Characterisation Observatory mission concept for constraining the atmospheric properties of hot and warm gas giants and super Earths. Synthetic primary and secondary transit spectra for a…
We calculated an atmospheric grid for hot mini-Neptune and giant exoplanets, that links astrophysical observable parameters- orbital distance and stellar type- with the chemical atmospheric species expected. The grid can be applied to…
We present a study of the photochemistry of abiotic habitable planets with anoxic CO$_2$-N$_2$ atmospheres. Such worlds are representative of early Earth, Mars and Venus, and analogous exoplanets. H$_2$O photodissociation controls the…
A large number of studies have responded to the growing body of confirmed terrestrial habitable zone exoplanets by presenting models of various possible climates. However, the impact of the partial pressure of background gases such as N$_2$…
Thermochemical models have been used in the past to constrain the deep oxygen abundance in the gas and ice giant planets from tropospheric CO spectroscopic measurements. Knowing the oxygen abundance of these planets is a key to better…
A planet's surface conditions can significantly impact its climate and habitability. In this study, we use the 3D general circulation model ExoPlaSim to systematically vary dayside land cover on a synchronously rotating, temperate rocky…
We present a study of the effect of wind-driven advection on the chemical composition of hot Jupiter atmospheres using a fully-consistent 3D hydrodynamics, chemistry and radiative transfer code, the Met Office Unified Model (UM). Chemical…
We compute models of the transmission spectra of planets HD 209458b, HD 189733b, and generic hot Jupiters. We examine the effects of temperature, surface gravity, and metallicity for the generic planets as a guide to understanding…
While steady empirical progress has been made in understanding the structure and composition of hot planet atmospheres, direct measurements of velocity signatures, including winds, rotation, and jets, have lagged behind. Quantifying…
The James Webb Space Telescope (JWST) will enable the search for and characterization of terrestrial exoplanet atmospheres in the habitable zone via transmission spectroscopy. However, relatively little work has been done to use solar…
Transmission spectroscopy enables the characterization of exoplanet atmospheres by probing absorption features in their terminator regions. In the optical, it is particularly sensitive to metal oxides and atomic species that can strongly…
High resolution spectroscopy has allowed for unprecedented levels of atmospheric characterization, especially for the hottest gas giant exoplanets known as ultrahot Jupiters (UHJs). High-resolution spectra are sensitive to 3D effects,…
Observed chemical species in the Venusian mesosphere show local-time variabilities. SO2 at the cloud top exhibits two local maxima over local time, H2O at the cloud top is uniformly distributed, and CO in the upper atmosphere shows a…
A carbon-to-oxygen ratio (C/O) of around unity is believed to act as a natural separator of water- and methane-dominated spectra when characterizing exoplanet atmospheres. In this paper we quantify the C/O ratios at which this separation…
Aerosols appear to be ubiquitous in close-in gas giant atmospheres, and disequilibrium chemistry likely impacts the emergent spectra of these planets. Lofted aerosols and disequilibrium chemistry are caused by vigorous vertical transport in…
Characterizing temperate exoplanet atmospheres remains challenging due to their small size and low temperatures. Recent JWST observations provide valuable data, but their interpretation has led to diverging conclusions. Complementary…