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The properties of rechargeable lithium-ion batteries are determined by the electrochemical and kinetic properties of their constituent materials as well as by their underlying microstructure. Microstructural design can be leveraged to…

Materials Science · Physics 2022-03-11 Giovanna Bucci , Tushar Swamy , W. Craig Carter , Morad Behandish

Continuum simulation is employed to study ion transport and fluid flow through a nanopore in a solid-state membrane under an applied potential drop. Results show the existence of concentration polarization layers on the surfaces of the…

Fluid Dynamics · Physics 2015-06-16 Mao Mao , Sandip Ghosal , Guohui Hu

Thick Li-ion battery electrodes with high ion transport rates could enable batteries that cost less and that have higher gravimetric and volumetric energy density, because they require fewer inactive cell-components. Finding ways to…

Materials Science · Physics 2015-05-14 V. Pavan Nemani , Stephen J. Harris , Kyle C. Smith

Designing lithium-ion batteries for long service life remains a challenge, as most cells are optimized for beginning-of-life metrics such as energy density, often overlooking how design and operating conditions shape degradation. This work…

Harvesting waste heat with temperatures lower than 100 oC can improve system efficiency and reduce greenhouse gas emissions, yet it has been a longstanding and challenging task. Electrochemical methods for harvesting low-grade heat have…

Applied Physics · Physics 2021-11-03 Xin Qian , Jungwoo Shin , Yaodong Tu , James Han Zhang , Gang Chen

Lithium-air batteries have been considered as ultimate solutions for the power source of long-range electrified transportation, but state-of-the-art prototypes still suffer from short cycle life, low efficiency and poor power output. Here,…

Chemical Physics · Physics 2016-03-24 Peng Bai , Martin Z. Bazant

We obtain the output characteristics of graphene field-effect transistors by using the charge-control model for the current, based on the solution of the Boltzmann equation in the field-dependent relaxation time approximation. Closed…

Mesoscale and Nanoscale Physics · Physics 2010-07-22 Brett W. Scott , Jean-Pierre Leburton

"Anode-free" lithium-metal batteries promise significantly higher energy density than conventional graphite-based lithium-ion batteries; however, lithium dendrite growth can lead to internal short circuits with associated safety risks.…

The development of high-power density vanadium redox flow batteries (VRFBs) with high energy efficiencies (EEs) is crucial for the widespread dissemination of this energy storage technology. In this work, we report the production of novel…

Space-charge-limited (SCL) current density for time-invariant injection (under long-pulse condition) via the diode cathode is the maximum transportable density, while it can be leveraged higher when the injection pulselength becomes shorter…

Plasma Physics · Physics 2026-02-11 H. Huang , Y. Liu

In this paper we report the theory describing the electro-osmotic flow in charged nanopores with constant radius and charge density driven by alternating current. We solve the ion and solution transport in unsteady conditions as described…

Chemical Physics · Physics 2018-10-17 J. Catalano , P. M. Biesheuvel

We investigate the flow of an electrolyte through a rigid nanochannel decorated with a surface charge pattern. Employing lattice Boltzmann and dissipative particle dynamics methods, as well as analytical theory, we show that the…

Soft Condensed Matter · Physics 2024-01-12 Tine Curk , Sergi G. Leyva , Ignacio Pagonabarraga

The behavior of a conductive membrane in a static (DC) electric field is investigated theoretically. An effective zero-thickness model is constructed based on a Robin-type boundary condition for the electric potential at the membrane,…

Soft Condensed Matter · Physics 2015-05-14 Falko Ziebert , Martin Z. Bazant , David Lacoste

Several effective methods have been developed recently to demonstrate simultaneous high energy and high power density in Li - carbon fluoride (CF$_x$) batteries. These methods can achieve as high as 1000 Wh/kg energy density at 60-70 kW/kg…

Materials Science · Physics 2023-03-28 Haobin Huo , Leon L. Shaw , Karoly Nemeth

Viscous electron fluids have emerged recently as a new paradigm of strongly-correlated electron transport in solids. Here we report on a direct observation of the transition to this long-sought-for state of matter in a high-mobility…

A general technique to investigate charge storage characteristics of conducting polymer films has been developed. A redox reaction is conducted on a polymer film on a rotating disk electrode under potentiostatic condition so that the rate…

Chemical Physics · Physics 2013-11-19 Asfiya Q. Contractor , Vinay A. Juvekar

The local persistent current in two dimensional strongly interacting systems is investigated. As the interaction strength is enhanced the current in the sample undergoes a transition from diffusive to ordered flow. The strong interacting…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Richard Berkovits , Yshai Avishai

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

Soft Condensed Matter · Physics 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

Lithium-ion batteries rely on particulate porous electrodes to realize high performance, especially the fast-charging capability. To minimize the particle-wise reaction heterogeneities that may lead to local hot spots, deeper understandings…

Materials Science · Physics 2022-04-15 Shubham Agrawal , Peng Bai

The quest for safe high-energy batteries with "5V-class" cathodes and lithium metal anodes drives research into solid electrolytes. However, reasons for the large charge transfer resistances -- the major bottleneck of all-solid-state…

Chemical Physics · Physics 2021-01-26 Katharina Becker-Steinberger , Simon Schardt , Birger Horstmann , Arnulf Latz