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We report the properties of two new series of compounds that show the ferroelectric nematic phase in which the length of a terminal chain is varied. The longer the terminal chain, the weaker the dipole-dipole interactions of the molecules…

The possibility that metals may support ferroelectricity is an open issue. Anderson and Blount showed that certain martensitic transitions involve inversion symmetry breaking and the formal existence of a polar axis, so 'metallic…

Materials Science · Physics 2016-04-08 Alessio Filippetti , Vincenzo Fiorentini , Francesco Ricci , Pietro Delugas , Jorge Íñiguez

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

Strongly Correlated Electrons · Physics 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

With gradual temperature increase in premelting regions of solid phase of methanol and high pressure phase of ethanol, and using novel procedure of separation of electrode polarization effects, we are able to register the contribution of…

Materials Science · Physics 2022-05-11 M. V. Kondrin , A. A. Pronin , Y. B. Lebed , V. V. Brazhkin

Polar metals based on binary and ternary compounds have been demonstrated in literature. Here, we propose a design principle for ferroelectric-like elemental polar metals and relate it to real materials. The design principle is that, to be…

Materials Science · Physics 2022-05-17 Hu Zhang , Bei Deng , Wei-Chao Wang , Xing-Qiang Shi

We study an unconventional phase transition in ferroelectrics where the polarization field is constrained to be divergence-free, allowing only loop-like configurations. This local constraint fundamentally alters the critical behavior,…

Mesoscale and Nanoscale Physics · Physics 2026-03-25 Svitlana Kondovych , Asle Sudbø , Flavio S. Nogueira

Ferroelectrics with spontaneous electric polarization play an essential role in today's device engineering, such as capacitors and memories. Their physical properties are further enriched by suppressing the long-range polar order, as is…

Materials Science · Physics 2017-03-14 H. Sakai , K. Ikeura , M. S. Bahramy , N. Ogawa , D. Hashizume , J. Fujioka , Y. Tokura , S. Ishiwata

Ionic crystals, such as solid electrolytes and complex oxides, are central to modern technologies for energy storage, sensing, actuation, and other functional applications. An important fundamental issue in the atomic and quantum-scale…

Materials Science · Physics 2026-02-12 Shoham Sen , Yang Wang , Timothy Breitzman , Kaushik Dayal

The Thomas-Fermi (TF) approximation for the static dielectric constant of a three-dimensional electron liquid can be derived from minimizing the TF local-density approximation for the kinetic-energy functional. Here we show that this…

Materials Science · Physics 2009-11-11 A. P. Favaro , Joao Vitor Batista Ferreira , K. Capelle

Improper ferroelectrics are described by two order parameters: a primary one, driving a transition to long-range distortive, magnetic or otherwise non-electric order, and the electric polarization, which is induced by the primary order…

The phenomenon of the spontaneous electric polarization (ferro- and antiferroelectricity) is one of the fundamental problems of the solid-state physics. Although, there has been lot of experimental and theoretical progress, still needs to…

General Physics · Physics 2009-01-27 Shpend Mushkolaj

The existence of the linear on the order parameter term of the thermodynamic functions expansion near the critical point is justified. The criticism of the arguments, used for the rejection of the odd-power expansion terms of the…

Condensed Matter · Physics 2007-05-23 V. A. Skrebnev

Searching for space/time noncommutativity we reconsider open strings in a constant background electric field. The main difference between this situation and its magnetic counterpart is that here there is a critical electric field beyond…

High Energy Physics - Theory · Physics 2009-10-31 N. Seiberg , L. Susskind , N. Toumbas

Ferroelectric crystals must adopt one of the 10 polar point groups according to the Neumann's principle. In this paper we propose that this conclusion is based on perfect bulk crystals without taking the boundaries into account, and we show…

Materials Science · Physics 2024-07-01 Yuxuan Sheng , Menghao Wu

The design of the interfacial bondings at metal-oxide interfaces yields exciting new phenomena and can be a route to sustain, and even promote, ferroelectricity at the nanoscale. We study the impact of these interfaces on the nature of the…

Materials Science · Physics 2014-08-12 A. Cano , A. P. Levanyuk

We have investigated the dielectric properties of Gd$_{1-x}$Tb$_{x}$MnO$_{3}$ crystals in magnetic fields to clarify the crossover between two distinct ferroelectric phases, GdMnO$_{3}$-type (first-order displacive) and TbMnO$_{3}$-type…

Strongly Correlated Electrons · Physics 2009-11-11 K. Noda , S. Nakamura , H. Kuwahara

Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and…

Chemical Physics · Physics 2007-05-23 Francesca Terenziani , Anna Painelli , Zoltan G. Soos

In contrast to ordinary ferroelectrics where the temperature, Tm, of the permittivity maximum monotonically increases with bias field, E, in (1-x)PbMg1/3Nb2/3O3-(x)PbTiO3 (0<x<0.35) single crystals, Tm was found to remain constant or…

An accurate estimate of the ferroelectric polarization in ferroelectric-dielectric stacks is important from a materials science perspective, and it is also crucial for the development of ferroelectric based electron devices. This paper…

Materials Science · Physics 2022-04-13 Mattia Segatto , Riccardo Fontanini , Francesco Driussi , Daniel Lizzit , David Esseni

To study the effects appearing under mechanical stresses, we have used the model of glycinium phosphite ferroelectric, modified by taking into account the piezoelectric coupling of ordering structure elements with lattice strains. In the…

Materials Science · Physics 2018-09-27 I. R. Zachek , R. R. Levitskii , A. S. Vdovych